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Complexes of metal chlorides with proton donors - promising polyfunctional catalysts for electrophilic processes

Karl Samoilovich Minsker 1
Karl Samoilovich Minsker
, 
Svetlana Romanovna Ivanova 1
Svetlana Romanovna Ivanova
, 
Raisa Zigandarovna Biglova 1
Raisa Zigandarovna Biglova
1 Bashkir State University, Ufa
10.1070/RC1995v064n05ABEH000158
Published 30 November 1994
Communication , Volume 64, Issue 5, 429-444
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Minsker K. S., Ivanova S. R., Biglova R. Z. Complexes of metal chlorides with proton donors - promising polyfunctional catalysts for electrophilic processes // Russian Chemical Reviews. 1995. Vol. 64. No. 5. pp. 429-444.
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Minsker K. S., Ivanova S. R., Biglova R. Z. Complexes of metal chlorides with proton donors - promising polyfunctional catalysts for electrophilic processes // Russian Chemical Reviews. 1995. Vol. 64. No. 5. pp. 429-444.
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TY - JOUR
DO - 10.1070/RC1995v064n05ABEH000158
UR - https://rcr.colab.ws/publications/10.1070/RC1995v064n05ABEH000158
TI - Complexes of metal chlorides with proton donors - promising polyfunctional catalysts for electrophilic processes
T2 - Russian Chemical Reviews
AU - Minsker, Karl Samoilovich
AU - Ivanova, Svetlana Romanovna
AU - Biglova, Raisa Zigandarovna
PY - 1995
DA - 1994/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 429-444
IS - 5
VL - 64
ER -
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@article{1995_Minsker,
author = {Karl Samoilovich Minsker and Svetlana Romanovna Ivanova and Raisa Zigandarovna Biglova},
title = {Complexes of metal chlorides with proton donors - promising polyfunctional catalysts for electrophilic processes},
journal = {Russian Chemical Reviews},
year = {1995},
volume = {64},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1995v064n05ABEH000158},
number = {5},
pages = {429--444},
doi = {10.1070/RC1995v064n05ABEH000158}
}
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Minsker, Karl Samoilovich, et al. “Complexes of metal chlorides with proton donors - promising polyfunctional catalysts for electrophilic processes.” Russian Chemical Reviews, vol. 64, no. 5, Nov. 1995, pp. 429-444. https://rcr.colab.ws/publications/10.1070/RC1995v064n05ABEH000158.
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Abstract

The Bronsted acids formed as a result of the interaction of aluminium chlorides with Group I and II metal chlorides in the presence of proton-donating compounds are promising polyfunctional catalysts for electrophilic processes (polymerisation, depolymerisation and degradation of macromolecules, alkylation, desulfurisation, and hydrogenation). The factor determing the electrophilic activity and selectivity of the action of the catalysts is their acidity. This makes it possible to predict the direction of the changes in the activity and selectivity of the catalyst in specific chemical processes in conformity with the opposite variation rule: with increase in the acidity of the electrophilic catalyst, their activity increases but the selectivity of their action diminishes. The bibliography includes 72 references.

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