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Intermediates and mechanisms of the heterogeneous catalytic reactions. The simplest reactions of hydrocarbons, alcohols, and acids

Oleg Valentinovich Krylov 1
Oleg Valentinovich Krylov
, 
Valery Andreevich Matyshak 1
Valery Andreevich Matyshak
1 N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow
10.1070/RC1994v063n07ABEH000105
Published 30 November 1993
Communication , Volume 63, Issue 7, 559-574
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Krylov O. V., Matyshak V. A. Intermediates and mechanisms of the heterogeneous catalytic reactions. The simplest reactions of hydrocarbons, alcohols, and acids // Russian Chemical Reviews. 1994. Vol. 63. No. 7. pp. 559-574.
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Krylov O. V., Matyshak V. A. Intermediates and mechanisms of the heterogeneous catalytic reactions. The simplest reactions of hydrocarbons, alcohols, and acids // Russian Chemical Reviews. 1994. Vol. 63. No. 7. pp. 559-574.
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TY - JOUR
DO - 10.1070/RC1994v063n07ABEH000105
UR - https://rcr.colab.ws/publications/10.1070/RC1994v063n07ABEH000105
TI - Intermediates and mechanisms of the heterogeneous catalytic reactions. The simplest reactions of hydrocarbons, alcohols, and acids
T2 - Russian Chemical Reviews
AU - Krylov, Oleg Valentinovich
AU - Matyshak, Valery Andreevich
PY - 1994
DA - 1993/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 559-574
IS - 7
VL - 63
ER -
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@article{1994_Krylov,
author = {Oleg Valentinovich Krylov and Valery Andreevich Matyshak},
title = {Intermediates and mechanisms of the heterogeneous catalytic reactions. The simplest reactions of hydrocarbons, alcohols, and acids},
journal = {Russian Chemical Reviews},
year = {1994},
volume = {63},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1994v063n07ABEH000105},
number = {7},
pages = {559--574},
doi = {10.1070/RC1994v063n07ABEH000105}
}
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Krylov, Oleg Valentinovich, and Valery Andreevich Matyshak. “Intermediates and mechanisms of the heterogeneous catalytic reactions. The simplest reactions of hydrocarbons, alcohols, and acids.” Russian Chemical Reviews, vol. 63, no. 7, Nov. 1994, pp. 559-574. https://rcr.colab.ws/publications/10.1070/RC1994v063n07ABEH000105.
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Abstract

The structures of the intermediate surface compounds in heterogeneous-catalytic reactions of hydrocarbons, alcohols, and acids, established by spectroscopic (mainly IR spectroscopic) measurements, are examined. The evidence obtained concerning the role of particular structures in catalysis is differentiated: from spectroscopic data obtained before or after catalysis; from spectroscopic data obtained in situ but without kinetic measurements; from spectroscopic data obtained in situ by comparing the kinetics of the heterogeneous-catalytic reactions with the kinetics of the changes in the concentrations of the surface compounds. The mechanisms of heterogeneous catalytic reactions obtained on the basis of the available information about the surface complexes are presented. The bibliography includes 89 references.

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