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Inner valence molecular orbitals and the structure of X-ray photoelectron spectra

Yurii Aleksandrovich Teterin 1
Yurii Aleksandrovich Teterin
, 
Sergei Gavrilovich Gagarin 2
Sergei Gavrilovich Gagarin
1 Russian Research Centre "Kurchatov Institute", Moscow
2 Fossil Fuel Institute, Ministry of Fuel and Energetics of the Russian Federation, Moscow
10.1070/RC1996v065n10ABEH000278
Published 30 November 1995
Communication , Volume 65, Issue 10, 825-847
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Teterin Y. A., Gagarin S. G. Inner valence molecular orbitals and the structure of X-ray photoelectron spectra // Russian Chemical Reviews. 1996. Vol. 65. No. 10. pp. 825-847.
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Teterin Y. A., Gagarin S. G. Inner valence molecular orbitals and the structure of X-ray photoelectron spectra // Russian Chemical Reviews. 1996. Vol. 65. No. 10. pp. 825-847.
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TY - JOUR
DO - 10.1070/RC1996v065n10ABEH000278
UR - https://rcr.colab.ws/publications/10.1070/RC1996v065n10ABEH000278
TI - Inner valence molecular orbitals and the structure of X-ray photoelectron spectra
T2 - Russian Chemical Reviews
AU - Teterin, Yurii Aleksandrovich
AU - Gagarin, Sergei Gavrilovich
PY - 1996
DA - 1995/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 825-847
IS - 10
VL - 65
ER -
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@article{1996_Teterin,
author = {Yurii Aleksandrovich Teterin and Sergei Gavrilovich Gagarin},
title = {Inner valence molecular orbitals and the structure of X-ray photoelectron spectra},
journal = {Russian Chemical Reviews},
year = {1996},
volume = {65},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1996v065n10ABEH000278},
number = {10},
pages = {825--847},
doi = {10.1070/RC1996v065n10ABEH000278}
}
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Teterin, Yurii Aleksandrovich, and Sergei Gavrilovich Gagarin. “Inner valence molecular orbitals and the structure of X-ray photoelectron spectra.” Russian Chemical Reviews, vol. 65, no. 10, Nov. 1996, pp. 825-847. https://rcr.colab.ws/publications/10.1070/RC1996v065n10ABEH000278.
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Abstract

X-Ray photoelectron spectroscopy (XPS) and theoretical calculations show that under certain conditions inner valence molecular orbitals (IVMOs) can form within a rather broad binding energy range (15 eV to 50 eV) in compounds of many elements of the Periodic Table. This results in the appearance of a fine structure in their X-ray photoelectron spectra. The structure of X-ray photoelectron spectra associated with electrons of IVMOs correlates with contributions of the filled atomic orbitals (AOs) to the IVMO formation and the structure of compounds. In certain cases, the total contribution of electrons of the inner valence molecular orbitals to the bond energy in molecules and compounds is comparable to that of electrons of the outer valence molecular orbitals. This phenomenon is extremely important and new in principle for chemistry. The bibliography includes 128 references.

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