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Stereodynamics and degenerate ligand exchange in solutions of tetracoordinate chelate complexes of nontransition metals

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Leonid Efimovich Nivorozhkin 1
Leonid Efimovich Nivorozhkin
, 
Mikhail Stepanovich Korobov 1
Mikhail Stepanovich Korobov
1 Institute of Physical and Organic Chemistry at Rostov State University
10.1070/RC1994v063n04ABEH000085
Published 30 November 1993
Communication , Volume 63, Issue 4, 289-311
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Minkin V. I., Nivorozhkin L. E., Korobov M. S. Stereodynamics and degenerate ligand exchange in solutions of tetracoordinate chelate complexes of nontransition metals // Russian Chemical Reviews. 1994. Vol. 63. No. 4. pp. 289-311.
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Minkin V. I., Nivorozhkin L. E., Korobov M. S. Stereodynamics and degenerate ligand exchange in solutions of tetracoordinate chelate complexes of nontransition metals // Russian Chemical Reviews. 1994. Vol. 63. No. 4. pp. 289-311.
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TY - JOUR
DO - 10.1070/RC1994v063n04ABEH000085
UR - https://rcr.colab.ws/publications/10.1070/RC1994v063n04ABEH000085
TI - Stereodynamics and degenerate ligand exchange in solutions of tetracoordinate chelate complexes of nontransition metals
T2 - Russian Chemical Reviews
AU - Minkin, Vladimir Isaakovich
AU - Nivorozhkin, Leonid Efimovich
AU - Korobov, Mikhail Stepanovich
PY - 1994
DA - 1993/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 289-311
IS - 4
VL - 63
ER -
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@article{1994_Minkin,
author = {Vladimir Isaakovich Minkin and Leonid Efimovich Nivorozhkin and Mikhail Stepanovich Korobov},
title = {Stereodynamics and degenerate ligand exchange in solutions of tetracoordinate chelate complexes of nontransition metals},
journal = {Russian Chemical Reviews},
year = {1994},
volume = {63},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1994v063n04ABEH000085},
number = {4},
pages = {289--311},
doi = {10.1070/RC1994v063n04ABEH000085}
}
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Minkin, Vladimir Isaakovich, et al. “Stereodynamics and degenerate ligand exchange in solutions of tetracoordinate chelate complexes of nontransition metals.” Russian Chemical Reviews, vol. 63, no. 4, Nov. 1994, pp. 289-311. https://rcr.colab.ws/publications/10.1070/RC1994v063n04ABEH000085.
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Abstract

Nontransition metal (d0 , d10 ) chelate complexes possessing a tetrahedral configuration at the metal centre undergo fast intramolecular stereoisomerisation and intermolecular ligand exchange reactions in solution. Inversion of the stereochemical configuration is governed by two types of intramolecular reactions: (1) polytopal rearrangement (digonal twist) and (2) dissociation-recombination reaction due to the cleavage-formation of one of the metal-ligand bonds. The energetically preferred mechanism for the inversion is chiefly determined by the nature of the metal, but it also depends on the type of ligating atoms and their environment. The energy barriers to the inversion of the tetrahedral configuration vary in the range of 10-30 kcal mol-1. The bibliography includes 175 references.

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