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Oxo-acidity in ionic melts

Viktor Leonidovich Cherginets 1
Viktor Leonidovich Cherginets
1 Institute for Single Crystals, National Academy of Sciences of Ukraine, Kharkov
10.1070/RC1997v066n07ABEH000297
Published 30 November 1996
Communication , Volume 66, Issue 7, 597-611
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Cherginets V. L. Oxo-acidity in ionic melts // Russian Chemical Reviews. 1997. Vol. 66. No. 7. pp. 597-611.
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Cherginets V. L. Oxo-acidity in ionic melts // Russian Chemical Reviews. 1997. Vol. 66. No. 7. pp. 597-611.
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TY - JOUR
DO - 10.1070/RC1997v066n07ABEH000297
UR - https://rcr.colab.ws/publications/10.1070/RC1997v066n07ABEH000297
TI - Oxo-acidity in ionic melts
T2 - Russian Chemical Reviews
AU - Cherginets, Viktor Leonidovich
PY - 1997
DA - 1996/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 597-611
IS - 7
VL - 66
ER -
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@article{1997_Cherginets,
author = {Viktor Leonidovich Cherginets},
title = {Oxo-acidity in ionic melts},
journal = {Russian Chemical Reviews},
year = {1997},
volume = {66},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1997v066n07ABEH000297},
number = {7},
pages = {597--611},
doi = {10.1070/RC1997v066n07ABEH000297}
}
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Cherginets, Viktor Leonidovich. “Oxo-acidity in ionic melts.” Russian Chemical Reviews, vol. 66, no. 7, Nov. 1997, pp. 597-611. https://rcr.colab.ws/publications/10.1070/RC1997v066n07ABEH000297.
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Abstract

The current state of research into the oxo-acidity in alkali metal nitrate, sulfate, and halide melts is analysed on the basis of the proposed classification of oxo-acidity reactions (Lux–Flood acid–base interactions). It is established that a considerable proportion of literature data on homogeneous acid–base equilibria are incorrect, since no account is taken in them of either the levelling of the acid (basic) properties by the solvent or of the error in the determination of the reaction stoichiometries. An explanation is proposed for the considerable scatter of data on the solubilities of oxides in ionic melts, which has been the principal inhibiting factor in the development of this field. The reactions of melts with gaseous acid and basic reagents are examined. The bibliography includes 171 references.

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