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Heterogeneous free-radical reactions in oxidation processes

Mikhail Yur'evich Sinev 1
Mikhail Yur'evich Sinev
, 
Liya Yakovlevna Margolis 1
Liya Yakovlevna Margolis
, 
Vladimir Nikolaevich Korchak 1
Vladimir Nikolaevich Korchak
1 N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow
10.1070/RC1995v064n04ABEH000154
Published 30 November 1994
Communication , Volume 64, Issue 4, 349-364
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Sinev M. Y., Margolis L. Y., Korchak V. N. Heterogeneous free-radical reactions in oxidation processes // Russian Chemical Reviews. 1995. Vol. 64. No. 4. pp. 349-364.
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Sinev M. Y., Margolis L. Y., Korchak V. N. Heterogeneous free-radical reactions in oxidation processes // Russian Chemical Reviews. 1995. Vol. 64. No. 4. pp. 349-364.
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TY - JOUR
DO - 10.1070/RC1995v064n04ABEH000154
UR - https://rcr.colab.ws/publications/10.1070/RC1995v064n04ABEH000154
TI - Heterogeneous free-radical reactions in oxidation processes
T2 - Russian Chemical Reviews
AU - Sinev, Mikhail Yur'evich
AU - Margolis, Liya Yakovlevna
AU - Korchak, Vladimir Nikolaevich
PY - 1995
DA - 1994/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 349-364
IS - 4
VL - 64
ER -
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@article{1995_Sinev,
author = {Mikhail Yur'evich Sinev and Liya Yakovlevna Margolis and Vladimir Nikolaevich Korchak},
title = {Heterogeneous free-radical reactions in oxidation processes},
journal = {Russian Chemical Reviews},
year = {1995},
volume = {64},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1995v064n04ABEH000154},
number = {4},
pages = {349--364},
doi = {10.1070/RC1995v064n04ABEH000154}
}
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Sinev, Mikhail Yur'evich, et al. “Heterogeneous free-radical reactions in oxidation processes.” Russian Chemical Reviews, vol. 64, no. 4, Nov. 1995, pp. 349-364. https://rcr.colab.ws/publications/10.1070/RC1995v064n04ABEH000154.
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Abstract

The role of heterogeneous reactions of free radicals in oxidation processes of various types is analysed: homogeneous gas-phase, stabilised combustion, and heterogeneous-catalytic processes. It is shown that in all cases the observed kinetics and product compositions may be determined by the set of heterogeneous and homogeneous stages having the same nature, occurring in the systems simultaneously and as interdependent reactions. The possible mechanism of the heterogeneous formation of free radicals and of their subsequent reactions are discussed. The methods for the investigation of heterogeneous radical reactions are examined. The bibliography includes 198 references.

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