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Low-temperature functionalisation of alkanes and cycloalkanes by 'classical' and 'non-classical' (superacidic) Friedel–Crafts complexes

Irena Sergeevna Akhrem 1
Irena Sergeevna Akhrem
, 
Alexander Vyacheslavovich Orlinkov 1
Alexander Vyacheslavovich Orlinkov
, 
Mark Efimovich Vol'pin 1
Mark Efimovich Vol'pin
1 A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow
10.1070/RC1996v065n10ABEH000242
Published 30 November 1995
Communication , Volume 65, Issue 10, 849-863
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Akhrem I. S., Orlinkov A. V., Vol'pin M. E. Low-temperature functionalisation of alkanes and cycloalkanes by 'classical' and 'non-classical' (superacidic) Friedel–Crafts complexes // Russian Chemical Reviews. 1996. Vol. 65. No. 10. pp. 849-863.
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Akhrem I. S., Orlinkov A. V., Vol'pin M. E. Low-temperature functionalisation of alkanes and cycloalkanes by 'classical' and 'non-classical' (superacidic) Friedel–Crafts complexes // Russian Chemical Reviews. 1996. Vol. 65. No. 10. pp. 849-863.
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TY - JOUR
DO - 10.1070/RC1996v065n10ABEH000242
UR - https://rcr.colab.ws/publications/10.1070/RC1996v065n10ABEH000242
TI - Low-temperature functionalisation of alkanes and cycloalkanes by 'classical' and 'non-classical' (superacidic) Friedel–Crafts complexes
T2 - Russian Chemical Reviews
AU - Akhrem, Irena Sergeevna
AU - Orlinkov, Alexander Vyacheslavovich
AU - Vol'pin, Mark Efimovich
PY - 1996
DA - 1995/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 849-863
IS - 10
VL - 65
ER -
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@article{1996_Akhrem,
author = {Irena Sergeevna Akhrem and Alexander Vyacheslavovich Orlinkov and Mark Efimovich Vol'pin},
title = {Low-temperature functionalisation of alkanes and cycloalkanes by 'classical' and 'non-classical' (superacidic) Friedel–Crafts complexes},
journal = {Russian Chemical Reviews},
year = {1996},
volume = {65},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1996v065n10ABEH000242},
number = {10},
pages = {849--863},
doi = {10.1070/RC1996v065n10ABEH000242}
}
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Akhrem, Irena Sergeevna, et al. “Low-temperature functionalisation of alkanes and cycloalkanes by 'classical' and 'non-classical' (superacidic) Friedel–Crafts complexes.” Russian Chemical Reviews, vol. 65, no. 10, Nov. 1996, pp. 849-863. https://rcr.colab.ws/publications/10.1070/RC1996v065n10ABEH000242.
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Abstract

The results of studies on direct functionalisation of activated alkanes and cycloalkanes under the action of 'classical' Friedel–Crafts complexes (viz. equimolar complexes of acyl halides with aluminium halides) and related systems containing smaller or somewhat larger amounts of aluminium halide are surveyed. The studies carried out during the last decade on functionalisation of saturated hydrocarbons devoid of tertiary carbon atoms, by aprotic organic superacids RCOX.2AlCl3 are summarised. Reactions of alkanes with acylium cations in superacidic media are considered. The published data on the structure of complexes RCOX . AlCl3 and RCOX . 2AlCl3 and on the nature of the active complexes in the reactions of arenes with acylium cations and with complexes RCOX .AlCl3 in both acidic and organic media as well as in the reactions of alkanes with acylium salts in protic superacids and with superacidic complexes RCOX .2AlCl3 in aprotic solvents are analysed. The prospects for the synthesis of organic compounds from alkanes and cycloalkanes under the action of complexes of acyl halides with aluminium halides are outlined. The bibliography includes 128 references.

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