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Acid strength of proton donors in complexes of nontransition metal halides as a measure of the activity of electrophilic polymerisation catalysts

Karl Samoilovich Minsker 1
Karl Samoilovich Minsker
, 
Vladimir Aleksandrovich Babkin 1
Vladimir Aleksandrovich Babkin
, 
Gennadii Efremovich Zaikov 2
Gennadii Efremovich Zaikov
1 Bashkir State University, Ufa
2 N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow
10.1070/RC1994v063n03ABEH000558
Published 30 November 1993
Communication , Volume 63, Issue 3, 279-288
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Minsker K. S., Babkin V. A., Zaikov G. E. Acid strength of proton donors in complexes of nontransition metal halides as a measure of the activity of electrophilic polymerisation catalysts // Russian Chemical Reviews. 1994. Vol. 63. No. 3. pp. 279-288.
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Minsker K. S., Babkin V. A., Zaikov G. E. Acid strength of proton donors in complexes of nontransition metal halides as a measure of the activity of electrophilic polymerisation catalysts // Russian Chemical Reviews. 1994. Vol. 63. No. 3. pp. 279-288.
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TY - JOUR
DO - 10.1070/RC1994v063n03ABEH000558
UR - https://rcr.colab.ws/publications/10.1070/RC1994v063n03ABEH000558
TI - Acid strength of proton donors in complexes of nontransition metal halides as a measure of the activity of electrophilic polymerisation catalysts
T2 - Russian Chemical Reviews
AU - Minsker, Karl Samoilovich
AU - Babkin, Vladimir Aleksandrovich
AU - Zaikov, Gennadii Efremovich
PY - 1994
DA - 1993/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 279-288
IS - 3
VL - 63
ER -
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@article{1994_Minsker,
author = {Karl Samoilovich Minsker and Vladimir Aleksandrovich Babkin and Gennadii Efremovich Zaikov},
title = {Acid strength of proton donors in complexes of nontransition metal halides as a measure of the activity of electrophilic polymerisation catalysts},
journal = {Russian Chemical Reviews},
year = {1994},
volume = {63},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1994v063n03ABEH000558},
number = {3},
pages = {279--288},
doi = {10.1070/RC1994v063n03ABEH000558}
}
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Minsker, Karl Samoilovich, et al. “Acid strength of proton donors in complexes of nontransition metal halides as a measure of the activity of electrophilic polymerisation catalysts.” Russian Chemical Reviews, vol. 63, no. 3, Nov. 1994, pp. 279-288. https://rcr.colab.ws/publications/10.1070/RC1994v063n03ABEH000558.
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Abstract

Data on one of the most urgent problems in modern theoretical chemistry are reviewed: the calculation of the acid strength of the complexes formed by the interaction of Lewis acids with proton donors, and the correlation of the acid strength with the activity and selectivity of these complexes as catalysts of electrophilic processes. Complexes based on aluminium and magnesium chlorides and on boron fluorides are discussed. It is shown that increasing the acid strength of these complexes as catalysts of electrophilic polymerisation reactions increases their activity but lowers their selectivity. The bibliography includes 43 references.

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