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Electronic effects of substitution and reconstruction of the coordination polyhedron in adducts of Main Group IV element halides

Eleonora Aleksandrovna Kravchenko 1
Eleonora Aleksandrovna Kravchenko
, 
Yurii Aleksandrovich Buslaev 1
Yurii Aleksandrovich Buslaev
1 Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow
10.1070/RC1999v068n09ABEH000497
Published 30 November 1998
Communication , Volume 68, Issue 9, 709-726
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Kravchenko E. A., Buslaev Y. A. Electronic effects of substitution and reconstruction of the coordination polyhedron in adducts of Main Group IV element halides // Russian Chemical Reviews. 1999. Vol. 68. No. 9. pp. 709-726.
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Kravchenko E. A., Buslaev Y. A. Electronic effects of substitution and reconstruction of the coordination polyhedron in adducts of Main Group IV element halides // Russian Chemical Reviews. 1999. Vol. 68. No. 9. pp. 709-726.
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TY - JOUR
DO - 10.1070/RC1999v068n09ABEH000497
UR - https://rcr.colab.ws/publications/10.1070/RC1999v068n09ABEH000497
TI - Electronic effects of substitution and reconstruction of the coordination polyhedron in adducts of Main Group IV element halides
T2 - Russian Chemical Reviews
AU - Kravchenko, Eleonora Aleksandrovna
AU - Buslaev, Yurii Aleksandrovich
PY - 1999
DA - 1998/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 709-726
IS - 9
VL - 68
ER -
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@article{1999_Kravchenko,
author = {Eleonora Aleksandrovna Kravchenko and Yurii Aleksandrovich Buslaev},
title = {Electronic effects of substitution and reconstruction of the coordination polyhedron in adducts of Main Group IV element halides},
journal = {Russian Chemical Reviews},
year = {1999},
volume = {68},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1999v068n09ABEH000497},
number = {9},
pages = {709--726},
doi = {10.1070/RC1999v068n09ABEH000497}
}
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Kravchenko, Eleonora Aleksandrovna, and Yurii Aleksandrovich Buslaev. “Electronic effects of substitution and reconstruction of the coordination polyhedron in adducts of Main Group IV element halides.” Russian Chemical Reviews, vol. 68, no. 9, Nov. 1999, pp. 709-726. https://rcr.colab.ws/publications/10.1070/RC1999v068n09ABEH000497.
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Abstract

Nuclear quadrupole resonance and X-ray data on the electronic effects of substitution of acidoligands and reconstruction of the coordination polyhedra in adducts (complexes) of tin(IV), germanium(IV) and silicon(IV) tetrahalides due to the change in the central metal coordination number are surveyed and systematically described. The σ- and π-electron density redistribution over the central metal–halogen bonds resulting from substitution or reconstruction of the coordination polyhedra from pseudooctahedral to trigonal-bipyramidal geometry is discussed. The bibliography includes 55 references.

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