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The structure and vibrational spectra of proton solvates in solution

Georgii Vladimirovich Yukhnevich 1
Georgii Vladimirovich Yukhnevich
, 
Elena Georgievna Tarakanova (Kokhanova) 1
Elena Georgievna Tarakanova (Kokhanova)
, 
Vladimir Dmitrievich Maiorov 2
Vladimir Dmitrievich Maiorov
, 
Nikolai Bronislavovich Librovich 2
Nikolai Bronislavovich Librovich
1 Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow
2 N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow
10.1070/RC1995v064n10ABEH000183
Published 30 November 1994
Communication , Volume 64, Issue 10, 901-911
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Yukhnevich G. V. et al. The structure and vibrational spectra of proton solvates in solution // Russian Chemical Reviews. 1995. Vol. 64. No. 10. pp. 901-911.
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Yukhnevich G. V., Tarakanova (Kokhanova) E. G., Maiorov V. D., Librovich N. B. The structure and vibrational spectra of proton solvates in solution // Russian Chemical Reviews. 1995. Vol. 64. No. 10. pp. 901-911.
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TY - JOUR
DO - 10.1070/RC1995v064n10ABEH000183
UR - https://rcr.colab.ws/publications/10.1070/RC1995v064n10ABEH000183
TI - The structure and vibrational spectra of proton solvates in solution
T2 - Russian Chemical Reviews
AU - Yukhnevich, Georgii Vladimirovich
AU - Tarakanova (Kokhanova), Elena Georgievna
AU - Maiorov, Vladimir Dmitrievich
AU - Librovich, Nikolai Bronislavovich
PY - 1995
DA - 1994/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 901-911
IS - 10
VL - 64
ER -
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@article{1995_Yukhnevich,
author = {Georgii Vladimirovich Yukhnevich and Elena Georgievna Tarakanova (Kokhanova) and Vladimir Dmitrievich Maiorov and Nikolai Bronislavovich Librovich},
title = {The structure and vibrational spectra of proton solvates in solution},
journal = {Russian Chemical Reviews},
year = {1995},
volume = {64},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1995v064n10ABEH000183},
number = {10},
pages = {901--911},
doi = {10.1070/RC1995v064n10ABEH000183}
}
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Yukhnevich, Georgii Vladimirovich, et al. “The structure and vibrational spectra of proton solvates in solution.” Russian Chemical Reviews, vol. 64, no. 10, Nov. 1995, pp. 901-911. https://rcr.colab.ws/publications/10.1070/RC1995v064n10ABEH000183.
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Abstract

The experimental and theoretical studies on the structure and properties of the simple stable proton hydrate are surveyed. It is shown that the hydrate is the ion $(\mathrm{H}_2\mathrm{O}\dots\mathrm{H}\dots\mathrm{OH}_2)^+$. The mechanism of the generation of the continuous absorption observed in the IR spectra of solutions of acids and strong bases is examined. It has been found that a common feature of the structures of all stable proton solvates~-- the ions $(\mathrm{A}\dots\mathrm{H}\dots\mathrm{A})^\pm$~-- is the presence in the latter of a symmetrical hydrogen bridge, the properties of which hardly depend on the nature of the ligand~$\mathrm{A}$. The constancy of the parameters of the hydrogen brige provided a basis for the creation of a unique quantitative theory of the catalytic action of acids and bases. The bibliography includes 103 references.

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