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Silicon-containing alka-1,3-dienes and their functional derivatives in organic synthesis

Miroslav Dmitrovich Stadnichuk 1
Miroslav Dmitrovich Stadnichuk
, 
T I Voropaeva 1
T I Voropaeva
1 State Technological Institute of St. Petersburg
10.1070/RC1995v064n01ABEH000135
Published 30 November 1994
Communication , Volume 64, Issue 1, 25-46
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Stadnichuk M. D., Voropaeva T. I. Silicon-containing alka-1,3-dienes and their functional derivatives in organic synthesis // Russian Chemical Reviews. 1995. Vol. 64. No. 1. pp. 25-46.
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Stadnichuk M. D., Voropaeva T. I. Silicon-containing alka-1,3-dienes and their functional derivatives in organic synthesis // Russian Chemical Reviews. 1995. Vol. 64. No. 1. pp. 25-46.
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TY - JOUR
DO - 10.1070/RC1995v064n01ABEH000135
UR - https://rcr.colab.ws/publications/10.1070/RC1995v064n01ABEH000135
TI - Silicon-containing alka-1,3-dienes and their functional derivatives in organic synthesis
T2 - Russian Chemical Reviews
AU - Stadnichuk, Miroslav Dmitrovich
AU - Voropaeva, T I
PY - 1995
DA - 1994/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 25-46
IS - 1
VL - 64
ER -
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@article{1995_Stadnichuk,
author = {Miroslav Dmitrovich Stadnichuk and T I Voropaeva},
title = {Silicon-containing alka-1,3-dienes and their functional derivatives in organic synthesis},
journal = {Russian Chemical Reviews},
year = {1995},
volume = {64},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1995v064n01ABEH000135},
number = {1},
pages = {25--46},
doi = {10.1070/RC1995v064n01ABEH000135}
}
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Stadnichuk, Miroslav Dmitrovich, and T I Voropaeva. “Silicon-containing alka-1,3-dienes and their functional derivatives in organic synthesis.” Russian Chemical Reviews, vol. 64, no. 1, Nov. 1995, pp. 25-46. https://rcr.colab.ws/publications/10.1070/RC1995v064n01ABEH000135.
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Abstract

Data on the synthesis and chemical reactions of silicon-containing 1,3-dienes are surveyed for the first time in the present review. It is shown that the addition reactions of 1- and 2-triorganosilylalka-1,3-dienes and their derivatives are the most interesting and promising in fine organic synthesis. The application of the trialkylsilyl group as a protecting group and as a new reaction centre, which makes it possible to obtain carbon–carbon or carbon–heteroatom bonds, is examined. It has been found that the double bonds remote from the silicon atom are the most reactive in addition reactions and that regardless of the nature of the reagent the attacking species always binds to the terminal carbon atom of the buta-1,3-diene fragment. The bibliography includes 329 references.

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