Home / Articles / Hydrogen spillover in heterogeneous catalysis

Hydrogen spillover in heterogeneous catalysis

Valerii Vasil'evich Rozanov 1
Valerii Vasil'evich Rozanov
, 
Oleg Valentinovich Krylov 1
Oleg Valentinovich Krylov
1 N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow
10.1070/RC1997v066n02ABEH000308
Published 30 November 1996
Communication , Volume 66, Issue 2, 107-119
129
Share
Cite this
GOST
 | 
Cite this
GOST
Copy cite
Rozanov V. V., Krylov O. V. Hydrogen spillover in heterogeneous catalysis // Russian Chemical Reviews. 1997. Vol. 66. No. 2. pp. 107-119.
GOST all authors (up to 50)
Copy cite
Rozanov V. V., Krylov O. V. Hydrogen spillover in heterogeneous catalysis // Russian Chemical Reviews. 1997. Vol. 66. No. 2. pp. 107-119.
RIS
 | 
Cite this
RIS
Copy cite
TY - JOUR
DO - 10.1070/RC1997v066n02ABEH000308
UR - https://rcr.colab.ws/publications/10.1070/RC1997v066n02ABEH000308
TI - Hydrogen spillover in heterogeneous catalysis
T2 - Russian Chemical Reviews
AU - Rozanov, Valerii Vasil'evich
AU - Krylov, Oleg Valentinovich
PY - 1997
DA - 1996/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 107-119
IS - 2
VL - 66
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors)
Copy cite
@article{1997_Rozanov,
author = {Valerii Vasil'evich Rozanov and Oleg Valentinovich Krylov},
title = {Hydrogen spillover in heterogeneous catalysis},
journal = {Russian Chemical Reviews},
year = {1997},
volume = {66},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1997v066n02ABEH000308},
number = {2},
pages = {107--119},
doi = {10.1070/RC1997v066n02ABEH000308}
}
MLA
Cite this
MLA
Copy cite
Rozanov, Valerii Vasil'evich, and Oleg Valentinovich Krylov. “Hydrogen spillover in heterogeneous catalysis.” Russian Chemical Reviews, vol. 66, no. 2, Nov. 1997, pp. 107-119. https://rcr.colab.ws/publications/10.1070/RC1997v066n02ABEH000308.
Views / Visits / Downloads
22 / 22 / 9

Abstract

The phenomenon of hydrogen spillover (interphase diffusion of adsorbed hydrogen), the methods for its detection, and the factors influencing it are examined. The common occurrence of the spillover and its role in various adsorption and catalytic processes, particularly in reactions involving hydrogen on multiphase catalysts, are demonstrated. The possible mechanisms of the spillover are analysed. The bibliography includes 189 references.

References

1.
Adlineation, Portholes and Spillover
Boudart M., Vannice M.A., Benson J.E.
Zeitschrift fur Physikalische Chemie , 1969
4.
4
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1949
5.
Hydrogen Spillover
Sermon P.A., Bond G.C.
Catalysis Reviews - Science and Engineering , 1974
6.
SPILLOVER OF SORBED SPECIES
Curtis Conner W., Pajonk G.M., Teichner S.J.
Advances in Catalysis , 1986
7.
Catalysis by Supported Metals
Boudart M.
Advances in Catalysis , 1969
8.
8
V. N. Kondrat'ev
"Kinetika Reaktsii v Gazovoi Faze" (Kinetics of Reactions in the Gas Phase) , 1959
11.
11
T. T. Bannister
Diss. Abstr. , 1959
12.
Studies of hydrogen spillover. Part 2.—Titration of hydrogen adsorbed upon silica supported platinum by pent-1-ene
Sermon P.A., Bond G.C.
Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases , 1976
13.
13
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1954
14.
Highly dispersed cobalt catalysts modified with transition metals and their applications to CO hydrogenation
Sugi Y., Matsuzaki T., Arakawa H., Takeuchi K., Hanaoka T.
Studies in Surface Science and Catalysis , 1993
15.
15
A. S. Holt
"Research in Photosynthesis" , 1957
16.
16
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1949
20.
20
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1954
22.
Teichner S.J., Pajonk G.M., Lacroix M.
1983
23.
23
N. V. Vostrilova
Dokl. Akad. Nauk Uzbek. SSR , 1958
24.
24
M. S. Ashkinazi
Dokl. Akad. Nauk SSSR , 1951
27.
27
A. A. Krasnovskii
Biofizika , 1956
30.
Hydroisomerization of n-pentane over hybrid catalysts containing supported hydrogenation catalyst
Aimoto K., Fujimoto K., Maeda K.
Studies in Surface Science and Catalysis , 1993
31.
Hydrogenation of isobutylene by spiltover hydrogen from Pt/KA-zeolite to NaY-zeolite
Ohgoshi S., Nakamura I., wakushima Y.
Studies in Surface Science and Catalysis , 1993
33.
33
M. B. Neiman
"Issledovanie Mekhanizma Okisleniya Butana" (Research on the Mechanism of the Oxidation of Butane) , 1939
34.
Development of hydrodesulfurization catalysts prepared using metal carbonyls
Ishihara A., Nomura M., Azuma M., Matsushita M., Shirouchi K., Kabe T.
Studies in Surface Science and Catalysis , 1993
35.
Spillover hydrogen effect on amorphous hydrocracking catalysts
Stumbo A.M., Grange P., Delmon B.
Catalysis Letters , 1995
36.
Spillover assisted catalytic effects on zeolites:Influence of the carrier gas on hexane cracking
Roessner F., Hagen A., Dmitriev R.V.
Studies in Surface Science and Catalysis , 1995
37.
Investigations on hydrogen spillover. Part 2.—Hydrocarbon conversion on bifunctional catalysts
Roessner F., Roland U., Braunschweig T.
Journal of the Chemical Society Faraday Transactions , 1995
38.
38
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1956
39.
Hydrogen and Oxygen Spillover on Pt/Al2O3 During Naphtha Reforming
Parera J.M., Traffano E.M., Musso J.C., Pieck C.L.
Studies in Surface Science and Catalysis , 1983
40.
Re influence on hydrogen spillover on Pt-Re/Al2O3
Traffano E.M., Parera J.M.
Applied Catalysis , 1986
41.
Exchange of Deuterium with the Hydroxyl Groups of Alumina
Carter J.L., Lucchesi P.J., Corneil P., Yates D.J., Sinfelt J.H.
The Journal of Physical Chemistry , 1965
42.
42
L. K. Obukhova
Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1960
45.
45
W. Hendrich
Roczniki Chemii , 1958
49.
Catalytic and infrared demonstrations of the effect of hydrogen spillover on a gel of silica
BIANCHI D., LACROIX M., PAJONK G., TEICHNER S.
Journal of Catalysis , 1979
50.
50
G. Glacomello
Gazzetta. , 1935
51.
Applications of EPR to a study of the hydrogenation of ethene and benzene over a supported Pd catalyst: detection of free radicals on a catalyst surface
Carley A.F., Edwards H.A., Mile B., Roberts M.W., Rowlands C.C., Hancock F.E., Jackson S.D.
Journal of the Chemical Society Faraday Transactions , 1994
52.
52
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1957
53.
Kinetics of The Reduction of Titanium Dioxide in Rh/TiO2 Catalysts
Duprez D., Miloudi A.
Studies in Surface Science and Catalysis , 1983
59.
Spillover rate from Pd to AI203
Chen B., Falconer J.L.
Journal of Catalysis , 1992
60.
60
A. N. Terenin
Optika i Spektrosk. , 1956
62.
Hydrogen spillover phenomena on Pt/ZrO2
Hoang D.-., Berndt H., Lieske H.
Catalysis Letters , 1995
63.
Catalyst design based on spillover theory
Fujimoto K.
Studies in Surface Science and Catalysis , 1993
64.
Carbon-supported dehydrogenation catalysts composed of platinum and ruthenium metals
Ando Y., Li X., Ito E., Yamashita M., Saito Y.
Studies in Surface Science and Catalysis , 1993
65.
Hydrogen spillover in the conversion of cyclohexane on ZSM-5 zeolites
Roessner F., Mroczek U., Hagen A.
Studies in Surface Science and Catalysis , 1993
68.
Hydrogen back spillover phenomena in the aromatization of light alkanes over hybrid catalysts. Mechanistic considerations
Van Mao R.L., Yao J., Dufresne L., Carli R., Ragaini V.
Studies in Surface Science and Catalysis , 1993
71.
New active sltes induced by hydrogen spillover in reduced Pt-Ga/HZSM-5 aromatization catalysts
Shpiro E.S., Shevchenko D.P., Dmitriev R.V., Tkachenko O.P., Minachev K.M.
Studies in Surface Science and Catalysis , 1993
74.
74
F. F. Litvin
Uspekhi Fiz. Nauk , 1960
76.
76
A. N. Terenin
"Fotokhimiya Krasitelei" (The Photochemistry of Dyes) , 1947
78.
Enhancement of hydrogen spillover by surface labile oxygen species on oxidized Pt/TiO2 catalyst
Sheng Li X., Zhao Li W., Xin Chen Y., Wang H.L.
Catalysis Letters , 1995
80.
80
N. N. Mel'nikov
Zhur. Obshch. Khim. , 1937
81.
The Effect of Calcination on H2 Spillover in Pt/MoO3
Kim J.G., Shyu J.Z., Regalbuto J.R.
Journal of Catalysis , 1993
82.
The Effect of Calcination on H2 Spillover in Pt/MoO3
Kim J.G., Regalbuto J.R.
Journal of Catalysis , 1993
84.
84
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1947
85.
85
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1947
86.
86
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1958
87.
87
J. F. Arens
"Advances in Organic Chemistry" , 1960
88.
The history and perspectives of spillover
Teichner S.J.
Studies in Surface Science and Catalysis , 1993
89.
89
A. A. Krasnovskii
Izd. Akad. Nauk SSSR, Moscow , 1955
90.
90
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1951
93.
The role of irreversible and reversible spillover hydrogen in reforming reactions
Chen S., Sun Y., Peng S.
Studies in Surface Science and Catalysis , 1993
94.
A surface structure model with allowance for spillover
Edvinsson R.K., Hudgins R.R., Silveston P.L.
Studies in Surface Science and Catalysis , 1993
95.
A mathematical model for spillover
Nam Y.W., Silveston P.L.
Studies in Surface Science and Catalysis , 1993
96.
On the possible role of adparticles spillover on a heterophase surface in causing superadditive activity
Savchenko V.I., Dadayan K.A.
Reaction Kinetics and Catalysis Letters , 1995
97.
COads spillover and low-temperature activity of heterophase catalysts in CO oxidation
Savchenko V.I.
Reaction Kinetics and Catalysis Letters , 1995
98.
Studies of hydrogen spillover. Part 1.—Study of the rate, extent and products of hydrogen spillover from platinum to the trioxides of tungsten and molybdenum
Sermon P.A., Bond G.C.
Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases , 1976
100.
Self-diffusion of hydrogen in H1.65MoO3
TAYLOR R.
Journal of Catalysis , 1980
101.
Surface migration of oxygen and of hydrogen in supported metal catalysts
Martin D., Duprez D.
Studies in Surface Science and Catalysis , 1993
104.
Use of hydrogen atoms for the low-temperature reduction of oxides
Che M., Canosa B., Gonzalez-Elipe A.R.
Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases , 1982
105.
105
F. F. Litvin
Dokl. Akad. Nauk SSSR , 1958
109.
110
M. F. Shostakovskii
Dokl. Akad. Nauk SSSR , 1960
110.
111
M. Calvin
1956
111.
Studies of the influence of a magnetic field on the diffusion of spilt-over deuterium on Y zeolites
Roland U., Winkler H., Bauch H., Steinberg K.
Journal of the Chemical Society Faraday Transactions , 1991
115.
116
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1957
117.
Hydrogen adsorption on silica-supported platinum studied by proton nuclear magnetic resonance spectroscopy
Chesters M.A., Dolan A., Lennon D., Williamson D.J., Packer K.J.
Journal of the Chemical Society Faraday Transactions , 1990
118.
119
V. V. Levchenko
Zhur. Obshch. Khim. , 1947
122.
Reaction of molecular hydrogen with the 100 face of MoO3
Erre R., Legay M.H., Fripiat J.J.
Surface Science , 1983
123.
Microcalorimetry applied to hydrogen bronzes
Tinet D., Partyka S., Rouquerol J., Fripiat J.J.
Materials Research Bulletin , 1982
125.
126
J. Wiemannand Ch. Clachet
Compt. rend. , 1948
126.
Proton NMR in a hydrogen molybdenum bronze
Cirillo A.C., Ryan L., Gerstein B.C., Fripiat J.J.
Journal of Chemical Physics , 1980
127.
Electronic properties of hydrogen molybdenum bronze
Tinet D., Canesson P., Estrade H., Fripiat J.J.
Journal of Physics and Chemistry of Solids , 1980
130.
Surface-to-bulk spillover of hydrogen (proton) in the catalysis of solid heteropoly compounds
Misono M., Igarashi H., Katamura K., Okuhara T., Mizuno N.
Studies in Surface Science and Catalysis , 1993
131.
Nature of Brönsted-acid sites in Ag3PW12O40 in the presence of hydrogen and reversible interconversion of protons and hydrogen
Baba T., Nomura M., Ohno Y., Hiroyama Y., One Y.
Studies in Surface Science and Catalysis , 1993
132.
133
C. Wilson
Trans. Electrochem. Soc. , 1941
133.
134
V. V. Korshak
Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1948
134.
Platinum metals-ceria synergism in autoexhaust catalyst
Yamada T., Kayano K., Funabiki M.
Studies in Surface Science and Catalysis , 1993
135.
Hydrogenation catalysts based on nickel and rare earths oxides
Sohier M.P., Wrobel G., Bonnelle J.P., Marcq J.P.
Applied Catalysis A: General , 1992
136.
The role of copper and zinc oxide in methanol synthesis catalysts
Burch R., Golunski S.E., Spencer M.S.
Journal of the Chemical Society Faraday Transactions , 1990
138.
Catalysis and spillover
Barrett E.P., Blackburn A.J., Yates M.A., Wang Y., Sermon P.A.
Studies in Surface Science and Catalysis , 1993
139.
140
1912
140.
Synergy at a distance in the synthesis of methanol over copper catalysts
Burch R., Chappell R.J., Golunski S.E.
Catalysis Letters , 1988
142.
Promoting effect of Ti02 addition to CuO-ZnO catalyst on methanol synthesis by catalytic hydrogenation of CO2
Arakawa H., Sayama K., Okabe K., Murakami A.
Studies in Surface Science and Catalysis , 1993
144.
Proximity requirement for Pd enhanced reducibility of Co2+ in NaY
Zhang Z., Sachtler W.M., Suib S.L.
Catalysis Letters , 1989
149.
150
Ya. E. Bernadskaya
"Iskusstvennoe Volokno" (Artificial Fibres) , 1952
150.
Reversible titanium(3+) formation by hydrogen adsorption on M/anatase (TiO2) catalysts
Conesa J.C., Soria J.
The Journal of Physical Chemistry , 1982
151.
152
W. Albert
Trans. Electrochem. Soc. , 1943
154.
Electrical conductivity study of hydrogen spillover on TiO2
Braunschweig T., Roland U., Winkler H.
Studies in Surface Science and Catalysis , 1993
155.
Investigations on hydrogen spillover. Part 1.—Electrical conductivity studies on titanium dioxide
Roland U., Salzer R., Braunschweig T., Roessner F., Winkler H.
Journal of the Chemical Society Faraday Transactions , 1995
156.
157
1903
157.
New active site for CO hydrogenation formed on promoted Rh catalyst by spillover hydrogen
Kato H., Mori T., Nakajima M., Mori Y., Hattori T., Murakami Y.
Studies in Surface Science and Catalysis , 1993
158.
Hydrogenation of CO2 over metal supported fine particles
Uematsu T., Fukuda M., Iijima T., Shimazu S.
Studies in Surface Science and Catalysis , 1993
161.
The mechanism of ethylene formation on chloride and oxychloride catalysts
Burch R., Chalker S., Loader P., Mariscal R., Rice D.A., Webb G.
Catalysis Today , 1992
163.
A new concept explaining catalytic synergy between two solid phases
Delmon B.
Reaction Kinetics and Catalysis Letters , 1980
164.
Salt effects in the reaction of hexacyanoferrate(II) with periodate
Bueno Iborra M., Maestre Alvarez A., Balón Almeida M.
Reaction Kinetics and Catalysis Letters , 1983
166.
167
Friedl.
168.
169
Friedl.
170.
171
Friedl.
171.
172
1918
174.
On the structural differences between alumina-supported CoMoS type I and alumina-, silica-, and carbon-supported CoMoS type II phases studied by XAFS, MES, and XPS
Bouwens S.M., Vanzon F.B., Vandijk M.P., Vanderkraan A.M., Debeer V.H., Vanveen J.A., Koningsberger D.C.
Journal of Catalysis , 1994
176.
Sulfidability and HDS activity of Co-Mo/Al2O3 catalysts
Scheffer B., van Oers E.M., Arnoldy P., de Beer V.H., Moulijn J.A.
Applied Catalysis , 1986
177.
Sulfidation of Co/Al2O3 and CoMo/Al2O3 catalysts studied by Mössbauer emission spectroscopy
Craje M.W., Debeer V.H., Vanveen J.A., Vanderkraan A.M.
Journal of Catalysis , 1993
178.
So-called ·CoMoS“ phase observed in carbon-supported cobalt sulfide catalyst by mössbauer emission spectroscopy
Van Der Kraan A.M., Crajé M.W., Gerkema E., Ramselaar W.L., De Beer V.H.
Applied Catalysis , 1988
179.
The role of Co in sulphidised Co–Mo hydrodesulphurisation catalysts supported on carbon and alumina
Vissers J.P., de Beer V.H., Prins R.
Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases , 1987
181.
182
1947
182.
Molecular hydrogen-originated solid acid catalysts
Hattori H.
Studies in Surface Science and Catalysis , 1993
183.
A new concept of hydrogen storage: a Pt/SO42 -ZrO2 material
Tanaka T., Ebitani K., Hattori H., Yoshida S.
Studies in Surface Science and Catalysis , 1993
184.
Isomerization of n-butane over NiSO42−ZrO2
Yori J.C., Parera J.M.
Applied Catalysis A: General , 1995
185.
The role of spillover in the hydrogenation of oxygenates adsorbed on Ni/Al2O3
Chen B., Falconer J.L.
Studies in Surface Science and Catalysis , 1993
186.
188
Chem. Abs. , 1955
187.
189
M. Godchot
Bull. Soc. chim. France (5) , 1913
188.
Polyfunctional Heterogeneous Catalysis
Weisz P.B.
Advances in Catalysis , 1962