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Competitive coordination: ambident ligands in the modern chemistry of metal complexes

Alexander Dmitrievich Garnovskii 1
Alexander Dmitrievich Garnovskii
, 
Dmitrii Aleksandrovich Garnovskii 1
Dmitrii Aleksandrovich Garnovskii
, 
Igor Stanislavovich Vasil'chenko 1
Igor Stanislavovich Vasil'chenko
, 
Anatolii Sergeevich Burlov 1
Anatolii Sergeevich Burlov
, 
Aleksander Pavlovich Sadimenko 2
Aleksander Pavlovich Sadimenko
, 
Igor Dzhafarovich Sadekov 1
Igor Dzhafarovich Sadekov
1 Institute of Physical and Organic Chemistry at Rostov State University
2 University of the Orange Free State, Republic of South Africa
10.1070/RC1997v066n05ABEH000258
Published 30 November 1996
Communication , Volume 66, Issue 5, 389-416
51
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Garnovskii A. D. et al. Competitive coordination: ambident ligands in the modern chemistry of metal complexes // Russian Chemical Reviews. 1997. Vol. 66. No. 5. pp. 389-416.
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Garnovskii A. D., Garnovskii D. A., Vasil'chenko I. S., Burlov A. S., Sadimenko A. P., Sadekov I. D. Competitive coordination: ambident ligands in the modern chemistry of metal complexes // Russian Chemical Reviews. 1997. Vol. 66. No. 5. pp. 389-416.
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TY - JOUR
DO - 10.1070/RC1997v066n05ABEH000258
UR - https://rcr.colab.ws/publications/10.1070/RC1997v066n05ABEH000258
TI - Competitive coordination: ambident ligands in the modern chemistry of metal complexes
T2 - Russian Chemical Reviews
AU - Garnovskii, Alexander Dmitrievich
AU - Garnovskii, Dmitrii Aleksandrovich
AU - Vasil'chenko, Igor Stanislavovich
AU - Burlov, Anatolii Sergeevich
AU - Sadimenko, Aleksander Pavlovich
AU - Sadekov, Igor Dzhafarovich
PY - 1997
DA - 1996/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 389-416
IS - 5
VL - 66
ER -
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@article{1997_Garnovskii,
author = {Alexander Dmitrievich Garnovskii and Dmitrii Aleksandrovich Garnovskii and Igor Stanislavovich Vasil'chenko and Anatolii Sergeevich Burlov and Aleksander Pavlovich Sadimenko and Igor Dzhafarovich Sadekov},
title = {Competitive coordination: ambident ligands in the modern chemistry of metal complexes},
journal = {Russian Chemical Reviews},
year = {1997},
volume = {66},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1997v066n05ABEH000258},
number = {5},
pages = {389--416},
doi = {10.1070/RC1997v066n05ABEH000258}
}
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Garnovskii, Alexander Dmitrievich, et al. “Competitive coordination: ambident ligands in the modern chemistry of metal complexes.” Russian Chemical Reviews, vol. 66, no. 5, Nov. 1997, pp. 389-416. https://rcr.colab.ws/publications/10.1070/RC1997v066n05ABEH000258.
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Abstract

Data on the problem of competitive coordination, obtained mainly during the last 10 years, are surveyed and treated systematically. The competitive binding of metals in complexes of bi- and poly-dentate ligand systems — simple diatomic and triatomic compounds (N2, O2, CO, CO2, CS2, etc.), ambident anions (CN-, NCX-, NO2-, SO32-, etc.), and neutral aliphatic, aromatic, and heterocyclic compounds, including chelating organic ligands — is examined. Attention is specially concentrated on nontraditional ways in which typical ligand systems are coordinated and on regioselective synthesis as a method for the specific synthesis of metal complexes with a specified location of the coordinate bond. The bibliography includes 575 references.

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