Home / Articles / Intermediates and mechanisms of heterogeneous catalytic reactions. Reactions involing hydrogen and the monoxides of carbon and nitrogen

Intermediates and mechanisms of heterogeneous catalytic reactions. Reactions involing hydrogen and the monoxides of carbon and nitrogen

Oleg Valentinovich Krylov 1
Oleg Valentinovich Krylov
, 
Valery Andreevich Matyshak 1
Valery Andreevich Matyshak
1 N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow
10.1070/RC1995v064n01ABEH000137
Published 30 November 1994
Communication , Volume 64, Issue 1, 61-86
7
Share
Cite this
GOST
 | 
Cite this
GOST
Copy cite
Krylov O. V., Matyshak V. A. Intermediates and mechanisms of heterogeneous catalytic reactions. Reactions involing hydrogen and the monoxides of carbon and nitrogen // Russian Chemical Reviews. 1995. Vol. 64. No. 1. pp. 61-86.
GOST all authors (up to 50)
Copy cite
Krylov O. V., Matyshak V. A. Intermediates and mechanisms of heterogeneous catalytic reactions. Reactions involing hydrogen and the monoxides of carbon and nitrogen // Russian Chemical Reviews. 1995. Vol. 64. No. 1. pp. 61-86.
RIS
 | 
Cite this
RIS
Copy cite
TY - JOUR
DO - 10.1070/RC1995v064n01ABEH000137
UR - https://rcr.colab.ws/publications/10.1070/RC1995v064n01ABEH000137
TI - Intermediates and mechanisms of heterogeneous catalytic reactions. Reactions involing hydrogen and the monoxides of carbon and nitrogen
T2 - Russian Chemical Reviews
AU - Krylov, Oleg Valentinovich
AU - Matyshak, Valery Andreevich
PY - 1995
DA - 1994/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 61-86
IS - 1
VL - 64
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors)
Copy cite
@article{1995_Krylov,
author = {Oleg Valentinovich Krylov and Valery Andreevich Matyshak},
title = {Intermediates and mechanisms of heterogeneous catalytic reactions. Reactions involing hydrogen and the monoxides of carbon and nitrogen},
journal = {Russian Chemical Reviews},
year = {1995},
volume = {64},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1995v064n01ABEH000137},
number = {1},
pages = {61--86},
doi = {10.1070/RC1995v064n01ABEH000137}
}
MLA
Cite this
MLA
Copy cite
Krylov, Oleg Valentinovich, and Valery Andreevich Matyshak. “Intermediates and mechanisms of heterogeneous catalytic reactions. Reactions involing hydrogen and the monoxides of carbon and nitrogen.” Russian Chemical Reviews, vol. 64, no. 1, Nov. 1995, pp. 61-86. https://rcr.colab.ws/publications/10.1070/RC1995v064n01ABEH000137.
Views / Visits / Downloads
16 / 16 / 9

Abstract

The structure of intermediate surface compounds in heterogeneous catalytic reactions involving H2, CO, and NO is discussed. The relative reliability of the role of various structures in catalysis is discussed. Schemes for the reaction mechanism which have been developed from information on the surface complexes are described. The bibliography includes 248 references.

References

2.
Infrared studies of isotope effects for hydrogen adsorption on zinc oxide
Kokes R.J., Dent A.L., Chang C.C., Dixon L.T.
Journal of the American Chemical Society , 1972
3.
Butene isomerization over zinc oxide and chromia
Chang C.C., Conner W.C., Kokes R.J.
The Journal of Physical Chemistry , 1973
4.
Hydrogenation and Isomerization over Zinc Oxide
Kokes R.J., Dent A.L.
Advances in Catalysis , 1972
5.
Hydrogenation of ethylene by zinc oxide. I. Role of slow hydrogen chemisorption
Dent A.L., Kokes R.J.
The Journal of Physical Chemistry , 1969
6.
Hydrogenation of ethylene by zinc oxide. II. Mechanism and active sites
Dent A.L., Kokes R.J.
The Journal of Physical Chemistry , 1969
7.
Intermediates in ethylene hydrogenation over zinc oxide
Dent A.L., Kokes R.J.
The Journal of Physical Chemistry , 1970
8.
Behaviour of chemisorbed hydrogen under reaction conditions and the mechanism of the H2—D2exchange reaction over zinc oxide
Naito S., Shimizu H., Hagiwara E., Onishi T., Tamaru K.
Transactions of the Faraday Society , 1971
9.
Reaction mechanism of unsaturated hydrocarbons with deuterium over zinc oxide
Naito S., Sakurai Y., Shimizu H., Onishi T., Tamaru K.
Transactions of the Faraday Society , 1971
11.
Infrared studies of ethene hydrogenation over ZrO2. Part 3.—Reaction mechanism
Kondo J., Domen K., Maruya K., Onishi T.
Journal of the Chemical Society Faraday Transactions , 1992
12.
Adsorption and reactions of ethyne. Effects of modifiers and formation of bimetallics
Sassen N.R., den Hartog A.J., Jongerius F., Aarts J.F., Ponec V.
Faraday Discussions of the Chemical Society , 1989
13.
Generation of alkyl fragments on Rh/SiO2 and VO x -promoted Rh/SiO2
Trunschke A., Knözinger H.
Catalysis Letters , 1993
14.
Identification, by infra-red spectroscopy, of surface species during propyne hydrogenation
Jackson S.D., Casey N.J.
Reaction Kinetics and Catalysis Letters , 1993
18.
An Infrared Study of the Dehydrogenation of Ethylbenzene to Styrene over Iron-Based Catalysts
Addiego W.P., Estrada C.A., Goodman D.W., Rosynek M.P.
Journal of Catalysis , 1994
19.
20
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1954
21.
22
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1958
22.
23
N. V. Vostrilova
Dokl. Akad. Nauk Uzbek. SSR , 1958
23.
24
M. S. Ashkinazi
Dokl. Akad. Nauk SSSR , 1951
26.
27
A. A. Krasnovskii
Biofizika , 1956
27.
28
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1955
28.
29
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1951
29.
30
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1954
31.
Reaction intermediates in methyl alcohol decomposition on ZnO
Ueno A., Onishi T., Tamaru K.
Transactions of the Faraday Society , 1971
34.
35
Z. K. Maizus
Dokl. Akad. Nauk SSSR , 1960
35.
Methanol synthesis on Cu/ZnAl2O4 and Cu/ZnOAl2O3 Catalysts
Kiennemann A., Idriss H., Hindermann J.P., Lavalley J.C., Vallet A., Chaumette P., Courty P.
Applied Catalysis , 1990
37.
38
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1956
38.
39
V. F. Gachkovskii
Biofizika , 1959
39.
40
A. A. Krasnovskii
Biofizika , 1960
40.
41
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1950
42.
43
N. Bunge
Ber. Deutsch. Chem. Ges. , 1870
44.
45
W. Hendrich
Roczniki Chemii , 1958
46.
47
G. Oster
"Research in Photosynthesis" , 1957
47.
48
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1955
49.
Chapter 4: Heterogeneous Carbon Monoxide Hydrogenation
Kiennemann A., Hindermann J.
Studies in Surface Science and Catalysis , 1988
50.
51
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1954
51.
52
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1957
52.
In situ carbon-13 solid-state NMR study of the Cu/ZnO/Al2O3 methanol synthesis catalyst
Lazo N.D., Murray D.K., Kieke M.L., Haw J.F.
Journal of the American Chemical Society , 1992
53.
In situ NMR studies of a Cu/ZnO/Al2O3 methanol synthesis catalyst
Bendada A., Chinchen G., Clayden N., Heaton B.T., Iggo J.A., Smith C.S.
Catalysis Today , 1991
55.
The structure and energetics of the C3N+ ion
Harland P.W., Maclagan R.G.
Journal of the Chemical Society Faraday Transactions 2 Molecular and Chemical Physics , 1987
58.
59
H. Linshitz
"Research in Photosynthesis" , 1957
59.
60
A. N. Terenin
Optika i Spektrosk. , 1956
60.
61
A. N. Terenin
1959
61.
62
A. A. Krasnovskii
"Sbornik, Voprosy Khimicheskoi Kinetiki" (Symposium, Problems of Chemical Kinetics) , 1955
63.
64
Chem. Zentr. II , 1931
64.
65
A. A. Krasnovskii
Biofizika , 1959
67.
Catalytic reduction of carbon monoxide over potassium modified iron surfaces
Dwyer D.J., Hardenbergh J.H.
Applications of Surface Science , 1984
71.
Activation of CO by surface carbide on Fe(110)
Deng J., Wang H.
Catalysis Letters , 1992
75.
76
A. N. Terenin
"Fotokhimiya Krasitelei" (The Photochemistry of Dyes) , 1947
76.
77
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1948
77.
78
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1949
79.
80
N. N. Mel'nikov
Zhur. Obshch. Khim. , 1937
80.
CO2 activation and reaction with hydrogen on Ni(110): formate formation
Wambach J., Illing G., Freund H.-.
Chemical Physics Letters , 1991
84.
85
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1947
89.
90
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1951
90.
91
L. M. Vorob'eva
Biokhimiya , 1956
91.
92
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1948
93.
Carbon Monoxide Hydrogenation on Cobalt Foil and on Thin Cobalt Film Model Catalysts
Lahtinen J., Anraku T., Somorjai G.A.
Journal of Catalysis , 1993
95.
CO Hydrogenation on Supported Cobalt Catalysts Studied by in situ FTIR-Spectroscopy
Fredriksen G.R., Blekkan E.A., Schanke D., Holmen A.
Berichte der Bunsengesellschaft für physikalische Chemie , 1993
96.
X-ray photoelectron spectroscopy study of silica-alumina catalysts used for a new pyridine synthesis
Bicker R., Deger H., Herzog W., Rieser K., Pulm H., Hohlneicher G., Freund H.-.
Journal of Catalysis , 1985
97.
98
W. Franke
Chem. Zentr. , 1954
98.
99
V. V. Zolotarev
1938
101.
102
F. Fichter
Helv. Chim. Acta , 1922
104.
An in situ Mössbauer investigation of the influence of metal–support and metal–metal interactions on the activity and selectivity of iron–ruthenium catalysts
Berry F.J., Liwu L., Chengyu W., Renyuan T., Su Z., Dongbai L.
Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases , 1985
105.
106
F. Fichter
Helv. Chim. Acta , 1927
111.
In situ FTIR study of CO/H2 reactions over Rh/SiO2 catalysts at high pressure and temperature
Anderson J.A., McQuire M.W., Rochester C.H., Sweeney T.
Catalysis Today , 1991
115.
Infrared study of the reaction of H2+ CO on a Ru/SiO2 catalyst
Yamasaki H., Kobori Y., Naito S., Onishi T., Tamaru K.
Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases , 1981
118.
Mechanistic study of carbon monoxide hydrogenation over ruthenium catalysts
Kobori Y., Yamasaki H., Naito S., Onishi T., Tamaru K.
Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases , 1982
119.
120
V. V. Levchenko
Zhur. Obshch. Khim. , 1948
120.
FTIR studies on the CO, CO2 and H2 co-adsorption over Ru-RuO x /TiO2 catalyst
Gupta N.M., Kamble V.S., Iyer R.M., Thampi K.R., Gratzel M.
Catalysis Letters , 1993
121.
122
S. R. Rafikov
Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1953
123.
124
V. V. Levchenko
Zhur. Obshch. Khim. , 1952
127.
128
J. Wiemann
Bull. Soc. chim. France , 1952
129.
130
J. Wiemann
Bull. Soc. chim. France , 1958
130.
“In situ” drifts study of adsorbed species in the hydrogenation of carbon oxides
Benitez J.J., Alvero R., Carrizosa I., Odriozola J.A.
Catalysis Today , 1991
132.
Formation of C2 oxygenates on rhodium-containing catalysts during CO + H2 reactions. FTIR study of acetaldehyde adsorption
Demri D., Hindermann J., Diagne C., Kiennemann A.
Journal of the Chemical Society Faraday Transactions , 1994
133.
Elementary Steps in CO Hydrogenation on Rh Catalysts Supported on ZrO2 and Mo/ZrO2
Guglielminotti E., Giamello E., Pinna F., Strukul G., Martinengo S., Zanderighi L.
Journal of Catalysis , 1994
135.
137
S. R. Rafikov
Zh. Obshch. Khim. , 1944
137.
139
I. L. Knunyants
1959
140.
142
1913
141.
143
Friedl.
142.
Selective hydrogenation of carbon monoxide on palladium catalysts
Kikuzono Y., Kagami S., Naito S., Onishi T., Tamaru K.
Faraday Discussions of the Chemical Society , 1981
147.
Mechanism of branched carbon-chain formation from CO and H2over oxide catalysts. Part 1.—Adsorbed species on ZrO2and CeO2during CO hydrogenation
Maruya K., Takasawa A., Aikawa M., Haraoka T., Domen K., Onishi T.
Journal of the Chemical Society Faraday Transactions , 1994
148.
151
V. M. Rodionov
Zhur. Obshch. Khim. , 1936
149.
DRIFTS study of adsorbed formate species in the carbon dioxide and hydrogen reaction over rhodium catalysts
Benítez J.J., Alvero R., Capitán M.J., Carrizosa I., Odriozola J.A.
Applied Catalysis , 1991
154.
Adsorption and dissociation of CO2 on a potassium-promoted Rh(111) surface
Solymosi F., Bugyi L.
Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases , 1987
155.
158
Friedl.
158.
FTIR spectroscopic study of the interaction of CO2 and CO2 + H2 over partially oxidized Ru/TiO2 catalyst
GUPTA N., KAMBLE V., KARTHA V., IYER R., THAMPI K., GRATZEL M.
Journal of Catalysis , 1994
160.
Intermediates in CO and CO2 hydrogenation over Ni catalysts
Dalmon J., Martin G.A.
Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases , 1979
161.
164
1917
164.
167
Friedl.
168.
In situ IR Study of the Reactivity of RhI(CO)2/SiO2 Derived from Rh6(CO)16 for CO Insertion
Srinivas G., Chuang S.S.
The Journal of Physical Chemistry , 1994
171.
174
S. Calvert
India Rubber Tire Rev. , 1926
172.
175
I. Mayer
1966
173.
176
G. V. Samsonov
"Metody Ispytaniya na Mikrotverdost' i Pribory" (Methods of Microhardness Testing and Apparatus) , 1965
184.
187
1954
186.
Observation of cyanate and isocyanate surface species during the reaction of ammonia and carbon monoxide over supported rhodium
Paul D.K., McKee M.L., Worley S.D., Hoffman N.W., Ash D.H., Gautney J.
The Journal of Physical Chemistry , 1989
188.
IR spectroscopic studies of surface compounds in the reduction of no by CO on supported Pt, Pd and Rh catalysts
Alikina G.M., Davydov A.A., Sazanova I.S., Popovskii V.V.
Reaction Kinetics and Catalysis Letters , 1985
189.
192
E. Pannain
Rend. Classe Sci. fis. mat. nat. (5) , 1908
191.
194
A. A. Vertman
"Svoistva Rasplavov Zheleza" (Properties of Iron Melts) , 1969
192.
195
M. Allen
J. Chem. Soc. , 1961
193.
196
E. Müller
Z. Elektrochem. , 1910
194.
197
J. Sicher
Chem. Listy , 1955
195.
198
W. Cohen
Rec. Trav. chim. , 1919
196.
199
Yu. K. Delimarskii
Byull. Izobr. , 1970
198.
201
A. Aladjem
1969
199.
202
G. Shiroa
Mem. Coll. Sci., Kyoto Univ. , 1930
200.
203
L. Andrieux
Compt. rend. , 1929
202.
206
J. Petersen
Z. Phys. Chem. , 1900
203.
207
F. Fichter
"Organische Elektrochemie" , 1942
204.
208
O. A. Reutov
"Teoreticheskie Problemy Organicheskoi Khimii" (Theoretical Problems in Organic Chemistry) , 1956
205.
209
C. J. Haggerty
Trans. Am. Electrochem. Soc. , 1929
208.
212
L. V. Pavlova
Zh. Obshch. Khim. , 1965
209.
213
F. Yu. Rachinskii
"Khimiya Seraorganicheskikh Soedinenii, Soderzhashchikh-sya v Neftyakh i Nefteproduktakh" (Chemistry of Organo-sulphur Compounds Present in Petroleum and Petroleum Products) , 1966
214.
218
Chem. Zentr. II , 1925
217.
Kinetic and infrared spectroscopic studies of Fe-Y zeolites for the selective catalytic reduction of nitric oxide by ammonia
Amiridis M.D., Puglisi F., Dumesic J.A., Millman W.S., Topsoe N.Y.
Journal of Catalysis , 1993
220.
Hydrogenation of nitric oxide on (0 0 1) and (1 1 10) surfaces of ruthenium
Nishida T., Egawa C., Naito S., Tamaru K.
Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases , 1984
221.
225
1960
222.
226
Chem. Abs. , 1961
223.
227
B. Roetheke
1958
227.
231
1960
229.
The interaction of NO with copper ions in ZSM5 : an EPR and IR investigation
GIAMELLO E., MURPHY D., MAGNACCA G., MORTERRA C., SHIOYA Y., NOMURA T., ANPO M.
Journal of Catalysis , 1992
230.
234
Ebach E A
Chem. Abs. , 1966
232.
236
P. Peshev
Rev. internat. hautes Temperat. et Réfract. , 1969
234.
Removal of nitrogen monoxide through a novel catalytic process. 2. Infrared study on surface reaction of nitrogen monoxide adsorbed on copper ion-exchanged ZSM-5 zeolites
Iwamoto M., Yahiro H., Mizuno N., Zhang W.X., Mine Y., Furukawa H., Kagawa S.
The Journal of Physical Chemistry , 1992
235.
Studies of the surface species formed from nitric oxide on copper zeolites
Valyon J., Hall W.K.
The Journal of Physical Chemistry , 1993
237.
Mechanism of the lean NOx reaction over Cu/ZSM-5
Ansell G.P., Diwell A.F., Golunski S.E., Hayes J.W., Rajaram R.R., Truex T.J., Walker A.P.
Applied Catalysis B: Environmental , 1993
239.
Formation, storage and reactivity of nitrile species during the lean NOxreaction over Cu/ZSM-5 catalysts
Hayes N.W., Grünert W., Hutchings G.J., Joyner R.W., Shpiro E.S.
Journal of the Chemical Society Chemical Communications , 1994
240.
244
C. Wilson
Record. Chem. Prog. , 1949
241.
245
G. A. Meerson
1958
242.
Studies of the selective reduction of nitric oxide by hydrocarbons
Petunchi J.O., Sill G., Hall W.K.
Applied Catalysis B: Environmental , 1993
243.
247
E. I. Levkoeva
Khim. Geterotsikl. Soed. , 1976
244.
248
M. Ya. Fioshin
Plasticheskie Massy , 1960
247.
251
D. Goerrig
Chem. Abs. , 1959
249.
253
D. Goerrig
Chem. Abs. , 1959