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The problem of oxidation state stabilisation and some regularities of a Periodic system of the elements

Yurii Mikhailovich Kiselev 1
Yurii Mikhailovich Kiselev
, 
Yuriy Dmitrievich Tret'yakov 1
Yuriy Dmitrievich Tret'yakov
1 M. V. Lomonosov Moscow State University, Department of Chemistry
10.1070/RC1999v068n05ABEH000496
Published 30 November 1998
Communication , Volume 68, Issue 5, 365-379
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Kiselev Y. M., Tret'yakov Y. D. The problem of oxidation state stabilisation and some regularities of a Periodic system of the elements // Russian Chemical Reviews. 1999. Vol. 68. No. 5. pp. 365-379.
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Kiselev Y. M., Tret'yakov Y. D. The problem of oxidation state stabilisation and some regularities of a Periodic system of the elements // Russian Chemical Reviews. 1999. Vol. 68. No. 5. pp. 365-379.
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TY - JOUR
DO - 10.1070/RC1999v068n05ABEH000496
UR - https://rcr.colab.ws/publications/10.1070/RC1999v068n05ABEH000496
TI - The problem of oxidation state stabilisation and some regularities of a Periodic system of the elements
T2 - Russian Chemical Reviews
AU - Kiselev, Yurii Mikhailovich
AU - Tret'yakov, Yuriy Dmitrievich
PY - 1999
DA - 1998/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 365-379
IS - 5
VL - 68
ER -
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@article{1999_Kiselev,
author = {Yurii Mikhailovich Kiselev and Yuriy Dmitrievich Tret'yakov},
title = {The problem of oxidation state stabilisation and some regularities of a Periodic system of the elements},
journal = {Russian Chemical Reviews},
year = {1999},
volume = {68},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1999v068n05ABEH000496},
number = {5},
pages = {365--379},
doi = {10.1070/RC1999v068n05ABEH000496}
}
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Kiselev, Yurii Mikhailovich, and Yuriy Dmitrievich Tret'yakov. “The problem of oxidation state stabilisation and some regularities of a Periodic system of the elements.” Russian Chemical Reviews, vol. 68, no. 5, Nov. 1999, pp. 365-379. https://rcr.colab.ws/publications/10.1070/RC1999v068n05ABEH000496.
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Abstract

The general principles of the concept of oxidation state stabilisation are formulated. Problems associated with the preparation and provision of the highest valent forms of transition elements are considered. The empirical data concerning the synthesis of new compounds of rare-earth elements and d elements in unusually high oxidation states are analysed. The possibility of occurrence of the oxidation states + 9 and + 10 for some elements (for example, for iridium and platinum in tetraoxo ions) are discussed. Approaches to the realisation of these states are outlined and it is demonstrated that solid phases or matrices containing alkali metal cations are the most promising systems for the stabilisation of these high oxidation states. Selected thermodynamic features typical of metal halides and oxides and the regularities of the changes in the extreme oxidation states of d elements are considered. The bibliography includes 266 references.

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