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Peculiarities of the structure and properties of highly cross-linked polymer networks

Andrei Aleksandrovich Askadskii 1
Andrei Aleksandrovich Askadskii
1 A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow
10.1070/RC1998v067n08ABEH000387
Published 30 November 1997
Communication , Volume 67, Issue 8, 681-712
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Askadskii A. A. Peculiarities of the structure and properties of highly cross-linked polymer networks // Russian Chemical Reviews. 1998. Vol. 67. No. 8. pp. 681-712.
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Askadskii A. A. Peculiarities of the structure and properties of highly cross-linked polymer networks // Russian Chemical Reviews. 1998. Vol. 67. No. 8. pp. 681-712.
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TY - JOUR
DO - 10.1070/RC1998v067n08ABEH000387
UR - https://rcr.colab.ws/publications/10.1070/RC1998v067n08ABEH000387
TI - Peculiarities of the structure and properties of highly cross-linked polymer networks
T2 - Russian Chemical Reviews
AU - Askadskii, Andrei Aleksandrovich
PY - 1998
DA - 1997/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 681-712
IS - 8
VL - 67
ER -
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@article{1998_Askadskii,
author = {Andrei Aleksandrovich Askadskii},
title = {Peculiarities of the structure and properties of highly cross-linked polymer networks},
journal = {Russian Chemical Reviews},
year = {1998},
volume = {67},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1998v067n08ABEH000387},
number = {8},
pages = {681--712},
doi = {10.1070/RC1998v067n08ABEH000387}
}
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Askadskii, Andrei Aleksandrovich. “Peculiarities of the structure and properties of highly cross-linked polymer networks.” Russian Chemical Reviews, vol. 67, no. 8, Nov. 1998, pp. 681-712. https://rcr.colab.ws/publications/10.1070/RC1998v067n08ABEH000387.
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Abstract

Data on the structure and properties of highly cross-linked polymer networks in which the distance between cross-link points is several repeating units or even less than one unit, up to the networks consisting of nothing but cross-link points containing no linear fragments, are generalised. The dependences of a number of physical properties (the glass transition temperature, the modulus of elasticity, etc.) on the degree of cross-linking and the influence of various defects (branchings, dangled chains, etc.) on the properties of highly cross-linked networks are analysed. It is shown that the passage from sparse networks to highly cross-linked networks is accompanied by fundamental changes in their properties and that these properties can be described quantitatively taking into account the chemical structure of the network. The influence of the chemical structure of a cross-link point of the network on the properties is analysed; it is shown that the distances between the cross-link points in such networks can be estimated by nontraditional methods. Particular attention is paid to the cross-linked systems that are the basis for gradient-modulus materials in which the modulus of elasticity, the refractive index, and other properties vary over a wide range. The bibliography includes 93 references.

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