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Kinetic nonuniformity in radical polymerisation processes

Sergei Stepanovich Ivanchev 1
Sergei Stepanovich Ivanchev
, 
Valerii Nikolaevich Pavlyuchenko 1
Valerii Nikolaevich Pavlyuchenko
1 "Plastpolymer" Joint Stock Company, St. Petersburg
10.1070/RC1994v063n08ABEH000111
Published 30 November 1993
Communication , Volume 63, Issue 8, 667-684
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Ivanchev S. S., Pavlyuchenko V. N. Kinetic nonuniformity in radical polymerisation processes // Russian Chemical Reviews. 1994. Vol. 63. No. 8. pp. 667-684.
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Ivanchev S. S., Pavlyuchenko V. N. Kinetic nonuniformity in radical polymerisation processes // Russian Chemical Reviews. 1994. Vol. 63. No. 8. pp. 667-684.
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TY - JOUR
DO - 10.1070/RC1994v063n08ABEH000111
UR - https://rcr.colab.ws/publications/10.1070/RC1994v063n08ABEH000111
TI - Kinetic nonuniformity in radical polymerisation processes
T2 - Russian Chemical Reviews
AU - Ivanchev, Sergei Stepanovich
AU - Pavlyuchenko, Valerii Nikolaevich
PY - 1994
DA - 1993/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 667-684
IS - 8
VL - 63
ER -
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@article{1994_Ivanchev,
author = {Sergei Stepanovich Ivanchev and Valerii Nikolaevich Pavlyuchenko},
title = {Kinetic nonuniformity in radical polymerisation processes},
journal = {Russian Chemical Reviews},
year = {1994},
volume = {63},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1994v063n08ABEH000111},
number = {8},
pages = {667--684},
doi = {10.1070/RC1994v063n08ABEH000111}
}
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Ivanchev, Sergei Stepanovich, and Valerii Nikolaevich Pavlyuchenko. “Kinetic nonuniformity in radical polymerisation processes.” Russian Chemical Reviews, vol. 63, no. 8, Nov. 1994, pp. 667-684. https://rcr.colab.ws/publications/10.1070/RC1994v063n08ABEH000111.
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Abstract

The characteristic features of radical polymerisation in homogeneous and heterogeneous systems are considered from the standpoint of the kinetics nonuniformity of the elementary reactions. The kinetic nonuniformity is due to the variation of the properties of the reaction system during the process and to the appearance of kinetically nonequivalent zones for certain critical conversions. The kinetic nonuniformity in heterogeneous systems in examined in relation to emulsion polymerisation and polymerisation in the presence of a solid dispersed phase. It is shown that the specific formation in the reaction systems of kinetically nonuniform zones makes it possible to control effectively the polymerisation process and the properties of the polymers formed. The bibliography includes 143 references.

References

1.
1
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1948
2.
2
A. A. Krasnovskii
Zhur. Fiz. Khim. , 1956
3.
3
M. F. Shostakovskii
"Prostye Vinilovye Efiry" (Vinyl Ethers) , 1952
4.
4
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1949
5.
5
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1953
6.
6
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1953
7.
7
E. Rabinowitch
"Photosynthesis" , 1956
8.
8
V. N. Kondrat'ev
"Kinetika Reaktsii v Gazovoi Faze" (Kinetics of Reactions in the Gas Phase) , 1959
9.
9
V. H. Lynch
Carnegie Inst. Year Book , 1954
10.
10
T. A. Kryukova
"Polyaro-graficheskii Analiz" (Polarographic Analysis) , 1959
11.
Diffusion‐controlled vinyl polymerization. I. The gel effect
Soh S.K., Sundberg D.C.
Journal of Polymer Science Polymer Chemistry Edition , 1982
12.
12
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1950
13.
13
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1954
14.
14
V. B. Evstigneev
Zhur. Fiz. Khim. , 1958
15.
Nature of gel effect in radical polymerization
Lachinov M.B., Simonian R.A., Georgieva T.G., Zubov V.P., Kabanov V.A.
Journal of Polymer Science Polymer Chemistry Edition , 1979
17.
17
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1958
18.
18
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1951
19.
On the onset of the Trommsdorff effect
Tulig T.J., Tirrell M.
Macromolecules , 1982
20.
Consistent values of rate parameters in free radical polymerization systems
Buback M., Garcia-Rubio L.H., Gilbert R.G., Napper D.H., Guillot J., Hamielec A.E., Hill D., O'Driscoll K.F., Olaj O.F., Shen J., Solomon D., Moad G., Stickler M., Tirrell M., Winnik M.A., et. al.
Journal of Polymer Science Part C Polymer Letters , 1988
21.
Consistent values of rate parameters in free radical polymerization systems. II. Outstanding dilemmas and recommendations
Buback M., Gilbert R.G., Russell G.T., Hill D.J., Moad G., O'Driscoll K.F., Shen J., Winnik M.A.
Journal of Polymer Science, Part A: Polymer Chemistry , 1992
22.
22
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1958
24.
24
M. S. Ashkinazi
Dokl. Akad. Nauk SSSR , 1951
25.
25
G. W. Robinson
J. Chem. Phys. , 1955
26.
26
B. Ya. Dain
1957
27.
27
A. A. Krasnovskii
Biofizika , 1956
28.
28
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1955
29.
29
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1951
30.
Structures and compositions of copolymers
Harwood H.J.
Makromolekulare Chemie Macromolecular Symposia , 1987
31.
31
A. A. Krasnovskii
Biokhimiya , 1960
33.
34
G. W. Robinson
J. Chem. Phys. , 1886
34.
35
Z. K. Maizus
Dokl. Akad. Nauk SSSR , 1960
35.
36
J. Billon
Bull. Soc. chim. France , 1960
36.
Solvent influence on the free‐radical polymerization of 1‐naphthyl and 2‐naphthyl methacrylate
Madruga E.L., Roman J.S.
Die Makromolekulare Chemie Rapid Communications , 1986
37.
38
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1956
38.
39
V. F. Gachkovskii
Biofizika , 1959
39.
40
A. A. Krasnovskii
Biofizika , 1960
40.
41
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1950
41.
42
L. K. Obukhova
Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1960
42.
43
N. Bunge
Ber. Deutsch. Chem. Ges. , 1870
43.
44
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1953
44.
45
W. Hendrich
Roczniki Chemii , 1958
45.
46
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1955
47.
49
A. A. Krasnovskii
Biofizika , 1958
48.
A General Theory of the Mechanism of Emulsion Polymerization1
Harkins W.D.
Journal of the American Chemical Society , 1947
49.
51
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1954
50.
52
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1957
51.
SURFACE CHEMISTRY ASPECTS OF EMULSION POLYMERIZATION
Roe C.P.
Industrial & Engineering Chemistry , 1968
53.
Kinetics and Mechanism of Styrene Microemulsion Polymerization
Guo J.S., Sudol E.D., Vanderhoff J.W., El-Aasser M.S.
ACS Symposium Series , 1992
54.
Kinetics and Mechanism of Emulsion Polymerization
Hansen F.K., Ugelstad J.
Rubber Chemistry and Technology , 1976
55.
57
R. Livingston
"Research in Photosynthesis" , 1957
56.
Swelling of latex particles
Morton M., Kaizerman S., Altier M.W.
Journal of Colloid Science , 1954
58.
Note on the kinetics of emulsion polymerization
Stockmayer W.H.
Journal of Polymer Science , 1957
59.
Emulsion polymerization of styrene: Nucleation studies with nonionic emulsifier
Piirma I., Chang M.
Journal of Polymer Science Polymer Chemistry Edition , 1982
60.
Emulsion polymerization of styrene in the presence of poly(oxyethylene)‐poly(oxypropylene) block copolymers
Hergeth W., Bloß P., Biedenweg F., Abendroth P., Schmutzler K., Wartewig S.
Die Makromolekulare Chemie , 1990
62.
Non-seeded semi-continuous emulsion polymerization
Šňupárek J., Skoupil J., Podzimek Š., Kaštánek A.
Makromolekulare Chemie Macromolecular Symposia , 1990
63.
65
A. A. Krasnovskii
Biofizika , 1959
64.
66
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1950
65.
Partitioned polymerization, 1. Transfer of initiator and/or monomer
Bartoň J., Juraničová V., Hloušková Z.
Die Makromolekulare Chemie , 1988
66.
On the initiation mechanism in emulsion polymerization systems
Bartoň J.
Makromolekulare Chemie Macromolecular Symposia , 1990
67.
Establishing mechanisms for emulsion polymerizations
Casey B.S., Maxwell I.A., Morrison B.R., Gilbert R.G.
Makromolekulare Chemie Macromolecular Symposia , 1990
68.
Testing Nucleation Models for Emulsion-Polymerization Systems
Morrison B.R., Maxwell I.A., Gilbert R.G., Napper D.H.
ACS Symposium Series , 1992
70.
Kinetic features and mechanism of emulsion polymerization
Pavljučenko V.N., Ivančev S.S.
Acta Polymerica , 1983
71.
73
T. Skwarski
Chem. Abs. , 1957
72.
74
F. F. Litvin
Uspekhi Fiz. Nauk , 1960
73.
Miniemulsion Polymerization
Tang P.L., Sudol E.D., Adams M.E., Silebi C.A., El-Aasser M.S.
ACS Symposium Series , 1992
74.
76
A. N. Terenin
"Fotokhimiya Krasitelei" (The Photochemistry of Dyes) , 1947
75.
77
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1948
76.
78
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1949
77.
Kinetic and thermodynamic aspects of miniemulsion copolymerization
Delgado J., El-Aasser M.S.
Makromolekulare Chemie Macromolecular Symposia , 1990
78.
80
N. N. Mel'nikov
Zhur. Obshch. Khim. , 1937
79.
81
J. C. Ghosh
J. Indian Chem. Soc. , 1934
80.
Influence of monomer preemulsification on formation of particles from monomer drops in emulsion polymerization
Durbin D.P., El-Aasser M.S., Poehlein G.W., Vanderhoff J.W.
Journal of Applied Polymer Science , 1979
81.
Preparation of Particles for Microvoid Coatings by Seeded Emulsion Polymerization
Vanderhoff J.W., Park J.M., El-Aasser M.S.
ACS Symposium Series , 1992
82.
84
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1947
83.
85
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1947
85.
87
J. F. Arens
"Advances in Organic Chemistry" , 1960
86.
Elementary reactions of the emulsions polymerization of styrene with the localization of radical formation acts at the interface
Ivanchev S.S., Pavljuchenko V.N., Byrdina N.A.
Journal of Polymer Science, Part A: Polymer Chemistry , 1987
87.
Emulsion polymerization in the presence of polymerizable emulsifiers and surface active initiators
Tauer K., Goebel K., Kosmella S., Stähler K., Neelsen J.
Makromolekulare Chemie Macromolecular Symposia , 1990
88.
Kinetics of particle growth in emulsion polymerization systems with surface-active initiators
Kusters J.M., Napper D.H., Gilbert R.G., German A.L.
Macromolecules , 1992
90.
92
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1948
91.
93
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1956
92.
94
A. A. Krasnovskii
Fiziologiya Rastenii , 1957
93.
The decomposition of potassium persulphate used as initiator in emulsion polymerization
Okubo M., Mori T.
Makromolekulare Chemie Macromolecular Symposia , 1990
94.
Emulsion polymerization of vinyl chloride, 2 potassium persulfats decomposition in the presence of PVC latex
Georgescu C., Sarbu A., Butucea V.
Makromolekulare Chemie Macromolecular Symposia , 1991
95.
Kinetics of emulsion polymerization of methyl methacrylate
Ballard M.J., Napper D.H., Gilbert R.G.
Journal of Polymer Science Polymer Chemistry Edition , 1984
96.
Radical capture efficiencies in emulsion polymerization
Hawkett B.S., Napper D.H., Gilbert R.G.
Journal of Polymer Science Polymer Chemistry Edition , 1981
97.
Kinetics of the surfactant-free emulsion polymerization of styrene:-The post nucleation stage
Hearn J., Wilkinson M.C., Goodall A.R., Chainey M.
Journal of Polymer Science Polymer Chemistry Edition , 1985
99.
Characterization of water‐soluble oligomers formed during the emulsion polymerization of styrene by means of isotachophoresis
Morrison B.R., Maxwell I.A., Napper D.H., Gilbert R.G., Ammerdorffer J.L., German A.L.
Journal of Polymer Science, Part A: Polymer Chemistry , 1993
100.
Propagation rate coefficients from electron spin resonance studies of the emulsion polymerization of methyl methacrylate
Ballard M.J., Gilbert R.G., Napper D.H., Pomery P.J., O'Sullivan P.W., O'Donnell J.H.
Macromolecules , 1986
101.
103
L. N. Bell
Dokl. Akad. Nauk SSSR , 1956
102.
104
O. P. Osipova
Dokl. Akad. Nauk SSSR , 1950
103.
105
F. F. Litvin
Dokl. Akad. Nauk SSSR , 1958
105.
The morphology of the monomer–polymer particle in styrene emulsion polymerization
Grancio M.R., Williams D.J.
Journal of Polymer Science Part A-1 Polymer Chemistry , 1970
106.
Particle morphology in emulsion polymerization
Williams D.J.
Journal of Polymer Science Polymer Chemistry Edition , 1973
107.
KINETICS OF SEEDED EMULSION POLYMERIZATION OF STYRENE UNDER BATCH AND CONTINUOUS MONOMER ADDITION CONDITIONS
Kao C., Lee D.I., Stevens E.F.
Journal of Dispersion Science and Technology , 1984
108.
The characterization of latex particle surfaces by ion exchange and conductometric titration
Van Den Hul H.J., Vanderhoff J.W.
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry , 1972
109.
Characterization of surface endgroups in polystrene latexes
Jayasuriya R.M., El-Aasser M.S., Vanderhoff J.W., Yue H.J.
Journal of Polymer Science Polymer Chemistry Edition , 1985
110.
Polymerization in nonuniform latex particles: Distribution of free radicals
Chern C., Poehlein G.W.
Journal of Polymer Science, Part A: Polymer Chemistry , 1987
112.
Control of Core—Shell Latex Morphology
Lee S., Rudin A.
ACS Symposium Series , 1992
113.
Nucleation of Emulsion Polymerization in the Presence of Small Silica Particles
Espiard P., Revillon A., Guyot A., Mark J.E.
ACS Symposium Series , 1992
114.
Kinetics of (CO)polymerizations at the surface of inorganic submicron particles in emulsion-like systems
Caris C.H., Kuijpers R.P., van Herk A.M., German A.L.
Makromolekulare Chemie Macromolecular Symposia , 1990
115.
Production of Multihollow Polymer Particles by Stepwise Alkali—Acid Method
Okubo M., Ichikawa K., Fujimura M.
ACS Symposium Series , 1992
116.
Preparation and characterization of core-shell latexes
Hergeth W., Schmutzler K., Wartewig S.
Makromolekulare Chemie Macromolecular Symposia , 1990
118.
Rupture of anomalous composite particles prepared by seeded emulsion polymerization in aging period
Okubo M., Katsuta Y., Matsumoto T.
Journal of Polymer Science Part C Polymer Letters , 1980
119.
Morphology development of polymeric microparticles in aqueous dispersions. I. Thermodynamic considerations
Sundberg D.C., Casassa A.P., Pantazopoulos J., Muscato M.R., Kronberg B., Berg J.
Journal of Applied Polymer Science , 1990
120.
Morphology development for three‐component emulsion polymers: Theory and experiments
Sundberg E.J., Sundberg D.C.
Journal of Applied Polymer Science , 1993
122.
Supermicron poly(butyl acrylate)/polystyrene core-shell latexes
Cook D.G., Rudin A., Plumtree A.
Journal of Applied Polymer Science , 1992
123.
Synthesis of core-shell latexes by redox initiation at ambient temperatures
Lee S., Rudin A.
Journal of Polymer Science, Part A: Polymer Chemistry , 1992
124.
Kinetics of living radical polymerization of styrene with macromolecular initiator
Mikulášová D., Chrástová V., Citovický P., Horie K.
Die Makromolekulare Chemie , 1977
125.
129
J. Wiemann
Bull. Soc. chim. France , 1955
126.
130
J. Wiemann
Bull. Soc. chim. France , 1958
127.
131
N. Thooi
Compt. rend. , 1958
128.
132
G. Shima
Kyoto Univ. , 1929
129.
133
C. Wilson
Trans. Electrochem. Soc. , 1941
130.
134
V. V. Korshak
Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1948
131.
135
V. V. Korshak
Dokl. Akad. Nauk SSSR , 1945
132.
136
V. V. Korshak
Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1954
133.
137
S. R. Rafikov
Zh. Obshch. Khim. , 1944
134.
138
S. Ono
J. Chem. Soc. Japan , 1957
135.
139
I. L. Knunyants
1959
136.
140
1912
137.
141
Friedl.
138.
142
1913
139.
143
Friedl.
140.
144
1912
141.
145
Friedl.
142.
Polymer—inorganic selective adsorbents for gas chromatography produced by graft polymerization
Dmitrenko A.V., Shadrina N.E., Ivanchev S.S., Ulinskaya N.N., Volkov A.M.
Journal of Chromatography A , 1990
143.
147
Y. Sasada
Acta Cryst. , 1898
144.
148
P. Kresse
Chem. Abs. , 1960
145.
149
V. V. Korshak
Dokl. Akad. Nauk SSSR , 1954
146.
150
Ya. E. Bernadskaya
"Iskusstvennoe Volokno" (Artificial Fibres) , 1952
147.
151
V. M. Rodionov
Zhur. Obshch. Khim. , 1936
148.
152
W. Albert
Trans. Electrochem. Soc. , 1943
149.
Effects of diffusion control on the propagation and transfer rate coefficients in free radical polymerization
Casey B.S., Mills M.F., Sangster D.F., Gilbert R.G., Napper D.H.
Macromolecules , 1992
150.
Modeling of termination in intermediate and high conversion free radical polymerizations
Buback M., Huckestein B., Russell G.T.
Macromolecular Chemistry and Physics , 1994