Home / Articles / Epoxidation of substituted norbornenes. Stereochemical aspects and accompanying intramolecular transformations

Epoxidation of substituted norbornenes. Stereochemical aspects and accompanying intramolecular transformations

Liliya Ivanovna Kasyan 1
Liliya Ivanovna Kasyan
1 Dnepropetrovsk State University
10.1070/RC1998v067n04ABEH000355
Published 30 November 1997
Communication , Volume 67, Issue 4, 263-278
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Kasyan L. I. Epoxidation of substituted norbornenes. Stereochemical aspects and accompanying intramolecular transformations // Russian Chemical Reviews. 1998. Vol. 67. No. 4. pp. 263-278.
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Kasyan L. I. Epoxidation of substituted norbornenes. Stereochemical aspects and accompanying intramolecular transformations // Russian Chemical Reviews. 1998. Vol. 67. No. 4. pp. 263-278.
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TY - JOUR
DO - 10.1070/RC1998v067n04ABEH000355
UR - https://rcr.colab.ws/publications/10.1070/RC1998v067n04ABEH000355
TI - Epoxidation of substituted norbornenes. Stereochemical aspects and accompanying intramolecular transformations
T2 - Russian Chemical Reviews
AU - Kasyan, Liliya Ivanovna
PY - 1998
DA - 1997/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 263-278
IS - 4
VL - 67
ER -
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@article{1998_Kasyan,
author = {Liliya Ivanovna Kasyan},
title = {Epoxidation of substituted norbornenes. Stereochemical aspects and accompanying intramolecular transformations},
journal = {Russian Chemical Reviews},
year = {1998},
volume = {67},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1998v067n04ABEH000355},
number = {4},
pages = {263--278},
doi = {10.1070/RC1998v067n04ABEH000355}
}
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Kasyan, Liliya Ivanovna. “Epoxidation of substituted norbornenes. Stereochemical aspects and accompanying intramolecular transformations.” Russian Chemical Reviews, vol. 67, no. 4, Nov. 1998, pp. 263-278. https://rcr.colab.ws/publications/10.1070/RC1998v067n04ABEH000355.
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Abstract

Traditional and new procedures for epoxidation of substituted norbornenes are described. The stereochemistry of this reaction and the influence of substituents on the reactivity of the substrate are analysed. The molecular rearrangements and heterocyclisation reactions that can accompany epoxidation are considered; examples of selective attack of oxidants at one of the double bonds in norbornenes containing an unsaturated substituent and also at a multiple bond in some polycyclic di- and triene systems are given. The bibliography includes 252 references.

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