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Biomimetic alkane oxidation involving metal complexes

Elena Ivanovna Karasevich 1
Elena Ivanovna Karasevich
, 
Vera Sergeevna Kulikova 2
Vera Sergeevna Kulikova
, 
Aleksandr Evgen'evich Shilov 1
Aleksandr Evgen'evich Shilov
, 
Al'bert Aleksandrovich Shteinman 2
Al'bert Aleksandrovich Shteinman
1 Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow
2 Institute of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region
Published 30 November 1997
Communication , Volume 67, Issue 4, 335-355
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Karasevich E. I. et al. Biomimetic alkane oxidation involving metal complexes // Russian Chemical Reviews. 1998. Vol. 67. No. 4. pp. 335-355.
GOST all authors (up to 50)
Karasevich E. I., Kulikova V. S., Shilov A. E., Shteinman A. A. Biomimetic alkane oxidation involving metal complexes // Russian Chemical Reviews. 1998. Vol. 67. No. 4. pp. 335-355.
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TY - JOUR
DO - 10.1070/RC1998v067n04ABEH000315
UR - https://rcr.colab.ws/publications/10.1070/RC1998v067n04ABEH000315
TI - Biomimetic alkane oxidation involving metal complexes
T2 - Russian Chemical Reviews
AU - Karasevich, Elena Ivanovna
AU - Kulikova, Vera Sergeevna
AU - Shilov, Aleksandr Evgen'evich
AU - Shteinman, Al'bert Aleksandrovich
PY - 1998
DA - 1997/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 335-355
IS - 4
VL - 67
ER -
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@article{1998_Karasevich,
author = {Elena Ivanovna Karasevich and Vera Sergeevna Kulikova and Aleksandr Evgen'evich Shilov and Al'bert Aleksandrovich Shteinman},
title = {Biomimetic alkane oxidation involving metal complexes},
journal = {Russian Chemical Reviews},
year = {1998},
volume = {67},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1998v067n04ABEH000315},
number = {4},
pages = {335--355},
doi = {10.1070/RC1998v067n04ABEH000315}
}
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Cite this
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Karasevich, Elena Ivanovna, et al. “Biomimetic alkane oxidation involving metal complexes.” Russian Chemical Reviews, vol. 67, no. 4, Nov. 1998, pp. 335-355. https://rcr.colab.ws/publications/10.1070/RC1998v067n04ABEH000315.
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Abstract

The state-of-the-art of investigations in the field of catalysis of biological oxidation of saturated hydrocarbons by molecular oxygen and simulation of this process based on metal complexes is reviewed. The bibliography includes 296 references.

References

1.
1
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1948
2.
Cytochrome P450: Structure, function, and generation of reactive oxygen species
Bernhardt R.
Reviews of Physiology Biochemistry and Pharmacology , 1995
4.
Heme-Containing Oxygenases
Sono M., Roach M.P., Coulter E.D., Dawson J.H.
Chemical Reviews , 1996
5.
Cytochrome P450
Poulos T.L.
Current Opinion in Structural Biology , 1995
8.
8
V. N. Kondrat'ev
"Kinetika Reaktsii v Gazovoi Faze" (Kinetics of Reactions in the Gas Phase) , 1959
10.
Bacterial cytochromes P‐450
Munro A.W., Lindsay J.G.
Molecular Microbiology , 1996
11.
Epitope Mapping of Cytochrome P450cam (CYP101)
Kolesanova E.F., Kozin S.A., Rumyantsev A.B., Jung C., Hoa G.H., Archakov A.I.
Archives of Biochemistry and Biophysics , 1997
12.
12
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1950
13.
13
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1954
14.
Study of Water Binding to Low-Spin Fe(III) in Cytochrome P450 by Pulsed ENDOR and Four-Pulse ESEEM Spectroscopies
Goldfarb D., Bernardo M., Thomann H., Kroneck P.M., Ullrich V.
Journal of the American Chemical Society , 1996
16.
Highly purified microsomal P-450: The oxyferro intermediate stabilized at low temperature
Bonfils C., Debey P., Maurel P.
Biochemical and Biophysical Research Communications , 1979
17.
Structural characterization of horseradish peroxidase using EXAFS spectroscopy. Evidence for Fe = O ligation in compounds I and II
Penner-Hahn J.E., Smith Eble K., McMurry T.J., Renner M., Balch A.L., Groves J.T., Dawson J.H., Hodgson K.O.
Journal of the American Chemical Society , 1986
18.
18
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1951
19.
Chemical mechanisms of catalysis by cytochromes P-450: a unified view
Guengerich F.P., Macdonald T.L.
Accounts of Chemical Research , 1984
20.
Horseradish peroxidase. XXXVI. On the difference between peroxidase and metmyoglobin
Dunford H.B., Araiso T.
Biochemical and Biophysical Research Communications , 1979
23.
EPR‐spectroscopy of reduced oxyferrous‐P450cam
Davydov R., Kappl R., Hüttermann J., Peterson J.A.
FEBS Letters , 1991
26.
Mechanistic studies on a placental aromatase model reaction
Cole P.A., Robinson C.H.
Journal of the American Chemical Society , 1991
27.
Nitric oxide synthase structure and mechanism
Marletta M.A.
Journal of Biological Chemistry , 1993
29.
The enzymatic hydroxylation of n-octane by Corynebacterium sp. strain 7E1C.
31.
Cytochrome P450 and biological hydroxylation reactions
Ullrich V.
Topics in Current Chemistry , 1979
34.
Peroxo-iron and oxenoid-iron species as alternative oxygenating agents in cytochrome P450-catalyzed reactions: switching by threonine-302 to alanine mutagenesis of cytochrome P450 2B4.
35.
A role for Asp-251 in cytochrome P-450cam oxygen activation.
Gerber N.C., Sligar S.G.
Journal of Biological Chemistry , 1994
39.
39
V. F. Gachkovskii
Biofizika , 1959
40.
Enzymatic ω-Oxidation
Peterson J.A., Basu D., Coon M.J.
Journal of Biological Chemistry , 1966
45.
Substrate specificity of the alkane hydroxylase system of Pseudomonas oleovorans GPo1
van Beilen J.B., Kingma J., Witholt B.
Enzyme and Microbial Technology , 1994
46.
46
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1955
49.
Transient intermediates of the methane monooxygenase catalytic cycle.
Lee S.K., Nesheim J.C., Lipscomb J.D.
Journal of Biological Chemistry , 1993
50.
A transient intermediate of the methane monooxygenase catalytic cycle containing an FeIVFeIV cluster
Lee S.K., Fox B.G., Froland W.A., Lipscomb J.D., Munck E.
Journal of the American Chemical Society , 1993
51.
Spectroscopic detection of intermediates in the reaction of dioxygen with the reduced methane monooxygenase/hydroxylase from Methylococcus capsulatus (Bath)
Liu K.E., Wang D., Huynh B.H., Edmondson D.E., Salifoglou A., Lippard S.J.
Journal of the American Chemical Society , 1994
52.
Structures of met and azidomet hemerythrin at 1.66 A resolution.
Holmes M.A., Stenkamp R.E.
Journal of Molecular Biology , 1991
53.
Structure of myohemerythrin in the azidomet state at resolution
Sheriff S., Hendrickson W.A., Smith J.L.
Journal of Molecular Biology , 1987
54.
54
R. Livingston
J. Phys. Chem. , 1941
55.
55
G. A. Bogdanovskii
1958
56.
Mechanism of Assembly of the Tyrosyl Radical-Dinuclear Iron Cluster Cofactor of Ribonucleotide Reductase
Bollinger J.M., Edmondson D.E., Huynh B.H., Filley J., Norton J.R., Stubbe J.
Science , 1991
60.
60
A. N. Terenin
Optika i Spektrosk. , 1956
62.
62
A. A. Krasnovskii
"Sbornik, Voprosy Khimicheskoi Kinetiki" (Symposium, Problems of Chemical Kinetics) , 1955
64.
Substrate specificity of soluble methane monooxygenase
Green J., Dalton H.
Journal of Biological Chemistry , 1989
69.
Spectroscopic properties of the hydroxylase of methane monooxygenase.
Prince R.C., George G.N., Savas J.C., Cramer S.P., Patel R.N.
Biochimica et Biophysica Acta (BBA) - Protein Structure and Molecular Enzymology , 1988
70.
Structural characterization by EXAFS spectroscopy of the binuclear iron center in protein A of methane monooxygenase from Methylococcus capsulatus (Bath)
Ericson A., Hedman B., Hodgson K.O., Green J., Dalton H., Bentsen J.G., Beer R.H., Lippard S.J.
Journal of the American Chemical Society , 1988
71.
ESR studies of protein A of the soluble methane monooxygenase from Methylococcus capsulatus (Bath)
Woodland M.P., Patil D.S., Cammack R., Dalton H.
Biochimica et Biophysica Acta (BBA) - Protein Structure and Molecular Enzymology , 1986
73.
Ligation of the diiron site of the hydroxylase component of methane monooxygenase: An endor study.
Hendrich M.P., Fox B.G., Andersson K.K., Debrunner P.G., Lipscomb J.D.
Journal of Inorganic Biochemistry , 1991
74.
Amino acids at the active site of methane monooxygenase
Smith D.D., Dalton H.
Journal of Inorganic Biochemistry , 1991
76.
Kinetic and spectroscopic characterization of intermediates and component interactions in reactions of methane monooxygenase from Methylococcus capsulatus (Bath)
Liu K.E., Valentine A.M., Wang D., Huynh B.H., Edmondson D.E., Salifoglou A., Lippard S.J.
Journal of the American Chemical Society , 1995
78.
78
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1949
79.
79
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1952
80.
Large isotope effects in methane oxidation catalyzed by methane monooxygenase
Nesheim J.C., Lipscomb J.D.
Journal of Inorganic Biochemistry , 1995
81.
81
J. C. Ghosh
J. Indian Chem. Soc. , 1934
83.
Recombinant Toluene-4-monooxygenase:  Catalytic and Mössbauer Studies of the Purified Diiron and Rieske Components of a Four-Protein Complex
Pikus J.D., Studts J.M., Achim C., Kauffmann K.E., Münck E., Steffan R.J., McClay K., Fox B.G.
Biochemistry , 1996
85.
Reaction of the Excited Oxygen Atoms (O1D2) with Isobutane
Paraskevopoulos G., Cvetanović R.J.
Journal of Chemical Physics , 1969
86.
Reaction of the Excited Oxygen Atoms O(1D2) with Neopentane
Paraskevopoulos G., Cvetanović R.J.
Journal of Chemical Physics , 1970
88.
88
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1946
90.
90
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1951
91.
OXENOID MODELS FOR ENZYMIC HYDROXYLATIONS
Hamilton G.A., Giacin J.R., Hellman T.M., Snook M.E., Weller J.W.
Annals of the New York Academy of Sciences , 1973
92.
92
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1948
93.
93
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1956
94.
Epoxides as Obligatory Intermediates in the Metabolism of Olefins to Glycols
Maynert E.W., Foreman R.L., Watabe T.
Journal of Biological Chemistry , 1970
97.
1,2-Naphthalene oxide as an intermediate in the microsomal hydroxylation of naphthalene. V
Jerina D.M., Daly J.W., Witkop B., Zaltzman-Nirenberg P., Udenfriend S.
Biochemistry , 1970
98.
Arene Oxides as Intermediates in the Metabolism of Aromatic Substrates: Alkyl and Oxygen Migrations during Isomerization of Alkylated Arene Oxides
Jerina D.M., Kaubisch N., Daly J.W.
Proceedings of the National Academy of Sciences of the United States of America , 1971
99.
Differentiation between the concerted and stepwise mechanisms for aromatization (NIH-shift) of arene epoxides
Kasperek G.J., Bruice T.C., Yagi H., Jerina D.M.
Journal of the Chemical Society Chemical Communications , 1972
100.
Bioinorganic chemistry of oxygen
Ochiai E.
Journal of Inorganic and Nuclear Chemistry , 1975
102.
Electron paramagnetic resonance studies of the mechanism of substrate oxidation by methane monooxygenase
Dalton H., Wilkins P.C., Deighton N., Podmore I.D., Symons M.C.
Faraday Discussions , 1992
103.
103
L. N. Bell
Dokl. Akad. Nauk SSSR , 1956
104.
High-valent iron-porphyrin complexes related to peroxidase and cytochrome P-450
Groves J.T., Haushalter R.C., Nakamura M., Nemo T.E., Evans B.J.
Journal of the American Chemical Society , 1981
105.
Aliphatic hydroxylation by highly purified liver microsomal cytochrome P-450. Evidence for a carbon radical intermediate.
Groves J.T., McClusky G.A., White R.E., Coon M.J.
Biochemical and Biophysical Research Communications , 1978
106.
Intramolecular determination of primary kinetic isotope effects in hydroxylations catalyzed by cytochrome P-450.
Hjelmeland L.M., Aronow L., Trudell J.R.
Biochemical and Biophysical Research Communications , 1977
109.
Cryptic stereospecificity of methane monooxygenase
Priestley N.D., Floss H.G., Froland W.A., Lipscomb J.D., Williams P.G., Morimoto H.
Journal of the American Chemical Society , 1992
110.
Hydroxylation by cytochrome P-450 and metalloporphyrin models. Evidence for allylic rearrangement
111.
Timing of the radical recombination step in cytochrome P-450 catalysis with ring-strained probes
Ortiz de Montellano P.R., Stearns R.A.
Journal of the American Chemical Society , 1987
114.
Cytochrome P450-Catalyzed Hydroxylation of Hydrocarbons: Kinetic Deuterium Isotope Effects for the Hydroxylation of an Ultrafast Radical Clock
Atkinson J.K., Hollenberg P.F., Ingold K.U., Johnson C.C., Le Tadic M., Newcomb M., Putt D.A.
Biochemistry , 1994
115.
An incredibly fast apparent oxygen rebound rate constant for hydrocarbon hydroxylation by cytochrome P-450 enzymes
Newcomb M., Le Tadic M., Putt D.A., Hollenberg P.F.
Journal of the American Chemical Society , 1995
116.
Radical clock substrate probes and kinetic isotope effect studies of the hydroxylation of hydrocarbons by methane monooxygenase
Liu K.E., Johnson C.C., Newcomb M., Lippard S.J.
Journal of the American Chemical Society , 1993
117.
A Concerted Mechanism for Ethane Hydroxylation by the Particulate Methane Monooxygenase from Methylococcus capsulatus (Bath)
Wilkinson B., Zhu M., Priestley N.D., Nguyen H.-., Morimoto H., Williams P.G., Chan S.I., Floss H.G.
Journal of the American Chemical Society , 1996
119.
119
V. V. Levchenko
Zhur. Obshch. Khim. , 1947
120.
Five-coordinate carbon hydroxylation mechanism
Shestakov A.F., Shilov A.E.
Journal of Molecular Catalysis A Chemical , 1996
121.
121
V. V. Korshak
Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1953
122.
122
S. R. Rafikov
Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1953
123.
123
V. V. Levchenko
Zhur. Obshch. Khim. , 1952
124.
124
V. V. Levchenko
Zhur. Obshch. Khim. , 1952
125.
125
K. A. Andrianov
Vysokomol. Soed. , 1960
126.
Cytochrome P450 as an oxene transferase.
Lichtenberger F., Nastainczyk W., Ullrich V.
Biochemical and Biophysical Research Communications , 1976
127.
Hydroxylation and epoxidation catalyzed by iron-porphine complexes. Oxygen transfer from iodosylbenzene
Groves J.T., Nemo T.E., Myers R.S.
Journal of the American Chemical Society , 1979
128.
Catalytic hydroxylation of saturated hydrocarbons with the sodium hypohalite/manganese porphyrin system
De Poorter B., Ricci M., Bortolini O., Meunier B.
Journal of Molecular Catalysis , 1985
130.
130
J. Wiemann
Bull. Soc. chim. France , 1958
131.
131
N. Thooi
Compt. rend. , 1958
133.
Aliphatic hydroxylation catalyzed by iron porphyrin complexes
Groves J.T., Nemo T.E.
Journal of the American Chemical Society , 1983
134.
134
V. V. Korshak
Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1948
137.
137
S. R. Rafikov
Zh. Obshch. Khim. , 1944
138.
138
S. Ono
J. Chem. Soc. Japan , 1957
139.
A water-stable manganese(V)-oxo complex: definitive assignment of a .nu.Mnv.tplbond.O infrared vibration
Collins T.J., Powell R.D., Slebodnick C., Uffelman E.S.
Journal of the American Chemical Society , 1990
141.
Oxidation of red ferryl [(FeIVO)2+] porphyrin complexes to green ferryl [(FeIVO)2+] porphyrin radical complexes
Balch A.L., Latos-Grazynski L., Renner M.W.
Journal of the American Chemical Society , 1985
142.
Oxoiron(IV) porphyrins derived from charged iron(III) tetraarylporphyrins and chemical oxidants in aqueous and methanolic solutions
Bell S.E., Cooke P.R., Inchley P., Leanord D.R., Smith J.R., Robbins A.
Journal of the Chemical Society Perkin Transactions 2 , 1991
143.
143
Friedl.
144.
The contribution of tunnelling to high values of kinetic isotope effect in aliphatic hydroxylation by a cytochrome P-450 model
145.
145
Friedl.
146.
146
V. V. Korshak
Dokl. Akad. Nauk SSSR , 1952
147.
147
Y. Sasada
Acta Cryst. , 1898
150.
Ferric isoporphyrins from hydroperoxide oxidation of (tetraphenylporphinato)iron(III) complexes
151.
Shape-selective alkane hydroxylation by metalloporphyrin catalysts
Cook B.R., Reinert T.J., Suslick K.S.
Journal of the American Chemical Society , 1986
155.
Olefins epoxidation by Ph4PHSO5 catalyzed by manganese porphyrins: A novel mechanistic proposal
Campestrini S., Di Furia F., Ghiotti P., Novello F., Travaglini C.
Journal of Molecular Catalysis A Chemical , 1996
161.
Active Iron Oxo Centers for the Selective Catalytic Oxidation of Alkanes
Lyons J.E., Ellis P.E., Durante V.A.
Studies in Surface Science and Catalysis , 1991
163.
Mechanism of Catalytic Oxygenation of Alkanes by Halogenated Iron Porphyrins
Grinstaff M.W., Hill M.G., Labinger J.A., Gray H.B.
Science , 1994
164.
A chemical model of cytochrome P-450: mono-oxygenase-like activation of dioxygen
Karasevich E.I., Khenkin A.M., Shilov A.E.
Journal of the Chemical Society Chemical Communications , 1987
165.
165
Friedl.
166.
166
1917
167.
P-450-tpye dioxygen activation using hydrogen/colloidal platinum as an effective electron donor
169.
169
Friedl.
170.
170
1918
171.
Picket fence porphyrins. Synthetic models for oxygen binding hemoproteins
Collman J.P., Gagne R.R., Reed C., Halbert T.R., Lang G., Robinson W.T.
Journal of the American Chemical Society , 1975
173.
173
Friedl.
175.
Oxidation of Alkanes
Shilov A.E., Karasevich E.I.
Transition Metal Complexes as Drugs and Chemotherapeutic Agents , 1994
176.
176
G. V. Samsonov
"Metody Ispytaniya na Mikrotverdost' i Pribory" (Methods of Microhardness Testing and Apparatus) , 1965
177.
Reactivity of polyhalogenated and zeolite-encapsulated metalloporphyrins in oxidation with dioxygen
Battioni P., Iwanejko R., Mansuy D., Mlodnicka T., Poltowicz J., Sanchez F.
Journal of Molecular Catalysis A Chemical , 1996
178.
Metalloporphyrin-Catalyzed Oxidation of Cyclohexane with Dioxygen
Iwanejko R., Mulodnicka T., Potowicz J.
Studies in Surface Science and Catalysis , 1990
179.
Metal-dependent reactivity of some metalloporphyrins in oxidation with dioxygen
Haber J., Mlodnicka T., Poltowicz J.
Journal of Molecular Catalysis , 1989
180.
Oxidation of alkanes by dioxygen catalysed by photoactivated iron porphyrins
Maldotti A., Bartocci C., Amadelli R., Polo E., Battioni P., Mansuy D.
Journal of the Chemical Society Chemical Communications , 1991
181.
181
Chem. Abs. , 1947
182.
182
1947
183.
Synthesis of Biomimetic Heme Precursors:  The “Double Picket Fence” 5,10,15,20-Tetrakis(2‘,6‘- dinitro-4‘-tert-butylphenyl)porphyrin
Rose E., Kossanyi A., Quelquejeu M., Soleilhavoup M., Duwavran F., Bernard N., Lecas A.
Journal of the American Chemical Society , 1996
184.
184
F. Haurowitz
"The Chemistry and Function of Proteins" , 1965
185.
185
1954
187.
187
1954
188.
188
Chem. Abs. , 1955
192.
192
E. Pannain
Rend. Classe Sci. fis. mat. nat. (5) , 1908
193.
193
E. Pannain
Gazzetta , 1909
194.
194
A. A. Vertman
"Svoistva Rasplavov Zheleza" (Properties of Iron Melts) , 1969
195.
195
M. Allen
J. Chem. Soc. , 1961
196.
196
E. Müller
Z. Elektrochem. , 1910
198.
Aliphatic hydroxylation catalyzed by iron(III) porphyrins
Traylor T.G., Hill K.W., Fann W.P., Tsuchiya S., Dunlap B.E.
Journal of the American Chemical Society , 1992
199.
Asymmetric hydroxylation by a chiral iron porphyrin
Groves J.T., Viski P.
Journal of the American Chemical Society , 1989
200.
Triprotonated Methane, CH73+:  The Parent Heptacoordinate Carbonium Ion1
Olah G.A., Rasul G.
Journal of the American Chemical Society , 1996
201.
Synthesis, Structure, and Bonding of the Cation [{(C6H5)3PAu}5C]⊕
Scherbaum F., Grohmann A., Müller G., Schmidbaur H.
Angewandte Chemie - International Edition , 1989
202.
Fenton's reagent revisited
Walling C.
Accounts of Chemical Research , 1975
203.
204
Cherkesov A I
Ref. Zh. Khim. , 1968
204.
205
N. Bunge
Zhur. Russ. Fiz.-Khim. Obshch. , 1889
206.
New models of monooxygenase on the basis of Sn(II) compounds
Muradov N.Z., Shilov A.E., Shteinman A.A.
Reaction Kinetics and Catalysis Letters , 1975
207.
ASCORBIC ACID IN AROMATIC HYDROXYLATION
Udenfriend S., Clark C.T., Axelrod J., Brodie B.B.
Journal of Biological Chemistry , 1954
208.
Stereospecific aliphatic hydroxylation by iron-hydrogen peroxide. Evidence for a stepwise process
Groves J.T., Van der Puy M.
Journal of the American Chemical Society , 1976
209.
210
H. L. Wheeler
Chem. Zentr. , 1908
210.
A new combined oxidizing reagent system, Fe(CH3CN)63+-IO4-: Oxidation of paraffin hydrocarbons.
KOTANI E., KOBAYASHI S., ISHII Y., TOBINAGA S.
Chemical and Pharmaceutical Bulletin , 2011
213.
214
L. V. Pavlova
1965
214.
215
N. D. Tomashov
Zh. Prikl. Khim. , 1970
216.
Alkane functionalization by nonporphyrin iron complexes: mechanistic insights
Leising R.A., Norman R.E., Que L.
Inorganic Chemistry , 1990
217.
Free-radical clocks
Griller D., Ingold K.U.
Accounts of Chemical Research , 1980
221.
222
Chem. Abs. , 1961
223.
The selective functionalization of saturated hydrocarbons: Gif chemistry
Barton D.H., Doller D.
Accounts of Chemical Research , 1992
224.
Balavoine G., Barton D.H., Geletii Y.V., Hill D.R.
1993
225.
226
Chem. Abs. , 1961
229.
230
Chem. Abs. , 1962
234.
235
R. Peffen
1967
235.
Activation of the C–H bond in hydrocarbons: the isolation and catalytic activity of a trinuclear organoiron carboxylate cluster
Barton D.H., Gastiger M.J., Motherwell W.B.
Journal of the Chemical Society Chemical Communications , 1983
236.
Functionalization of saturated hydrocarbons. Part 4. The Gif system for selective oxidation using molecular oxygen
Barton D.H., Boivin J., Gastiger M., Morzycki J., Hay-Motherwell R.S., Motherwell W.B., Ozbalik N., Schwartzentruber K.M.
Journal of the Chemical Society Perkin Transactions 1 , 1986
238.
239
Mendelbaum H. G.
Bull. Soc. chim. France , 1973
239.
240
W. A. Waters
"The Chemistry of Free Radicals" , 1948
240.
241
M. S. Kharasch
"Grignard Reactions of Nonmetallic Substances" , 1954
241.
242
N. N. Seroenov
"O Nekotorykh Problemakh Khimicheskoi Kinetiki i Reaktsionnoi Sposobnosti" (Some Problems in Chemical Kinetics and Reactivity) , 1958
243.
Oxidation of saturated hydrocarbons by hydrogen peroxide in pyridine solution catalysed by copper and iron perchlorates
Geletii Y.V., Lavrushko V.V., Lubimova G.V.
Journal of the Chemical Society Chemical Communications , 1988
244.
245
G. A. Meerson
1958
248.
249
A. I. Fedorova
Dokl. Akad. Nauk SSSR , 1961
249.
Low-temperature, palladium(II)-catalyzed, solution-phase oxidation of methane to methanol derivative
Kao L.C., Hutson A.C., Sen A.
Journal of the American Chemical Society , 1991
250.
251
D. Goerrig
Chem. Abs. , 1959
252.
The role of iron in N2O decomposition on ZSM-5 zeolite and reactivity of the surface oxygen formed
Pannov G.I., Sobolev V.I., Kharitonov A.S.
Journal of Molecular Catalysis , 1990
253.
On the nature of superactive centers in H-ZSM-5 zeolites: Quantum chemical calculations
Filatov M.J., Pelmenschikov A.G., Zhidomirov G.M.
Journal of Molecular Catalysis , 1993
255.
A model for methane mono-oxygenase: dioxygen oxidation of alkanes by use of a µ-oxo binuclear iron complex
Kitajima N., Fukui H., Moro-oka Y.
Journal of the Chemical Society Chemical Communications , 1988
256.
Hydroxylation of alkanes and arenes using molecular oxygen
Kitajima N., Ito M., Fukui H., Moro-oka Y.
Journal of the Chemical Society Chemical Communications , 1991
257.
258
P. P. Alexander
Metals Alloys , 1938
258.
Alkane oxidation catalyzed by .mu.-oxo-bridged diferric complexes: a structure/reactivity correlation study
Menage S., Vincent J.M., Lambeaux C., Chottard G., Grand A., Fontecave M.
Inorganic Chemistry , 1993
259.
Alkane oxidation catalyzed by μ-oxo bridged diferric complexes: an overall mechanism
Ménage S., Vincent J., Lambeaux C., Fontecave M.
Journal of Molecular Catalysis A Chemical , 1996
260.
261
C. Friedel
Ann. Chim. Phys. , 1876
261.
262
C. Friedel
Ann. Chim. Phys. , 1876
262.
Fe(TPA)-Catalyzed Alkane Hydroxylation. Metal-Based Oxidation vs Radical Chain Autoxidation
Kim J., Harrison R.G., Kim C., Que L.
Journal of the American Chemical Society , 1996
264.
Alkane functionalization at (.mu.-oxo)diiron(III) centers
Leising R.A., Kim J., Perez M.A., Que L.
Journal of the American Chemical Society , 1993
265.
Alkane functionalization at nonheme iron centers. Stoichiometric transfer of metal-bound ligands to alkane
Kojima T., Leising R.A., Yan S., Que L.
Journal of the American Chemical Society , 1993
269.
270
N. Whitehouse
J. Soc. Chem. Ind. , 1907
270.
271
Stepanov B I
Zh. Obshch. Khim. , 1962
271.
Modeling the dinuclear sites of iron biomolecules: synthesis and properties of Fe2O(OAc)2Cl2(bipy)2 and its use as an alkane activation catalyst
Vincent J.B., Huffman J.C., Christou G., Li Q., Nanny M.A., Hendrickson D.N., Fong R.H., Fish R.H.
Journal of the American Chemical Society , 1988
275.
Models for diiron-oxo proteins: the peroxide adduct of Fe2(HPTB)(OH)(NO3)4
Brennan B.A., Chen Q., Juarez-Garcia C., True A.E., O'Connor C.J., Que L.
Inorganic Chemistry , 1991
276.
A binuclear iron peroxide complex capable of olefin epoxidation
Murch B.P., Bradley F.C., Que L.
Journal of the American Chemical Society , 1986
277.
Synthesis, Characterization, and Reversible Oxygenation of .mu.-Alkoxo Diiron(II) Complexes with the Dinucleating Ligand N,N,N',N'-Tetrakis{(6-methyl-2-pyridyl)methyl}-1,3-diamino- propan-2-olate
Hayashi Y., Kayatani T., Sugimoto H., Suzuki M., Inomata K., Uehara A., Mizutani Y., Kitagawa T., Maeda Y.
Journal of the American Chemical Society , 1995
278.
Models for iron-oxo proteins: dioxygen binding to a diferrous complex
Menage S., Brennan B.A., Juarez-Garcia C., Munck E., Que L.
Journal of the American Chemical Society , 1990
279.
Dioxygen binding to diferrous centers. Models for diiron-oxo proteins
Dong Y., Menage S., Brennan B.A., Elgren T.E., Jang H.G., Pearce L.L., Que L.
Journal of the American Chemical Society , 1993
280.
cis-μ-1,2-Peroxo Diiron Complex:  Structure and Reversible Oxygenation
Ookubo T., Sugimoto H., Nagayama T., Masuda H., Sato T., Tanaka K., Maeda Y., Ōkawa H., Hayashi Y., Uehara A., Suzuki M.
Journal of the American Chemical Society , 1996
282.
283
H. Moissan
Compt. rend. , 1902
283.
Belova Vera Sergeevna, Khenkin Alexander Mikhailovich, Postnov Victor Nikolaevich, Prusakov Valerii Evgen'evich, Shilov Aleksandr Evgen'evich, Stepanova Marina L
Mendeleev Communications , 1992
284.
Functionalization of silica gel: application for the catalytic oxidation of alkanes
285.
Biomimetic oxidation studies. 5. Mechanistic aspects of alkane functionalization with iron and iron-oxygen (Fe2O and Fe4O2) complexes in the presence of hydrogen peroxide
Fish R.H., Konings M.S., Oberhausen K.J., Fong R.H., Yu W.M., Christou G., Vincent J.B., Coggin D.K., Buchanan R.M.
Inorganic Chemistry , 1991
287.
BIOCHEMISTRY OF THE SOLUBLE METHANE MONOOXYGENASE
290.
Resonance Raman spectra of ferrylporphyrins and related compounds in dioxygen matrixes
Proniewicz L.M., Bajdor K., Nakamoto K.
The Journal of Physical Chemistry , 1986
292.
Rapid mineralisation of organophosphonates by visible light-enhanced peroxidase action of iron(III) complexes
Inouye Y., Jirousek M., Grätzel C.K., Grätzel M.
Journal of Molecular Catalysis , 1991
293.
Models for non-heme iron oxygenases: a high-valent iron-oxo intermediate
Leising R.A., Brennan B.A., Que L., Fox B.G., Munck E.
Journal of the American Chemical Society , 1991
294.
A High-Valent Nonheme Iron Intermediate. Structure and Properties of [Fe2(.mu.-O)2(5-Me-TPA)2](ClO4)3
Dong Y., Fujii H., Hendrich M.P., Leising R.A., Pan G., Randall C.R., Wilkinson E.C., Zang Y., Que L.
Journal of the American Chemical Society , 1995
295.
A binuclear non-heme iron oxo-transfer analog reaction system: observations and biological implications
Stassinopoulos A., Caradonna J.P.
Journal of the American Chemical Society , 1990