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The spatial organisation of macromolecular metal chelates

Anatolii Dmitrievich Pomogailo 1
Anatolii Dmitrievich Pomogailo
, 
Igor Efimovich Uflyand 2
Igor Efimovich Uflyand
, 
Èduard Fridrikhovich Vainshtein 3
Èduard Fridrikhovich Vainshtein
1 Institute of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region
2 Rostov Pedagogical University
3 N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow
10.1070/RC1995v064n09ABEH000181
Published 30 November 1994
Communication , Volume 64, Issue 9, 857-876
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Pomogailo A. D., Uflyand I. E., Vainshtein È. F. The spatial organisation of macromolecular metal chelates // Russian Chemical Reviews. 1995. Vol. 64. No. 9. pp. 857-876.
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Pomogailo A. D., Uflyand I. E., Vainshtein È. F. The spatial organisation of macromolecular metal chelates // Russian Chemical Reviews. 1995. Vol. 64. No. 9. pp. 857-876.
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TY - JOUR
DO - 10.1070/RC1995v064n09ABEH000181
UR - https://rcr.colab.ws/publications/10.1070/RC1995v064n09ABEH000181
TI - The spatial organisation of macromolecular metal chelates
T2 - Russian Chemical Reviews
AU - Pomogailo, Anatolii Dmitrievich
AU - Uflyand, Igor Efimovich
AU - Vainshtein, Èduard Fridrikhovich
PY - 1995
DA - 1994/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 857-876
IS - 9
VL - 64
ER -
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@article{1995_Pomogailo,
author = {Anatolii Dmitrievich Pomogailo and Igor Efimovich Uflyand and Èduard Fridrikhovich Vainshtein},
title = {The spatial organisation of macromolecular metal chelates},
journal = {Russian Chemical Reviews},
year = {1995},
volume = {64},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1995v064n09ABEH000181},
number = {9},
pages = {857--876},
doi = {10.1070/RC1995v064n09ABEH000181}
}
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Pomogailo, Anatolii Dmitrievich, et al. “The spatial organisation of macromolecular metal chelates.” Russian Chemical Reviews, vol. 64, no. 9, Nov. 1995, pp. 857-876. https://rcr.colab.ws/publications/10.1070/RC1995v064n09ABEH000181.
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Abstract

The spatial organisation of metallopolymers (macromolecular metal chelates) is analysed on three levels; local, molecular, and supermolecular. The thermodynamic features of the formation of chelates with polymeric ligands are examined and data are presented concerning the dependence of the structure of the chelate units on various factors. The principal changes which the macrochain may undergo on formation of metal chelate centres are considered. The behaviour of the macromolecular ligands and their low-molecular- mass analogues is compared on the molecular level. The principal characteristics of the formation of intramolecular and intermolecular complexes are listed and the causes of their stability are examined. The bibliography includes 125 references.

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