Home / Articles / Haloalkenes activated by geminal groups in reactions with N-nucleophiles

Haloalkenes activated by geminal groups in reactions with N-nucleophiles

Alexander Yur'evich Rulev 1
Alexander Yur'evich Rulev
1 Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
10.1070/RC1998v067n04ABEH000372
Published 30 November 1997
Communication , Volume 67, Issue 4, 279-293
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Rulev A. Y. Haloalkenes activated by geminal groups in reactions with N-nucleophiles // Russian Chemical Reviews. 1998. Vol. 67. No. 4. pp. 279-293.
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Rulev A. Y. Haloalkenes activated by geminal groups in reactions with N-nucleophiles // Russian Chemical Reviews. 1998. Vol. 67. No. 4. pp. 279-293.
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TY - JOUR
DO - 10.1070/RC1998v067n04ABEH000372
UR - https://rcr.colab.ws/publications/10.1070/RC1998v067n04ABEH000372
TI - Haloalkenes activated by geminal groups in reactions with N-nucleophiles
T2 - Russian Chemical Reviews
AU - Rulev, Alexander Yur'evich
PY - 1998
DA - 1997/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 279-293
IS - 4
VL - 67
ER -
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@article{1998_Rulev,
author = {Alexander Yur'evich Rulev},
title = {Haloalkenes activated by geminal groups in reactions with N-nucleophiles},
journal = {Russian Chemical Reviews},
year = {1998},
volume = {67},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1998v067n04ABEH000372},
number = {4},
pages = {279--293},
doi = {10.1070/RC1998v067n04ABEH000372}
}
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Rulev, Alexander Yur'evich. “Haloalkenes activated by geminal groups in reactions with N-nucleophiles.” Russian Chemical Reviews, vol. 67, no. 4, Nov. 1998, pp. 279-293. https://rcr.colab.ws/publications/10.1070/RC1998v067n04ABEH000372.
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Abstract

Reactions of nitrogen nucleophiles with haloalkenes in which the halogen atom occupies α-position with respect to an electron-withdrawing group are considered. Primary attention is devoted to the elucidation of the dependence of the reaction path on the nature of the nucleophile and substrate and on the reaction conditions. Possible mechanisms of nucleophilic substitution of vinylic halogen atoms in alkenes with activating and leaving groups attached to the same carbon atom are discussed. The bibliography includes 169 references.

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