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Open-chain poly(organophosphazenes). Synthesis and properties

Svetlana Vasil'evna Vinogradova 1
Svetlana Vasil'evna Vinogradova
, 
Dzidra Rudol'fovna Tur 1
Dzidra Rudol'fovna Tur
, 
1 A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow
10.1070/RC1998v067n06ABEH000342
Published 30 November 1997
Communication , Volume 67, Issue 6, 515-534
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Vinogradova S. V., Tur D. R., Vasnev V. A. Open-chain poly(organophosphazenes). Synthesis and properties // Russian Chemical Reviews. 1998. Vol. 67. No. 6. pp. 515-534.
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Vinogradova S. V., Tur D. R., Vasnev V. A. Open-chain poly(organophosphazenes). Synthesis and properties // Russian Chemical Reviews. 1998. Vol. 67. No. 6. pp. 515-534.
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TY - JOUR
DO - 10.1070/RC1998v067n06ABEH000342
UR - https://rcr.colab.ws/publications/10.1070/RC1998v067n06ABEH000342
TI - Open-chain poly(organophosphazenes). Synthesis and properties
T2 - Russian Chemical Reviews
AU - Vinogradova, Svetlana Vasil'evna
AU - Tur, Dzidra Rudol'fovna
AU - Vasnev, Valery Aleksandrovich
PY - 1998
DA - 1997/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 515-534
IS - 6
VL - 67
ER -
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@article{1998_Vinogradova,
author = {Svetlana Vasil'evna Vinogradova and Dzidra Rudol'fovna Tur and Valery Aleksandrovich Vasnev},
title = {Open-chain poly(organophosphazenes). Synthesis and properties},
journal = {Russian Chemical Reviews},
year = {1998},
volume = {67},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1998v067n06ABEH000342},
number = {6},
pages = {515--534},
doi = {10.1070/RC1998v067n06ABEH000342}
}
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Vinogradova, Svetlana Vasil'evna, et al. “Open-chain poly(organophosphazenes). Synthesis and properties.” Russian Chemical Reviews, vol. 67, no. 6, Nov. 1998, pp. 515-534. https://rcr.colab.ws/publications/10.1070/RC1998v067n06ABEH000342.
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Abstract

Various methods for the synthesis of open-chain poly(organophosphazenes) are considered. The mechanism of polymerisation of hexachlorocyclotriphosphazene and the basic principles of formation of poly(organophosphazene) macromolecules by polymeranalogous reactions of poly(dichloro-phosphazene) with various nucleophilic reagents are analysed from a new viewpoint. The potential of this synthetic method for targeted design of poly(organophosphazenes) of various structures is shown. The possibility of synthesising poly(organophosphazenes) by polymerisation of cyclophosphazenes is also discussed. The problem of unit non-uniformity of poly(organophosphazenes) and its influence on the properties of these polymers are considered. The properties of poly(organophosphazenes) are considered in detail and it is shown that these polymers possess unusual valuable properties, which provide opportunities for their successful practical application. The bibliography includes 276 references.

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