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Stabilisation of metal ions in unusual oxidation states and electron dynamics in oxide glasses

Aleksei Ivanovich Aleksandrov 1
Aleksei Ivanovich Aleksandrov
, 
Alexandr Ivanovich Prokof'ev 2
Alexandr Ivanovich Prokof'ev
, 
Nikolai Nikolaevich Bubnov 2
Nikolai Nikolaevich Bubnov
1 Institute of Synthetic Polymer Materials RAS, Moscow
2 A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow
10.1070/RC1996v065n06ABEH000300
Published 30 November 1995
Communication , Volume 65, Issue 6, 479-496
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Aleksandrov A. I., Prokof'ev A. I., Bubnov N. N. Stabilisation of metal ions in unusual oxidation states and electron dynamics in oxide glasses // Russian Chemical Reviews. 1996. Vol. 65. No. 6. pp. 479-496.
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Aleksandrov A. I., Prokof'ev A. I., Bubnov N. N. Stabilisation of metal ions in unusual oxidation states and electron dynamics in oxide glasses // Russian Chemical Reviews. 1996. Vol. 65. No. 6. pp. 479-496.
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TY - JOUR
DO - 10.1070/RC1996v065n06ABEH000300
UR - https://rcr.colab.ws/publications/10.1070/RC1996v065n06ABEH000300
TI - Stabilisation of metal ions in unusual oxidation states and electron dynamics in oxide glasses
T2 - Russian Chemical Reviews
AU - Aleksandrov, Aleksei Ivanovich
AU - Prokof'ev, Alexandr Ivanovich
AU - Bubnov, Nikolai Nikolaevich
PY - 1996
DA - 1995/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 479-496
IS - 6
VL - 65
ER -
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@article{1996_Aleksandrov,
author = {Aleksei Ivanovich Aleksandrov and Alexandr Ivanovich Prokof'ev and Nikolai Nikolaevich Bubnov},
title = {Stabilisation of metal ions in unusual oxidation states and electron dynamics in oxide glasses},
journal = {Russian Chemical Reviews},
year = {1996},
volume = {65},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1996v065n06ABEH000300},
number = {6},
pages = {479--496},
doi = {10.1070/RC1996v065n06ABEH000300}
}
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Aleksandrov, Aleksei Ivanovich, et al. “Stabilisation of metal ions in unusual oxidation states and electron dynamics in oxide glasses.” Russian Chemical Reviews, vol. 65, no. 6, Nov. 1996, pp. 479-496. https://rcr.colab.ws/publications/10.1070/RC1996v065n06ABEH000300.
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Abstract

The results of studies on the stabilisation of metal ions in unusual oxidation states in oxide glasses are surveyed. Attention is concentrated on the relation between the stabilisation of these ions and redistribution of the electron density, and on the disproportionation reactions accompanying it. The effect of reversible low-temperature disproportionation on niobium, titanium, vanadium, molybdenum, tungsten, and other ions is considered. The formation of metal clusters in oxide glasses is shown also to be associated with disproportionation. The bibliography includes 108 references.

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