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Metal ions in unusual and unstable oxidation states in aqueous solutions: preparation and properties

Boris Grigor'evich Ershov 1
Boris Grigor'evich Ershov
1 Institute of Physical Chemistry, Russian Academy of Sciences, Moscow
10.1070/RC1997v066n02ABEH000264
Published 30 November 1996
Communication , Volume 66, Issue 2, 93-105
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Ershov B. G. Metal ions in unusual and unstable oxidation states in aqueous solutions: preparation and properties // Russian Chemical Reviews. 1997. Vol. 66. No. 2. pp. 93-105.
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Ershov B. G. Metal ions in unusual and unstable oxidation states in aqueous solutions: preparation and properties // Russian Chemical Reviews. 1997. Vol. 66. No. 2. pp. 93-105.
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TY - JOUR
DO - 10.1070/RC1997v066n02ABEH000264
UR - https://rcr.colab.ws/publications/10.1070/RC1997v066n02ABEH000264
TI - Metal ions in unusual and unstable oxidation states in aqueous solutions: preparation and properties
T2 - Russian Chemical Reviews
AU - Ershov, Boris Grigor'evich
PY - 1997
DA - 1996/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 93-105
IS - 2
VL - 66
ER -
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@article{1997_Ershov,
author = {Boris Grigor'evich Ershov},
title = {Metal ions in unusual and unstable oxidation states in aqueous solutions: preparation and properties},
journal = {Russian Chemical Reviews},
year = {1997},
volume = {66},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1997v066n02ABEH000264},
number = {2},
pages = {93--105},
doi = {10.1070/RC1997v066n02ABEH000264}
}
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Ershov, Boris Grigor'evich. “Metal ions in unusual and unstable oxidation states in aqueous solutions: preparation and properties.” Russian Chemical Reviews, vol. 66, no. 2, Nov. 1997, pp. 93-105. https://rcr.colab.ws/publications/10.1070/RC1997v066n02ABEH000264.
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Abstract

The properties of short-lived metal atoms and ions in unusual oxidation states in aqueous solutions, characterised by the presence of one electron in the outer s or p orbitals (the d10s1 and d10s2p1 configurations respectively), are discussed. The results of studies on such ions by pulse radiolysis with rapid optical detection and by the matrix isolation method in frozen aqueous solutions are presented. The nature of the dependences of fundamental characteristics of metal atoms and ions (optical transition energies, the electronic structures of various complexes, the oxidation–reduction potentials, etc.) on their positions in the Periodic System are analysed. The bibliography includes 93 references.

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