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Synthetic diamond in electrochemistry

Yurii Viktorovich Pleskov 1
Yurii Viktorovich Pleskov
1 Frumkin Institute of Electrochemistry, Russian Academy of Sciences
Published 30 November 1998
Communication , Volume 68, Issue 5, 381-392
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Pleskov Y. V. Synthetic diamond in electrochemistry // Russian Chemical Reviews. 1999. Vol. 68. No. 5. pp. 381-392.
GOST all authors (up to 50)
Pleskov Y. V. Synthetic diamond in electrochemistry // Russian Chemical Reviews. 1999. Vol. 68. No. 5. pp. 381-392.
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TY - JOUR
DO - 10.1070/RC1999v068n05ABEH000494
UR - https://rcr.colab.ws/publications/10.1070/RC1999v068n05ABEH000494
TI - Synthetic diamond in electrochemistry
T2 - Russian Chemical Reviews
AU - Pleskov, Yurii Viktorovich
PY - 1999
DA - 1998/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 381-392
IS - 5
VL - 68
ER -
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@article{1999_Pleskov,
author = {Yurii Viktorovich Pleskov},
title = {Synthetic diamond in electrochemistry},
journal = {Russian Chemical Reviews},
year = {1999},
volume = {68},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1999v068n05ABEH000494},
number = {5},
pages = {381--392},
doi = {10.1070/RC1999v068n05ABEH000494}
}
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MLA
Pleskov, Yurii Viktorovich. “Synthetic diamond in electrochemistry.” Russian Chemical Reviews, vol. 68, no. 5, Nov. 1999, pp. 381-392. https://rcr.colab.ws/publications/10.1070/RC1999v068n05ABEH000494.
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Abstract

The results of studies on the electrochemistry of diamond carried out during the last decade are reviewed. Methods for the preparation, the crystalline structure and the main electrophysical properties of diamond thin films are considered. Depending on the doping conditions, the diamond behaves as a superwide-gap semiconductor or as a semimetal. It is shown that the 'metal-like' diamond is corrosion-resistant and can be used advantageously as an electrode in the electrosynthesis (in particular, for the electroreduction of compounds that are difficult to reduce) and electroanalysis. Kinetic characteristics of some redox reactions and the impedance parameters for diamond electrodes are presented. The results of comparative studies of the electrodes made of diamond single crystals, polycrystalline diamond and amorphous diamond-like carbon, which reveal the effect of the crystalline structure (e.g., the influence of intercrystallite boundaries) on the electrochemical properties of diamond, are presented. The bibliography includes 99 references.

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