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The effect of strong intermolecular and chemical interactions on the compatibility of polymers

Andrei Aleksandrovich Askadskii 1
Andrei Aleksandrovich Askadskii
1 A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow
10.1070/RC1999v068n04ABEH000503
Published 30 November 1998
Communication , Volume 68, Issue 4, 317-331
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Askadskii A. A. The effect of strong intermolecular and chemical interactions on the compatibility of polymers // Russian Chemical Reviews. 1999. Vol. 68. No. 4. pp. 317-331.
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Askadskii A. A. The effect of strong intermolecular and chemical interactions on the compatibility of polymers // Russian Chemical Reviews. 1999. Vol. 68. No. 4. pp. 317-331.
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TY - JOUR
DO - 10.1070/RC1999v068n04ABEH000503
UR - https://rcr.colab.ws/publications/10.1070/RC1999v068n04ABEH000503
TI - The effect of strong intermolecular and chemical interactions on the compatibility of polymers
T2 - Russian Chemical Reviews
AU - Askadskii, Andrei Aleksandrovich
PY - 1999
DA - 1998/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 317-331
IS - 4
VL - 68
ER -
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@article{1999_Askadskii,
author = {Andrei Aleksandrovich Askadskii},
title = {The effect of strong intermolecular and chemical interactions on the compatibility of polymers},
journal = {Russian Chemical Reviews},
year = {1999},
volume = {68},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1999v068n04ABEH000503},
number = {4},
pages = {317--331},
doi = {10.1070/RC1999v068n04ABEH000503}
}
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Askadskii, Andrei Aleksandrovich. “The effect of strong intermolecular and chemical interactions on the compatibility of polymers.” Russian Chemical Reviews, vol. 68, no. 4, Nov. 1999, pp. 317-331. https://rcr.colab.ws/publications/10.1070/RC1999v068n04ABEH000503.
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Abstract

The data on compatibility and on the properties of polymer blends are generalised. The emphasis is placed on the formation of strong intermolecular interactions (dipole–dipole interaction and hydrogen bonding) between the components of blends, as well as on the chemical reactions between them. A criterion for the prediction of compatibility of polymers is described in detail. Different cases of compatibility are considered and the dependences of the glass transition temperatures on the composition of blends are analysed. The published data on the effect of strong intermolecular interactions between the blend components on the glass transition temperature are considered. The preparation of interpolymers is described whose macromolecules are composed of incompatible polymers, which leads to the so-called 'forced compatibility.' The bibliography includes 80 references.

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