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Skeletal and polycyclic sterically hindered alkenes

Berta Moiseevna Lerman 1
Berta Moiseevna Lerman
1 Institute of Organic Chemistry, Ufa Scientific Centre of RAS
10.1070/RC1995v064n01ABEH000134
Published 30 November 1994
Communication , Volume 64, Issue 1, 1-24
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Lerman B. M. Skeletal and polycyclic sterically hindered alkenes // Russian Chemical Reviews. 1995. Vol. 64. No. 1. pp. 1-24.
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Lerman B. M. Skeletal and polycyclic sterically hindered alkenes // Russian Chemical Reviews. 1995. Vol. 64. No. 1. pp. 1-24.
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TY - JOUR
DO - 10.1070/RC1995v064n01ABEH000134
UR - https://rcr.colab.ws/publications/10.1070/RC1995v064n01ABEH000134
TI - Skeletal and polycyclic sterically hindered alkenes
T2 - Russian Chemical Reviews
AU - Lerman, Berta Moiseevna
PY - 1995
DA - 1994/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1-24
IS - 1
VL - 64
ER -
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@article{1995_Lerman,
author = {Berta Moiseevna Lerman},
title = {Skeletal and polycyclic sterically hindered alkenes},
journal = {Russian Chemical Reviews},
year = {1995},
volume = {64},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1995v064n01ABEH000134},
number = {1},
pages = {1--24},
doi = {10.1070/RC1995v064n01ABEH000134}
}
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Lerman, Berta Moiseevna. “Skeletal and polycyclic sterically hindered alkenes.” Russian Chemical Reviews, vol. 64, no. 1, Nov. 1995, pp. 1-24. https://rcr.colab.ws/publications/10.1070/RC1995v064n01ABEH000134.
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Abstract

Data on the chemistry of strained tetrasubstituted alkenes with skeletal and polycyclic fragments are surveyed. A systematic account is given of information concerning the methods of their synthesis and data presented on the deformation of their molecular geometry relative to the usual geometry. The characterictic features of the reactivity of skeletal compounds of this type are considered – the formation of unusual adducts and substitution products in reactions with electrophiles. The oxidation reactions of the alkenes are discussed and their value as starting materials for the synthesis of stable dioxetanes, which have found practical application as chemiluminescent labels and probes in immunology and molecular biology, is demonstrated. The bibliography includes 152 references.

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