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Trivalent phosphorus acids amides as phosphorylating agents for alcohols and amines

Eduard Evgen'evich Nifantyev 1
Eduard Evgen'evich Nifantyev
, 
Mikhail Konstantinovich Grachev 1
Mikhail Konstantinovich Grachev
1 Department of Chemistry, Moscow State Pedagogical University
10.1070/RC1994v063n07ABEH000106
Published 30 November 1993
Communication , Volume 63, Issue 7, 575-609
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Nifantyev E. E., Grachev M. K. Trivalent phosphorus acids amides as phosphorylating agents for alcohols and amines // Russian Chemical Reviews. 1994. Vol. 63. No. 7. pp. 575-609.
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Nifantyev E. E., Grachev M. K. Trivalent phosphorus acids amides as phosphorylating agents for alcohols and amines // Russian Chemical Reviews. 1994. Vol. 63. No. 7. pp. 575-609.
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TY - JOUR
DO - 10.1070/RC1994v063n07ABEH000106
UR - https://rcr.colab.ws/publications/10.1070/RC1994v063n07ABEH000106
TI - Trivalent phosphorus acids amides as phosphorylating agents for alcohols and amines
T2 - Russian Chemical Reviews
AU - Nifantyev, Eduard Evgen'evich
AU - Grachev, Mikhail Konstantinovich
PY - 1994
DA - 1993/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 575-609
IS - 7
VL - 63
ER -
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@article{1994_Nifantyev,
author = {Eduard Evgen'evich Nifantyev and Mikhail Konstantinovich Grachev},
title = {Trivalent phosphorus acids amides as phosphorylating agents for alcohols and amines},
journal = {Russian Chemical Reviews},
year = {1994},
volume = {63},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1994v063n07ABEH000106},
number = {7},
pages = {575--609},
doi = {10.1070/RC1994v063n07ABEH000106}
}
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Nifantyev, Eduard Evgen'evich, and Mikhail Konstantinovich Grachev. “Trivalent phosphorus acids amides as phosphorylating agents for alcohols and amines.” Russian Chemical Reviews, vol. 63, no. 7, Nov. 1994, pp. 575-609. https://rcr.colab.ws/publications/10.1070/RC1994v063n07ABEH000106.
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Abstract

The principal results of studies on trivalent phosphorus acid amides (TPAA) as phosphorylating agents for alcohols, phenols, and amines are summarised and discussed. Problems concerning the catalysis and mechanism of the phosphorylation of proton-donating nucleophiles by TPAA are considered and new possibilities for the development of investigations on these lines are analysed. The preparative advantages of TPAA and the specific prospects for their use in fine organic synthesis and macromolecular chemistry are demonstrated. The bibliography includes 560 references.

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