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Thermal decomposition of aliphatic nitro-compounds

Gennadii Mikhailovich Nazin 1
Gennadii Mikhailovich Nazin
, 
Georgii Borisovich Manelis 1
Georgii Borisovich Manelis
1 Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region
10.1070/RC1994v063n04ABEH000086
Published 30 November 1993
Communication , Volume 63, Issue 4, 313-322
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Nazin G. M., Manelis G. B. Thermal decomposition of aliphatic nitro-compounds // Russian Chemical Reviews. 1994. Vol. 63. No. 4. pp. 313-322.
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Nazin G. M., Manelis G. B. Thermal decomposition of aliphatic nitro-compounds // Russian Chemical Reviews. 1994. Vol. 63. No. 4. pp. 313-322.
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TY - JOUR
DO - 10.1070/RC1994v063n04ABEH000086
UR - https://rcr.colab.ws/publications/10.1070/RC1994v063n04ABEH000086
TI - Thermal decomposition of aliphatic nitro-compounds
T2 - Russian Chemical Reviews
AU - Nazin, Gennadii Mikhailovich
AU - Manelis, Georgii Borisovich
PY - 1994
DA - 1993/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 313-322
IS - 4
VL - 63
ER -
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@article{1994_Nazin,
author = {Gennadii Mikhailovich Nazin and Georgii Borisovich Manelis},
title = {Thermal decomposition of aliphatic nitro-compounds},
journal = {Russian Chemical Reviews},
year = {1994},
volume = {63},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1994v063n04ABEH000086},
number = {4},
pages = {313--322},
doi = {10.1070/RC1994v063n04ABEH000086}
}
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Nazin, Gennadii Mikhailovich, and Georgii Borisovich Manelis. “Thermal decomposition of aliphatic nitro-compounds.” Russian Chemical Reviews, vol. 63, no. 4, Nov. 1994, pp. 313-322. https://rcr.colab.ws/publications/10.1070/RC1994v063n04ABEH000086.
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Abstract

Literature data on the thermal decomposition reactions of aliphatic nitro-compounds are surveyed and described systematically. Information concerning the influence of molecular structure on the rates and mechanisms of the gas-phase reactions is presented and the structures of the transition states in the C-N dissociation and HNO2 elimination processes are examined. The characteristic features of the decomposition of nitro-compounds in the condensed phase are desctibed. Data are presented on the C-N bond dissociation energy and the influence on the latter of electronic, steric, and conformational effects. The bibliography includes 86 references.

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