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Cryopolymerisation

Igor Mstislavovich Barkalov 1
Igor Mstislavovich Barkalov
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1 Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region
10.1070/RC1994v063n06ABEH000100
Published 30 November 1993
Communication , Volume 63, Issue 6, 491-505
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Barkalov I. M., Kiryukhin D. P. Cryopolymerisation // Russian Chemical Reviews. 1994. Vol. 63. No. 6. pp. 491-505.
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Barkalov I. M., Kiryukhin D. P. Cryopolymerisation // Russian Chemical Reviews. 1994. Vol. 63. No. 6. pp. 491-505.
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TY - JOUR
DO - 10.1070/RC1994v063n06ABEH000100
UR - https://rcr.colab.ws/publications/10.1070/RC1994v063n06ABEH000100
TI - Cryopolymerisation
T2 - Russian Chemical Reviews
AU - Barkalov, Igor Mstislavovich
AU - Kiryukhin, Dmitrii Pavlovich
PY - 1994
DA - 1993/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 491-505
IS - 6
VL - 63
ER -
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@article{1994_Barkalov,
author = {Igor Mstislavovich Barkalov and Dmitrii Pavlovich Kiryukhin},
title = {Cryopolymerisation},
journal = {Russian Chemical Reviews},
year = {1994},
volume = {63},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1994v063n06ABEH000100},
number = {6},
pages = {491--505},
doi = {10.1070/RC1994v063n06ABEH000100}
}
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Barkalov, Igor Mstislavovich, and Dmitrii Pavlovich Kiryukhin. “Cryopolymerisation.” Russian Chemical Reviews, vol. 63, no. 6, Nov. 1994, pp. 491-505. https://rcr.colab.ws/publications/10.1070/RC1994v063n06ABEH000100.
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Abstract

The mechanism of cryochemical chain reactions is examined in relation to polymerisation. The study of such processes in crystals has led to the discovery of a low-temperature limit to the rates of chemical reactions. Polymerisation occurring under the conditions of a sharp change (by 5–6 orders of magnitude) in the molecular mobility of the medium in the region of the devitrification of the matrix has been investigated in vitreous systems. Unusual mechanoenergetic chains of chemical reactions have been observed in the study of systems immersed in liquid helium. The chemical reaction is initiated by a local brittle fracture and is propagated along the specimen in the form of an autowave. Auto-oscillations of the rate of cryopolymerisation have been observed under certain conditions. The bibliography includes 132 references.

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