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Organic reactions on the surface of silicon dioxide: synthetic applications

Vladimir Alexandrovich Basiuk 1
Vladimir Alexandrovich Basiuk
1 Institute of Nuclear Research, National Autonomous University of Mexico
10.1070/RC1995v064n11ABEH000190
Published 30 November 1994
Communication , Volume 64, Issue 11, 1003-1019
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Basiuk V. A. Organic reactions on the surface of silicon dioxide: synthetic applications // Russian Chemical Reviews. 1995. Vol. 64. No. 11. pp. 1003-1019.
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Basiuk V. A. Organic reactions on the surface of silicon dioxide: synthetic applications // Russian Chemical Reviews. 1995. Vol. 64. No. 11. pp. 1003-1019.
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TY - JOUR
DO - 10.1070/RC1995v064n11ABEH000190
UR - https://rcr.colab.ws/publications/10.1070/RC1995v064n11ABEH000190
TI - Organic reactions on the surface of silicon dioxide: synthetic applications
T2 - Russian Chemical Reviews
AU - Basiuk, Vladimir Alexandrovich
PY - 1995
DA - 1994/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1003-1019
IS - 11
VL - 64
ER -
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@article{1995_Basiuk,
author = {Vladimir Alexandrovich Basiuk},
title = {Organic reactions on the surface of silicon dioxide: synthetic applications},
journal = {Russian Chemical Reviews},
year = {1995},
volume = {64},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1995v064n11ABEH000190},
number = {11},
pages = {1003--1019},
doi = {10.1070/RC1995v064n11ABEH000190}
}
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Basiuk, Vladimir Alexandrovich. “Organic reactions on the surface of silicon dioxide: synthetic applications.” Russian Chemical Reviews, vol. 64, no. 11, Nov. 1995, pp. 1003-1019. https://rcr.colab.ws/publications/10.1070/RC1995v064n11ABEH000190.
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Abstract

The literature data on the specific features of organic reactions in the presence of silicon dioxide (predominantly in the unmodified form) and its use for synthetic purposes are analysed. Oxidation (including dry ozonisation), reduction, alkylation and acylation, halogenation, elimination, hydrolytic and dehydration reactions, intermolecular cycloaddition and other cyclisation reactions, three-membered ring opening reactions, and peroxide decomposition reactions, as well as certain photochemical reactions are considered. In the processes investigated, the surface of silicon dioxide can function as a catalyst, as a solid medium for the occurrence of reactions, and/or as a matrix influencing the stereospecificity. The bibliography includes 214 references.

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