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The nature of electronic transitions in linear conjugated systems

Aleksei Dmitrievich Kachkovskii 1
Aleksei Dmitrievich Kachkovskii
1 Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kyiv
10.1070/RC1997v066n08ABEH000274
Published 30 November 1996
Communication , Volume 66, Issue 8, 647-664
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Kachkovskii A. D. The nature of electronic transitions in linear conjugated systems // Russian Chemical Reviews. 1997. Vol. 66. No. 8. pp. 647-664.
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Kachkovskii A. D. The nature of electronic transitions in linear conjugated systems // Russian Chemical Reviews. 1997. Vol. 66. No. 8. pp. 647-664.
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TY - JOUR
DO - 10.1070/RC1997v066n08ABEH000274
UR - https://rcr.colab.ws/publications/10.1070/RC1997v066n08ABEH000274
TI - The nature of electronic transitions in linear conjugated systems
T2 - Russian Chemical Reviews
AU - Kachkovskii, Aleksei Dmitrievich
PY - 1997
DA - 1996/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 647-664
IS - 8
VL - 66
ER -
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@article{1997_Kachkovskii,
author = {Aleksei Dmitrievich Kachkovskii},
title = {The nature of electronic transitions in linear conjugated systems},
journal = {Russian Chemical Reviews},
year = {1997},
volume = {66},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1997v066n08ABEH000274},
number = {8},
pages = {647--664},
doi = {10.1070/RC1997v066n08ABEH000274}
}
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Kachkovskii, Aleksei Dmitrievich. “The nature of electronic transitions in linear conjugated systems.” Russian Chemical Reviews, vol. 66, no. 8, Nov. 1997, pp. 647-664. https://rcr.colab.ws/publications/10.1070/RC1997v066n08ABEH000274.
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Abstract

The current state of investigations of the relationship between electronic transitions and molecular topology of linear conjugated systems, viz. polymethine dyes and α,ω-disubstituted polyenes, is considered. The effect of parity of methine groups in a polymethine chain, of filling of the electronic shell, molecular symmetry, and the topology of terminal groups on the electronic structure of polymethines and polyenes are described. Spectral effects arising upon changes in the structures of chromophores, and the nature of the first and higher transitions in linear conjugated compounds containing several chromophores are discussed. The localisation of transitions in molecular fragments and the conditions for the inversion of the polymethine and local electronic transitions in polyenes and polymethines are considered. The bibliography includes 242 references.

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