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Clusters of IIA and IIIA groups metals: synthesis and reactivity

Vladimir Valentinovich Smirnov 1
Vladimir Valentinovich Smirnov
, 
Lyudmila Alexandrovna Tyurina 1
Lyudmila Alexandrovna Tyurina
1 M. V. Lomonosov Moscow State University, Department of Chemistry
10.1070/RC1994v063n01ABEH000071
Published 30 November 1993
Communication , Volume 63, Issue 1, 55-69
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Smirnov V. V., Tyurina L. A. Clusters of IIA and IIIA groups metals: synthesis and reactivity // Russian Chemical Reviews. 1994. Vol. 63. No. 1. pp. 55-69.
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Smirnov V. V., Tyurina L. A. Clusters of IIA and IIIA groups metals: synthesis and reactivity // Russian Chemical Reviews. 1994. Vol. 63. No. 1. pp. 55-69.
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TY - JOUR
DO - 10.1070/RC1994v063n01ABEH000071
UR - https://rcr.colab.ws/publications/10.1070/RC1994v063n01ABEH000071
TI - Clusters of IIA and IIIA groups metals: synthesis and reactivity
T2 - Russian Chemical Reviews
AU - Smirnov, Vladimir Valentinovich
AU - Tyurina, Lyudmila Alexandrovna
PY - 1994
DA - 1993/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 55-69
IS - 1
VL - 63
ER -
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@article{1994_Smirnov,
author = {Vladimir Valentinovich Smirnov and Lyudmila Alexandrovna Tyurina},
title = {Clusters of IIA and IIIA groups metals: synthesis and reactivity},
journal = {Russian Chemical Reviews},
year = {1994},
volume = {63},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1994v063n01ABEH000071},
number = {1},
pages = {55--69},
doi = {10.1070/RC1994v063n01ABEH000071}
}
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Smirnov, Vladimir Valentinovich, and Lyudmila Alexandrovna Tyurina. “Clusters of IIA and IIIA groups metals: synthesis and reactivity.” Russian Chemical Reviews, vol. 63, no. 1, Nov. 1994, pp. 55-69. https://rcr.colab.ws/publications/10.1070/RC1994v063n01ABEH000071.
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Abstract

Experimental and theoretical data on the structure of clusters of Group IIA and IIIA metals are summarised. General trends in the properties of the clusters as a function of nuclearity are outlined, and special points on the dependences, corresponding to the so-called magic numbers, are identified. Data on the reactivity of clusters in the gas phase are used to establish the anomalies corresponding to these points. It is shown that the reactivity of mixed clusters obeys more complex relationships, determined by their electronic structure and geometry. A new type of organomagnesium cluster is described, and shown to be promising as a component of catalytic systems. The cryochemical synthesis of giant clusters of transition metals, which offer a high reactivity and catalytic activity is described. The bibliography includes 176 references.

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