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Labile products of interaction of cellulose with nitrogen oxide compounds

Evgenii Vladimirovich Gert 1
Evgenii Vladimirovich Gert
1 Research Institute for Physical Chemical Problems of the Belarusian State University, Minsk
10.1070/RC1997v066n01ABEH000275
Published 30 November 1996
Communication , Volume 66, Issue 1, 73-92
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Gert E. V. Labile products of interaction of cellulose with nitrogen oxide compounds // Russian Chemical Reviews. 1997. Vol. 66. No. 1. pp. 73-92.
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Gert E. V. Labile products of interaction of cellulose with nitrogen oxide compounds // Russian Chemical Reviews. 1997. Vol. 66. No. 1. pp. 73-92.
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TY - JOUR
DO - 10.1070/RC1997v066n01ABEH000275
UR - https://rcr.colab.ws/publications/10.1070/RC1997v066n01ABEH000275
TI - Labile products of interaction of cellulose with nitrogen oxide compounds
T2 - Russian Chemical Reviews
AU - Gert, Evgenii Vladimirovich
PY - 1997
DA - 1996/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 73-92
IS - 1
VL - 66
ER -
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@article{1997_Gert,
author = {Evgenii Vladimirovich Gert},
title = {Labile products of interaction of cellulose with nitrogen oxide compounds},
journal = {Russian Chemical Reviews},
year = {1997},
volume = {66},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1997v066n01ABEH000275},
number = {1},
pages = {73--92},
doi = {10.1070/RC1997v066n01ABEH000275}
}
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Gert, Evgenii Vladimirovich. “Labile products of interaction of cellulose with nitrogen oxide compounds.” Russian Chemical Reviews, vol. 66, no. 1, Nov. 1997, pp. 73-92. https://rcr.colab.ws/publications/10.1070/RC1997v066n01ABEH000275.
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Abstract

Data concerning the conditions and kinetics of the formation, the methods for identification and isolation, the chemical and physical properties, and the crystal structure of cellulose trinitrite are presented. The conditions governing the formation of Knecht' sorption compound and other unstable crystalline products in the cellulose–N2O4 system are also discussed. The primary role of labile derivatives in the manifestation of polymorphism by cellulose on its regeneration from these compounds is demonstrated. The causes of the amorphisation of cellulose, which may occur in these systems, are examined. Examples of a rational combination of several functions of the reaction medium and of the labile nitrogen-containing compound present in it in the preparation of other materials of practical importance from polysaccharides (sulfate and acetate esters and structurally and chemically modified powdered forms of cellulose) are presented. The bibliography includes 160 references.

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