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Principles of the electronic structure of complexes of non-transition elements

Galina Petrovna Kostikova 1
Galina Petrovna Kostikova
, 
Dimitrii Vasil'evich Korol'kov 1
Dimitrii Vasil'evich Korol'kov
, 
Yury Pavlovich Kostikov 1
Yury Pavlovich Kostikov
1 St. Petersburg State University, Department of Chemistry
10.1070/RC1997v066n04ABEH000243
Published 30 November 1996
Communication , Volume 66, Issue 4, 281-300
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Kostikova G. P., Korol'kov D. V., Kostikov Y. P. Principles of the electronic structure of complexes of non-transition elements // Russian Chemical Reviews. 1997. Vol. 66. No. 4. pp. 281-300.
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Kostikova G. P., Korol'kov D. V., Kostikov Y. P. Principles of the electronic structure of complexes of non-transition elements // Russian Chemical Reviews. 1997. Vol. 66. No. 4. pp. 281-300.
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TY - JOUR
DO - 10.1070/RC1997v066n04ABEH000243
UR - https://rcr.colab.ws/publications/10.1070/RC1997v066n04ABEH000243
TI - Principles of the electronic structure of complexes of non-transition elements
T2 - Russian Chemical Reviews
AU - Kostikova, Galina Petrovna
AU - Korol'kov, Dimitrii Vasil'evich
AU - Kostikov, Yury Pavlovich
PY - 1997
DA - 1996/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 281-300
IS - 4
VL - 66
ER -
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@article{1997_Kostikova,
author = {Galina Petrovna Kostikova and Dimitrii Vasil'evich Korol'kov and Yury Pavlovich Kostikov},
title = {Principles of the electronic structure of complexes of non-transition elements},
journal = {Russian Chemical Reviews},
year = {1997},
volume = {66},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1997v066n04ABEH000243},
number = {4},
pages = {281--300},
doi = {10.1070/RC1997v066n04ABEH000243}
}
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Kostikova, Galina Petrovna, et al. “Principles of the electronic structure of complexes of non-transition elements.” Russian Chemical Reviews, vol. 66, no. 4, Nov. 1997, pp. 281-300. https://rcr.colab.ws/publications/10.1070/RC1997v066n04ABEH000243.
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Abstract

The results of quantum-chemical calculations of electronic structures of complexes of non-transition elements are surveyed. Their X-ray emission and X-ray photoelectron spectra are analysed. General principles of the electronic structure of these complexes are established. It is shown that the effective participation of partially or completely occupied valence npm orbitals of the central atom A of ALk complexes in the formation of delocalised MOs, the negligibly small contribution of vacant And orbitals to the bonds with ligands, the valence inertness or rather low contribution of occupied Ans2 orbitals (except for 2s2 AO) to the valence MOs, and the initiation of the multiple bonds (in the electronic structure of complexes) due to covalent or hypervalent π-interactions involving only 2p (but not 3p, 4p, etc.) atomic orbitals are the most significant factors influencing the electronic structure of non-transition element compounds. The concept of d orbitals and hypervalent bonds is critisised. The bibliography includes 130 references.

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