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Specific features of the reactivity of organotellurium compounds

Igor Dzhafarovich Sadekov 1
Igor Dzhafarovich Sadekov
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1 Institute of Physical and Organic Chemistry at Rostov State University
10.1070/RC1995v064n06ABEH000162
Published 30 November 1994
Communication , Volume 64, Issue 6, 491-522
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Sadekov I. D., Minkin V. I. Specific features of the reactivity of organotellurium compounds // Russian Chemical Reviews. 1995. Vol. 64. No. 6. pp. 491-522.
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Sadekov I. D., Minkin V. I. Specific features of the reactivity of organotellurium compounds // Russian Chemical Reviews. 1995. Vol. 64. No. 6. pp. 491-522.
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TY - JOUR
DO - 10.1070/RC1995v064n06ABEH000162
UR - https://rcr.colab.ws/publications/10.1070/RC1995v064n06ABEH000162
TI - Specific features of the reactivity of organotellurium compounds
T2 - Russian Chemical Reviews
AU - Sadekov, Igor Dzhafarovich
AU - Minkin, Vladimir Isaakovich
PY - 1995
DA - 1994/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 491-522
IS - 6
VL - 64
ER -
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@article{1995_Sadekov,
author = {Igor Dzhafarovich Sadekov and Vladimir Isaakovich Minkin},
title = {Specific features of the reactivity of organotellurium compounds},
journal = {Russian Chemical Reviews},
year = {1995},
volume = {64},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1995v064n06ABEH000162},
number = {6},
pages = {491--522},
doi = {10.1070/RC1995v064n06ABEH000162}
}
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Sadekov, Igor Dzhafarovich, and Vladimir Isaakovich Minkin. “Specific features of the reactivity of organotellurium compounds.” Russian Chemical Reviews, vol. 64, no. 6, Nov. 1995, pp. 491-522. https://rcr.colab.ws/publications/10.1070/RC1995v064n06ABEH000162.
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Abstract

The characteristic features of the reactivity of the principal classes of organic compounds of tellurium(II) and tellurium(IV) are examined and compared with the analogous compounds of sulfur and selenium. The factors determing the specific features of the chemical behaviour of orgamotellurium compounds are characterised. It is shown that the possibility of the convenient introduction of tellurium-containing functional groups, their structural modification, elimination, the low-temperature elimination of the tellurium atom as a result of the low energy of the C–Te bond, and the high nucleophilicity of the tellurolate anions and diorganyl tellurides together with other properties create preconditions for the development of a new methodology in organic synthesis. The bibliography includes 446 references.

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