Home / Articles / Organoelement derivatives of 2-pyrone and their applications in organic synthesis

Organoelement derivatives of 2-pyrone and their applications in organic synthesis

Valery Nikolaevich Kalinin 1
Valery Nikolaevich Kalinin
, 
Olga Sergeevna Shilova 1
Olga Sergeevna Shilova
1 A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow
Published 30 November 1993
Communication , Volume 63, Issue 8, 661-666
8
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Kalinin V. N., Shilova O. S. Organoelement derivatives of 2-pyrone and their applications in organic synthesis // Russian Chemical Reviews. 1994. Vol. 63. No. 8. pp. 661-666.
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Kalinin V. N., Shilova O. S. Organoelement derivatives of 2-pyrone and their applications in organic synthesis // Russian Chemical Reviews. 1994. Vol. 63. No. 8. pp. 661-666.
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TY - JOUR
DO - 10.1070/RC1994v063n08ABEH000110
UR - https://rcr.colab.ws/publications/10.1070/RC1994v063n08ABEH000110
TI - Organoelement derivatives of 2-pyrone and their applications in organic synthesis
T2 - Russian Chemical Reviews
AU - Kalinin, Valery Nikolaevich
AU - Shilova, Olga Sergeevna
PY - 1994
DA - 1993/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 661-666
IS - 8
VL - 63
ER -
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@article{1994_Kalinin,
author = {Valery Nikolaevich Kalinin and Olga Sergeevna Shilova},
title = {Organoelement derivatives of 2-pyrone and their applications in organic synthesis},
journal = {Russian Chemical Reviews},
year = {1994},
volume = {63},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1994v063n08ABEH000110},
number = {8},
pages = {661--666},
doi = {10.1070/RC1994v063n08ABEH000110}
}
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Kalinin, Valery Nikolaevich, and Olga Sergeevna Shilova. “Organoelement derivatives of 2-pyrone and their applications in organic synthesis.” Russian Chemical Reviews, vol. 63, no. 8, Nov. 1994, pp. 661-666. https://rcr.colab.ws/publications/10.1070/RC1994v063n08ABEH000110.
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Abstract

The methods of synthesis and properties of organometallic (Li, Cu) and organoelement (Si, N, S) σ-derivatives and η4-iron tricarbonyl complexes of 2-pyrone are considered. The Diels–Alder reactions of the organoelement derivatives of 2-pyrone with dienophyles take place stereoselectively and under mild conditions, which opens new pathways to the specific synthesis of polyfunctional cyclohexenes and cyclohexadienes. The bibliography includes 40 references.

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