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Characteristic features of the radical polymerisation of water-soluble monomers

Vladimir Fedorovich Gromov 1
Vladimir Fedorovich Gromov
, 
Elena Viktorovna Bune 1
Elena Viktorovna Bune
, 
Eduard Nikanorovich Teleshov 1
Eduard Nikanorovich Teleshov
1 Karpov Institute of Physical Chemistry, Moscow
10.1070/RC1994v063n06ABEH000101
Published 30 November 1993
Communication , Volume 63, Issue 6, 507-517
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Gromov V. F., Bune E. V., Teleshov E. N. Characteristic features of the radical polymerisation of water-soluble monomers // Russian Chemical Reviews. 1994. Vol. 63. No. 6. pp. 507-517.
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Gromov V. F., Bune E. V., Teleshov E. N. Characteristic features of the radical polymerisation of water-soluble monomers // Russian Chemical Reviews. 1994. Vol. 63. No. 6. pp. 507-517.
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TY - JOUR
DO - 10.1070/RC1994v063n06ABEH000101
UR - https://rcr.colab.ws/publications/10.1070/RC1994v063n06ABEH000101
TI - Characteristic features of the radical polymerisation of water-soluble monomers
T2 - Russian Chemical Reviews
AU - Gromov, Vladimir Fedorovich
AU - Bune, Elena Viktorovna
AU - Teleshov, Eduard Nikanorovich
PY - 1994
DA - 1993/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 507-517
IS - 6
VL - 63
ER -
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@article{1994_Gromov,
author = {Vladimir Fedorovich Gromov and Elena Viktorovna Bune and Eduard Nikanorovich Teleshov},
title = {Characteristic features of the radical polymerisation of water-soluble monomers},
journal = {Russian Chemical Reviews},
year = {1994},
volume = {63},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1994v063n06ABEH000101},
number = {6},
pages = {507--517},
doi = {10.1070/RC1994v063n06ABEH000101}
}
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Gromov, Vladimir Fedorovich, et al. “Characteristic features of the radical polymerisation of water-soluble monomers.” Russian Chemical Reviews, vol. 63, no. 6, Nov. 1994, pp. 507-517. https://rcr.colab.ws/publications/10.1070/RC1994v063n06ABEH000101.
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Abstract

The results of studies on the influence of the nature of the solvent on the kinetics of the radical polymerisation of water-soluble monomers are surveyed. It is noted that the rate of the process and the chain propagation rate constant in the polymerisation of monomers of this kind change sharply on passing from organic solvents to aqueous solutions. Comparative analysis of the kinetic data and the results of spectroscopic and viscometric studies made it possible to put forward a mechanism for the polymerisation of water-soluble monomers in various solvents. A distinctive feature of the polymerisation of water-soluble monomers is the hydrophobic interactions arising in aqueous solutions of the polymers and leading to a sharp difference between the kinetic parameters of the polymerisation of monomers of this class in water and organic solvents. The bibliography includes 76 references.

References

1.
1
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1948
2.
2
A. A. Krasnovskii
Zhur. Fiz. Khim. , 1956
3.
3
M. F. Shostakovskii
"Prostye Vinilovye Efiry" (Vinyl Ethers) , 1952
4.
Über den Lösungsmitteleinfluß bei der Radikalpolymerisation. II
Henrici-Olivé V.G., Olivé S.
Die Makromolekulare Chemie , 1963
5.
Über den Lösungsmitteleinfluß bei der Radikalpolymerisation
Henrici-Olivé G., Olivé S.
Zeitschrift fur Physikalische Chemie , 1965
6.
Über den Lösungsmitteleinfluß bei der Radikalpolymerisation
Henrici-Olivé G., Olivé S.
Zeitschrift fur Physikalische Chemie , 1966
9.
10
T. A. Kryukova
"Polyaro-graficheskii Analiz" (Polarographic Analysis) , 1959
11.
12
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1950
12.
13
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1954
13.
Solvent effects on the free radical polymerization of styrene
Burnett G.M., Cameron G.G., Joiner S.N.
Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases , 1973
14.
Free radical polymerization in the presence of non‐solvents, 1. Styrene
Bartoň J., Capek I., Juraničová V., Mlynárová M.
Die Makromolekulare Chemie , 1980
16.
Solvent effect on radical polymerization of butyl acrylate
Kamachi M., Fujii M., Ninomiya S., Katsuki S., Nozakura S.
Journal of Polymer Science Polymer Chemistry Edition , 1982
17.
Solvent influence on the free‐radical polymerization of 1‐naphthyl and 2‐naphthyl methacrylate
Madruga E.L., Roman J.S.
Die Makromolekulare Chemie Rapid Communications , 1986
18.
19
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1959
20.
22
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1958
21.
23
N. V. Vostrilova
Dokl. Akad. Nauk Uzbek. SSR , 1958
23.
25
G. W. Robinson
J. Chem. Phys. , 1955
24.
26
B. Ya. Dain
1957
25.
27
A. A. Krasnovskii
Biofizika , 1956
26.
28
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1955
27.
29
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1951
28.
30
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1954
29.
31
A. A. Krasnovskii
Biokhimiya , 1960
30.
Effect of solvent on chain propagation and termination reaction rates in radical polymerization
Gromov V.F., Galperina N.I., Osmanov T.O., Khomikovskii P.M., Abkin A.D.
European Polymer Journal , 1980
31.
Effect of solvent on radical polymerization of vinyl benzoate
Kamachi M., Satoh J., Nozakura S.
Journal of Polymer Science Polymer Chemistry Edition , 1978
32.
Solvent Effect on Radical Polymerization of Vinyl Acetate
Kamachi M., Liaw D.J., Nozakura S.
Polymer Journal , 1979
33.
35
Z. K. Maizus
Dokl. Akad. Nauk SSSR , 1960
34.
36
J. Billon
Bull. Soc. chim. France , 1960
35.
37
L. M. Kosobutskaya
Dokl. Akad. Nauk SSSR , 1950
36.
38
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1956
37.
39
V. F. Gachkovskii
Biofizika , 1959
38.
40
A. A. Krasnovskii
Biofizika , 1960
39.
41
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1950
40.
42
L. K. Obukhova
Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1960
41.
43
N. Bunge
Ber. Deutsch. Chem. Ges. , 1870
42.
HYDROGEN BONDS AND π-COMPLEXES IN RADICAL LIQUID-PHASE REACTIONS
Buchachenko A.L., Sukhanova O.P.
Russian Chemical Reviews , 1967
43.
46
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1955
44.
47
G. Oster
"Research in Photosynthesis" , 1957
45.
48
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1955
46.
49
A. A. Krasnovskii
Biofizika , 1958
47.
50
G. Glacomello
Gazzetta. , 1935
48.
51
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1954
49.
52
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1957
50.
53
D. Porretand E. Rabinowitch
Nature , 1937
51.
Carbon-13 nuclear magnetic resonance spectroscopy IX—monosubstituted ethylenes
Miyajima G., Takahashi K., Nishimoto K.
Magnetic Resonance in Chemistry , 1974
52.
55
G. A. Bogdanovskii
1958
54.
57
R. Livingston
"Research in Photosynthesis" , 1957
55.
58
N. E. Khomutov
1953
56.
59
H. Linshitz
"Research in Photosynthesis" , 1957
57.
60
A. N. Terenin
Optika i Spektrosk. , 1956
58.
61
A. N. Terenin
1959
59.
62
A. A. Krasnovskii
"Sbornik, Voprosy Khimicheskoi Kinetiki" (Symposium, Problems of Chemical Kinetics) , 1955
60.
63
1930
61.
Radical polymerization of water-soluble monomers in various solvents
Gromov V.F., Bogachev Y.S., Bune Y.V., Zhuravleva I.L., Teleshov E.N.
European Polymer Journal , 1991
62.
65
A. A. Krasnovskii
Biofizika , 1959
63.
Radical polymerization of diethylaminoethyl methacrylate and its salts in various solvents
Bune Y.V., Sheinker A.P., Bogachev Y.S., Zhuravleva I.L., Teleshov E.N.
European Polymer Journal , 1991
64.
67
N. N. Mel'nikov
Zhur. Obshch. Khim. , 1940
65.
68
N. N. Mel'nikov
Zhur. Obshch. Khim. , 1946
68.
71
Yu. A. Shlyapnikov
Vysokomol. Soed. , 1962
69.
Water-soluble copolymers. 30. Effects of molecular structure on drag reduction efficiency
McCormick C.L., Hester R.D., Morgan S.E., Safieddine A.M.
Macromolecules , 1990
78.
81
J. C. Ghosh
J. Indian Chem. Soc. , 1934
79.
Physicochemical Foundations of Micellar Catalysis
Berezin I.V., Martinek K., Yatsimirskii A.K.
Russian Chemical Reviews , 1973
80.
Consolvency of poly(N-isopropylacrylamide) in mixed water-methanol solutions: a look at spin-labeled polymers
Winnik F.M., Ottaviani M.F., Bossmann S.H., Garcia-Garibay M., Turro N.J.
Macromolecules , 1992
82.
85
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1947
83.
86
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1958