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Catastrophic oxidation of metals

1 Scientific Research Institute of Steel, Moscow
10.1070/RC1998v067n07ABEH000374
Published 30 November 1997
Communication , Volume 67, Issue 7, 563-571
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Belousov V. V. Catastrophic oxidation of metals // Russian Chemical Reviews. 1998. Vol. 67. No. 7. pp. 563-571.
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Belousov V. V. Catastrophic oxidation of metals // Russian Chemical Reviews. 1998. Vol. 67. No. 7. pp. 563-571.
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TY - JOUR
DO - 10.1070/RC1998v067n07ABEH000374
UR - https://rcr.colab.ws/publications/10.1070/RC1998v067n07ABEH000374
TI - Catastrophic oxidation of metals
T2 - Russian Chemical Reviews
AU - Belousov, Valerii Vasil'evich
PY - 1998
DA - 1997/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 563-571
IS - 7
VL - 67
ER -
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@article{1998_Belousov,
author = {Valerii Vasil'evich Belousov},
title = {Catastrophic oxidation of metals},
journal = {Russian Chemical Reviews},
year = {1998},
volume = {67},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1998v067n07ABEH000374},
number = {7},
pages = {563--571},
doi = {10.1070/RC1998v067n07ABEH000374}
}
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Belousov, Valerii Vasil'evich. “Catastrophic oxidation of metals.” Russian Chemical Reviews, vol. 67, no. 7, Nov. 1998, pp. 563-571. https://rcr.colab.ws/publications/10.1070/RC1998v067n07ABEH000374.
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Abstract

The review deals with the current state of the problem of catastrophic oxidation of metals ('hot corrosion') caused by formation of a liquid corrosion product in a multi-component system. The kinetics, thermodynamics, and mechanisms of the two stages of accelerated oxidation of metals, namely, fast and super-fast stages, are considered with the copper–bismuth oxide system as an example. It is shown that the fast stage is caused by the formation of a liquid-channel grain boundary structure in the corrosion product, while the super-fast stage is caused by the high rate of dissolution of the oxide layer. The results of studies of the interaction of liquid phase with two-dimensional defects (grain boundaries) in solids are generalised. A model of catastrophic oxidation of metals is proposed. The bibliography includes 104 references.

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