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Spatial and electronic structure of vinyl and allenyl chalcogenides

Lidia Mikhailovna Sinegovskaya 1
Lidia Mikhailovna Sinegovskaya
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1 Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
10.1070/RC1996v065n12ABEH000248
Published 30 November 1995
Communication , Volume 65, Issue 12, 1009-1038
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Sinegovskaya L. M., Trofimov B. A. Spatial and electronic structure of vinyl and allenyl chalcogenides // Russian Chemical Reviews. 1996. Vol. 65. No. 12. pp. 1009-1038.
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Sinegovskaya L. M., Trofimov B. A. Spatial and electronic structure of vinyl and allenyl chalcogenides // Russian Chemical Reviews. 1996. Vol. 65. No. 12. pp. 1009-1038.
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TY - JOUR
DO - 10.1070/RC1996v065n12ABEH000248
UR - https://rcr.colab.ws/publications/10.1070/RC1996v065n12ABEH000248
TI - Spatial and electronic structure of vinyl and allenyl chalcogenides
T2 - Russian Chemical Reviews
AU - Sinegovskaya, Lidia Mikhailovna
AU - Trofimov, Boris Aleksandrovich
PY - 1996
DA - 1995/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1009-1038
IS - 12
VL - 65
ER -
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@article{1996_Sinegovskaya,
author = {Lidia Mikhailovna Sinegovskaya and Boris Aleksandrovich Trofimov},
title = {Spatial and electronic structure of vinyl and allenyl chalcogenides},
journal = {Russian Chemical Reviews},
year = {1996},
volume = {65},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1996v065n12ABEH000248},
number = {12},
pages = {1009--1038},
doi = {10.1070/RC1996v065n12ABEH000248}
}
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Sinegovskaya, Lidia Mikhailovna, and Boris Aleksandrovich Trofimov. “Spatial and electronic structure of vinyl and allenyl chalcogenides.” Russian Chemical Reviews, vol. 65, no. 12, Nov. 1996, pp. 1009-1038. https://rcr.colab.ws/publications/10.1070/RC1996v065n12ABEH000248.
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Abstract

Alkyl vinyl chalcogenides show a complex picture of rotational isomerism and are characterised by the presence of several qualitatively different types of stable conformers. The features of conformational structure of these compounds can be understood only by considering the stationary states altogether. Conformational analysis of divinyl chalcogenides indicates that the potential energy surface of internal rotation should be considered not as just a source of information on rotational isomerism; rather, it is a tool in a search for stationary states corresponding to definite intervals of variation of internal molecular coordinates. The principal details of the orbital structure of allenyl ethers and vinyl chalcogenides including a weak dependence of the structure and relative location of higher occupied π-MOs of alkyl vinyl chalcogenides on the nature of the heteroatom and the structure of the alkyl substituent are discussed. The common feature of chalcogenides is the presence of a low energy excited state of σ-symmetry. The excited states of π-symmetry are always located higher on the energy scale than the states of σ-symmetry. The bibliography includes 198 references.

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