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Transformations of organic compounds under the action of mechanical stress

Aleksandra Mikhailovna Dubinskaya 1
Aleksandra Mikhailovna Dubinskaya
1 N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow
10.1070/RC1999v068n08ABEH000435
Published 30 November 1998
Communication , Volume 68, Issue 8, 637-652
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Dubinskaya A. M. Transformations of organic compounds under the action of mechanical stress // Russian Chemical Reviews. 1999. Vol. 68. No. 8. pp. 637-652.
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Dubinskaya A. M. Transformations of organic compounds under the action of mechanical stress // Russian Chemical Reviews. 1999. Vol. 68. No. 8. pp. 637-652.
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TY - JOUR
DO - 10.1070/RC1999v068n08ABEH000435
UR - https://rcr.colab.ws/publications/10.1070/RC1999v068n08ABEH000435
TI - Transformations of organic compounds under the action of mechanical stress
T2 - Russian Chemical Reviews
AU - Dubinskaya, Aleksandra Mikhailovna
PY - 1999
DA - 1998/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 637-652
IS - 8
VL - 68
ER -
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@article{1999_Dubinskaya,
author = {Aleksandra Mikhailovna Dubinskaya},
title = {Transformations of organic compounds under the action of mechanical stress},
journal = {Russian Chemical Reviews},
year = {1999},
volume = {68},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1999v068n08ABEH000435},
number = {8},
pages = {637--652},
doi = {10.1070/RC1999v068n08ABEH000435}
}
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Dubinskaya, Aleksandra Mikhailovna. “Transformations of organic compounds under the action of mechanical stress.” Russian Chemical Reviews, vol. 68, no. 8, Nov. 1999, pp. 637-652. https://rcr.colab.ws/publications/10.1070/RC1999v068n08ABEH000435.
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Abstract

Transformations of organic compounds (monomeric and polymeric) under the action of mechanical stress are considered. Two types of processes occur under these conditions. The first type involves disordering and amorphisation of crystal structure and conformational transformations as a result of rupture of intermolecular bonds. The second type includes mechanochemical reactions activated by deformation of valence bonds and angles under mechanical stress, namely, the rupture of bonds, oxidation and hydrolysis. Data on the organic mechanochemical synthesis of new compounds or molecular complexes are systematised and generalised. It is demonstrated that mechanical treatment ensures mass transfer and the contact of reacting species in these reactions. Proteins are especially sensitive to mechanical stress and undergo denaturation; enzymes are inactivated. The bibliography includes 115 references.

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