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The physical chemistry of the compounds MIP(As)UO6 (MI=H, Li, Na, K, Rb, Cs) and their crystalline hydrates

Nikolai Georgievich Chernorukov 1
Nikolai Georgievich Chernorukov
, 
Nikolai Vladimirovich Karyakin 1
Nikolai Vladimirovich Karyakin
1 N. I. Lobachevski State University of Nizhni Novgorod
10.1070/RC1995v064n10ABEH000184
Published 30 November 1994
Communication , Volume 64, Issue 10, 913-927
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Chernorukov N. G., Karyakin N. V. The physical chemistry of the compounds MIP(As)UO6 (MI=H, Li, Na, K, Rb, Cs) and their crystalline hydrates // Russian Chemical Reviews. 1995. Vol. 64. No. 10. pp. 913-927.
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Chernorukov N. G., Karyakin N. V. The physical chemistry of the compounds MIP(As)UO6 (MI=H, Li, Na, K, Rb, Cs) and their crystalline hydrates // Russian Chemical Reviews. 1995. Vol. 64. No. 10. pp. 913-927.
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TY - JOUR
DO - 10.1070/RC1995v064n10ABEH000184
UR - https://rcr.colab.ws/publications/10.1070/RC1995v064n10ABEH000184
TI - The physical chemistry of the compounds MIP(As)UO6 (MI=H, Li, Na, K, Rb, Cs) and their crystalline hydrates
T2 - Russian Chemical Reviews
AU - Chernorukov, Nikolai Georgievich
AU - Karyakin, Nikolai Vladimirovich
PY - 1995
DA - 1994/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 913-927
IS - 10
VL - 64
ER -
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@article{1995_Chernorukov,
author = {Nikolai Georgievich Chernorukov and Nikolai Vladimirovich Karyakin},
title = {The physical chemistry of the compounds MIP(As)UO6 (MI=H, Li, Na, K, Rb, Cs) and their crystalline hydrates},
journal = {Russian Chemical Reviews},
year = {1995},
volume = {64},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1995v064n10ABEH000184},
number = {10},
pages = {913--927},
doi = {10.1070/RC1995v064n10ABEH000184}
}
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Chernorukov, Nikolai Georgievich, and Nikolai Vladimirovich Karyakin. “The physical chemistry of the compounds MIP(As)UO6 (MI=H, Li, Na, K, Rb, Cs) and their crystalline hydrates.” Russian Chemical Reviews, vol. 64, no. 10, Nov. 1995, pp. 913-927. https://rcr.colab.ws/publications/10.1070/RC1995v064n10ABEH000184.
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Abstract

Problems concerning the structures of compounds of the series MIP(As)UO6.nH 2O (MI = H, Li, Na, K, Rb, Cs; n = 4 for MI = H, Li and n = 3 for MI = Na, K, Rb, Cs) are examined. The results of X-ray powder diffraction, thermographic, and IR spectroscopic studies on the above compounds are analysed. The experimental standard enthalpies of formation (ΔfHo) of the compounds MI P(As)UO6 and their crystalline hydrates are discussed. The characteristic features of the variation of ΔfHo as a function of the structural characteristics of the compounds and of the physical properties of the Group I elements in the series of phosphorus and arsenic compounds are described. The enthalpies of dehydration and ion exchange involving the compounds investigated are presented. The bibliography includes 103 references.

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