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Gas hydrates, a new class of impurities in high purity gases and gas–vapour mixtures

Vladimir Mikhailovich Vorotyntsev 1
Vladimir Mikhailovich Vorotyntsev
, 
Vladimir Mikhailovich Malyshev 1
Vladimir Mikhailovich Malyshev
1 Institute of Chemistry of High-Purity Substances RAS, Nizhnii Novgorod
10.1070/RC1998v067n01ABEH000318
Published 30 November 1997
Communication , Volume 67, Issue 1, 81-92
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Vorotyntsev V. M., Malyshev V. M. Gas hydrates, a new class of impurities in high purity gases and gas–vapour mixtures // Russian Chemical Reviews. 1998. Vol. 67. No. 1. pp. 81-92.
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Vorotyntsev V. M., Malyshev V. M. Gas hydrates, a new class of impurities in high purity gases and gas–vapour mixtures // Russian Chemical Reviews. 1998. Vol. 67. No. 1. pp. 81-92.
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TY - JOUR
DO - 10.1070/RC1998v067n01ABEH000318
UR - https://rcr.colab.ws/publications/10.1070/RC1998v067n01ABEH000318
TI - Gas hydrates, a new class of impurities in high purity gases and gas–vapour mixtures
T2 - Russian Chemical Reviews
AU - Vorotyntsev, Vladimir Mikhailovich
AU - Malyshev, Vladimir Mikhailovich
PY - 1998
DA - 1997/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 81-92
IS - 1
VL - 67
ER -
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@article{1998_Vorotyntsev,
author = {Vladimir Mikhailovich Vorotyntsev and Vladimir Mikhailovich Malyshev},
title = {Gas hydrates, a new class of impurities in high purity gases and gas–vapour mixtures},
journal = {Russian Chemical Reviews},
year = {1998},
volume = {67},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1998v067n01ABEH000318},
number = {1},
pages = {81--92},
doi = {10.1070/RC1998v067n01ABEH000318}
}
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Vorotyntsev, Vladimir Mikhailovich, and Vladimir Mikhailovich Malyshev. “Gas hydrates, a new class of impurities in high purity gases and gas–vapour mixtures.” Russian Chemical Reviews, vol. 67, no. 1, Nov. 1998, pp. 81-92. https://rcr.colab.ws/publications/10.1070/RC1998v067n01ABEH000318.
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Abstract

The conditions of formation and structural features of gas hydrates are considered. The existing physicochemical models of formation of gas hydrates are analysed and an algorithm for calculating the parameters which influence the efficiency of gas purification is proposed. Theoretical values of dissociation pressure and water vapour pressure over the surface of mixed hydrates in mixtures of volatile inorganic hydrides are given as well as the distribution coefficients of the components between phases in the process of their formation. It is shown that the appearance of impurities in the form of gas hydrates in hydrides can markedly affect the efficiency of their refinement. The bibliography includes 43 references.

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