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Heterogeneous catalytic synthesis of alkanethiols and dialkyl sulfides from alcohols and hydrogen sulfide

Anna Vasil'evna Mashkina 1
Anna Vasil'evna Mashkina
1 Boreskov Institute of Catalysis SB RAS, Novosibirsk
10.1070/RC1995v064n12ABEH000196
Published 30 November 1994
Communication , Volume 64, Issue 12, 1131-1147
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Mashkina A. V. Heterogeneous catalytic synthesis of alkanethiols and dialkyl sulfides from alcohols and hydrogen sulfide // Russian Chemical Reviews. 1995. Vol. 64. No. 12. pp. 1131-1147.
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Mashkina A. V. Heterogeneous catalytic synthesis of alkanethiols and dialkyl sulfides from alcohols and hydrogen sulfide // Russian Chemical Reviews. 1995. Vol. 64. No. 12. pp. 1131-1147.
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TY - JOUR
DO - 10.1070/RC1995v064n12ABEH000196
UR - https://rcr.colab.ws/publications/10.1070/RC1995v064n12ABEH000196
TI - Heterogeneous catalytic synthesis of alkanethiols and dialkyl sulfides from alcohols and hydrogen sulfide
T2 - Russian Chemical Reviews
AU - Mashkina, Anna Vasil'evna
PY - 1995
DA - 1994/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1131-1147
IS - 12
VL - 64
ER -
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@article{1995_Mashkina,
author = {Anna Vasil'evna Mashkina},
title = {Heterogeneous catalytic synthesis of alkanethiols and dialkyl sulfides from alcohols and hydrogen sulfide},
journal = {Russian Chemical Reviews},
year = {1995},
volume = {64},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1995v064n12ABEH000196},
number = {12},
pages = {1131--1147},
doi = {10.1070/RC1995v064n12ABEH000196}
}
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Mashkina, Anna Vasil'evna. “Heterogeneous catalytic synthesis of alkanethiols and dialkyl sulfides from alcohols and hydrogen sulfide.” Russian Chemical Reviews, vol. 64, no. 12, Nov. 1995, pp. 1131-1147. https://rcr.colab.ws/publications/10.1070/RC1995v064n12ABEH000196.
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Abstract

The results of studies of the heterogeneous acid-base catalysis of reactions of alcohols with hydrogen sulfides, which yield alkanethiols and dialkyl sulfides, are surveyed. Data concerning the activity and selectivity of the catalysts under the reaction conditions are considered. A relation is established between the catalytic and acid–base properties of the catalysts. The mechanism of the thiolation reaction is discussed and the criteria for the selection of the effective catalysts are formulated. The bibliography includes 97 references.

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