Home / Articles / The influence of chemical structure on the relaxation properties of heat-resistant aromatic polymers

The influence of chemical structure on the relaxation properties of heat-resistant aromatic polymers

Andrei Aleksandrovich Askadskii 1
Andrei Aleksandrovich Askadskii
1 A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow
10.1070/RC1996v065n08ABEH000322
Published 30 November 1995
Communication , Volume 65, Issue 8, 677-707
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Askadskii A. A. The influence of chemical structure on the relaxation properties of heat-resistant aromatic polymers // Russian Chemical Reviews. 1996. Vol. 65. No. 8. pp. 677-707.
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Askadskii A. A. The influence of chemical structure on the relaxation properties of heat-resistant aromatic polymers // Russian Chemical Reviews. 1996. Vol. 65. No. 8. pp. 677-707.
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TY - JOUR
DO - 10.1070/RC1996v065n08ABEH000322
UR - https://rcr.colab.ws/publications/10.1070/RC1996v065n08ABEH000322
TI - The influence of chemical structure on the relaxation properties of heat-resistant aromatic polymers
T2 - Russian Chemical Reviews
AU - Askadskii, Andrei Aleksandrovich
PY - 1996
DA - 1995/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 677-707
IS - 8
VL - 65
ER -
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@article{1996_Askadskii,
author = {Andrei Aleksandrovich Askadskii},
title = {The influence of chemical structure on the relaxation properties of heat-resistant aromatic polymers},
journal = {Russian Chemical Reviews},
year = {1996},
volume = {65},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1996v065n08ABEH000322},
number = {8},
pages = {677--707},
doi = {10.1070/RC1996v065n08ABEH000322}
}
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Askadskii, Andrei Aleksandrovich. “The influence of chemical structure on the relaxation properties of heat-resistant aromatic polymers.” Russian Chemical Reviews, vol. 65, no. 8, Nov. 1996, pp. 677-707. https://rcr.colab.ws/publications/10.1070/RC1996v065n08ABEH000322.
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Abstract

Data concerning the experimental method for the estimation of the mechanical workability of heat-resistant polymers, based on relaxation measurements, as well as concerning procedures for the fitting of stress relaxation and creep curves with the aid of new memory functions are surveyed. The influence of the chemical structures of various heat-resistant polymers (aromatic polyethers and polyamides, polyimides, polybenzoxazoles, polyoxadiazoles, etc.) on their relaxation behaviour is analysed in detail. Attention is concentrated on the relaxation transitions manifested in the glassy state. The mechanism of the deformation and relaxation in heat-resistant polymers, investigated with the aid of the positron annihilation method, is described. The relaxation behaviour of heat-resistant aromatic polymers down to the temperature of liquid helium is considered. Attention is drawn to the relaxation behaviour. The bibliography includes167 references.

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