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New empirical models of radical abstraction reactions

Evgenii Timofeevich Denisov 1
Evgenii Timofeevich Denisov
1 Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region
10.1070/RC1997v066n10ABEH000364
Published 30 November 1996
Communication , Volume 66, Issue 10, 859-876
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Denisov E. T. New empirical models of radical abstraction reactions // Russian Chemical Reviews. 1997. Vol. 66. No. 10. pp. 859-876.
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Denisov E. T. New empirical models of radical abstraction reactions // Russian Chemical Reviews. 1997. Vol. 66. No. 10. pp. 859-876.
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TY - JOUR
DO - 10.1070/RC1997v066n10ABEH000364
UR - https://rcr.colab.ws/publications/10.1070/RC1997v066n10ABEH000364
TI - New empirical models of radical abstraction reactions
T2 - Russian Chemical Reviews
AU - Denisov, Evgenii Timofeevich
PY - 1997
DA - 1996/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 859-876
IS - 10
VL - 66
ER -
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@article{1997_Denisov,
author = {Evgenii Timofeevich Denisov},
title = {New empirical models of radical abstraction reactions},
journal = {Russian Chemical Reviews},
year = {1997},
volume = {66},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1997v066n10ABEH000364},
number = {10},
pages = {859--876},
doi = {10.1070/RC1997v066n10ABEH000364}
}
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Denisov, Evgenii Timofeevich. “New empirical models of radical abstraction reactions.” Russian Chemical Reviews, vol. 66, no. 10, Nov. 1997, pp. 859-876. https://rcr.colab.ws/publications/10.1070/RC1997v066n10ABEH000364.
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Abstract

Two physical models of radical abstraction reactions are described: the model of intersecting parabolas and the model of intersecting Morse curves. A systematic account is given of the results of the analysis of a large set of experimental data (rate constants and activation energies) for a wide variety of radical reactions. It is shown that the activation energies for such reactions depend on their enthalpies, on the force constants of the reacting bonds, the strength, length, and polarity of the X–Y bond in the X• +HY reaction, and also the presence in the reactants of one or several polar groups, π-bonds, and bulky groups adjoining the reaction centre. Solvation plays an important role in processes involving polar reactants. Both methods are compared as instruments for the calculation of the activation energy and bond strengths. The limits of applicability of the methods are examined. The bibliography includes 93 references.

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