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Inhomogeneity in the molecular structure of cellulose nitrates

Valeri Ignat'evich Kovalenko 1
Valeri Ignat'evich Kovalenko
1 Kazan State Technological University
Published 30 November 1994
Communication , Volume 64, Issue 8, 753-766
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Kovalenko V. I. Inhomogeneity in the molecular structure of cellulose nitrates // Russian Chemical Reviews. 1995. Vol. 64. No. 8. pp. 753-766.
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Kovalenko V. I. Inhomogeneity in the molecular structure of cellulose nitrates // Russian Chemical Reviews. 1995. Vol. 64. No. 8. pp. 753-766.
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RIS
TY - JOUR
DO - 10.1070/RC1995v064n08ABEH000173
UR - https://rcr.colab.ws/publications/10.1070/RC1995v064n08ABEH000173
TI - Inhomogeneity in the molecular structure of cellulose nitrates
T2 - Russian Chemical Reviews
AU - Kovalenko, Valeri Ignat'evich
PY - 1995
DA - 1994/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 753-766
IS - 8
VL - 64
ER -
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@article{1995_Kovalenko,
author = {Valeri Ignat'evich Kovalenko},
title = {Inhomogeneity in the molecular structure of cellulose nitrates},
journal = {Russian Chemical Reviews},
year = {1995},
volume = {64},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1995v064n08ABEH000173},
number = {8},
pages = {753--766},
doi = {10.1070/RC1995v064n08ABEH000173}
}
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Cite this
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Kovalenko, Valeri Ignat'evich. “Inhomogeneity in the molecular structure of cellulose nitrates.” Russian Chemical Reviews, vol. 64, no. 8, Nov. 1995, pp. 753-766. https://rcr.colab.ws/publications/10.1070/RC1995v064n08ABEH000173.
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Abstract

The results of studies on the molecular structures of cellulose nitrates and related saccharide nitrates are surveyed. The inhomogeneity of the structures of cellulose nitrates can be analysed on three hierarchical levels: in terms of the composition of the elementary units, in terms of the distribution of the elementary units along the chain, and in terms of their distribution in the bulk phase. The possibilities of NMR and FT-IR spectroscopy for studies of these structural levels are discussed. A simple method has been developed for the estimation of the molecular-structural inhomogeneity of cellulose nitrates. It is shown that this inhomogeneity is determined by the inhomogeneity of the nitration process. A procedure is proposed for taking into account the diffusion of the nitrating agent in studies of the kinetics of the inhomogeneneous reactions. The bibliography includes 121 references.

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