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Selective oxidation of gaseous hydrocarbons by bacterial cells

Galina Artem'evna Kovalenko 1
Galina Artem'evna Kovalenko
1 Boreskov Institute of Catalysis SB RAS, Novosibirsk
Published 30 November 1995
Communication , Volume 65, Issue 7, 625-639
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Kovalenko G. A. Selective oxidation of gaseous hydrocarbons by bacterial cells // Russian Chemical Reviews. 1996. Vol. 65. No. 7. pp. 625-639.
GOST all authors (up to 50)
Kovalenko G. A. Selective oxidation of gaseous hydrocarbons by bacterial cells // Russian Chemical Reviews. 1996. Vol. 65. No. 7. pp. 625-639.
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TY - JOUR
DO - 10.1070/RC1996v065n07ABEH000230
UR - https://rcr.colab.ws/publications/10.1070/RC1996v065n07ABEH000230
TI - Selective oxidation of gaseous hydrocarbons by bacterial cells
T2 - Russian Chemical Reviews
AU - Kovalenko, Galina Artem'evna
PY - 1996
DA - 1995/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 625-639
IS - 7
VL - 65
ER -
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@article{1996_Kovalenko,
author = {Galina Artem'evna Kovalenko},
title = {Selective oxidation of gaseous hydrocarbons by bacterial cells},
journal = {Russian Chemical Reviews},
year = {1996},
volume = {65},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1996v065n07ABEH000230},
number = {7},
pages = {625--639},
doi = {10.1070/RC1996v065n07ABEH000230}
}
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Kovalenko, Galina Artem'evna. “Selective oxidation of gaseous hydrocarbons by bacterial cells.” Russian Chemical Reviews, vol. 65, no. 7, Nov. 1996, pp. 625-639. https://rcr.colab.ws/publications/10.1070/RC1996v065n07ABEH000230.
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Abstract

Studies on the direct selective oxidation of gaseous C1–C4 alkanes and C2–C4 alkenes to valuable oxygen-containing products (alcohols, methyl ketones, and epoxides) with the aid of the bacterial cells of gas-assimilating microorganisms are surveyed. The resting bacterial cells of the microorganisms grown on gaseous hydrocarbons possess an enzymic monoxygenase activity: they promote the insertion of an oxygen atom into the hydrocarbon molecule with formation of an oxygen-containing product. This process is effected under very mild conditions and is characterised by high selectivity and stereospecificity. It proceeds without the formation of toxic by-products. Certain problems of the practical implementation of biocatalytic oxidation processes, namely the regeneration of the monoxygenase cofactor, the reduction of the toxic effect of the oxygen-containing product formed, as well as the immobilisation of the cells on solid carriers in order to obtain an active and stable heterogeneous biocatalyst for the direct partial oxidation of hydrocarbons are considered. The bibliography includes 111 references.

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