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Radical pairs in redox reactions involving sterically hindered quinones and phenols

Alexandr Ivanovich Prokof'ev 1
Alexandr Ivanovich Prokof'ev
1 A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow
10.1070/RC1999v068n09ABEH000508
Published 30 November 1998
Communication , Volume 68, Issue 9, 727-736
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Prokof'ev A. I. Radical pairs in redox reactions involving sterically hindered quinones and phenols // Russian Chemical Reviews. 1999. Vol. 68. No. 9. pp. 727-736.
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Prokof'ev A. I. Radical pairs in redox reactions involving sterically hindered quinones and phenols // Russian Chemical Reviews. 1999. Vol. 68. No. 9. pp. 727-736.
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TY - JOUR
DO - 10.1070/RC1999v068n09ABEH000508
UR - https://rcr.colab.ws/publications/10.1070/RC1999v068n09ABEH000508
TI - Radical pairs in redox reactions involving sterically hindered quinones and phenols
T2 - Russian Chemical Reviews
AU - Prokof'ev, Alexandr Ivanovich
PY - 1999
DA - 1998/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 727-736
IS - 9
VL - 68
ER -
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@article{1999_Prokof'ev,
author = {Alexandr Ivanovich Prokof'ev},
title = {Radical pairs in redox reactions involving sterically hindered quinones and phenols},
journal = {Russian Chemical Reviews},
year = {1999},
volume = {68},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1999v068n09ABEH000508},
number = {9},
pages = {727--736},
doi = {10.1070/RC1999v068n09ABEH000508}
}
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Prokof'ev, Alexandr Ivanovich. “Radical pairs in redox reactions involving sterically hindered quinones and phenols.” Russian Chemical Reviews, vol. 68, no. 9, Nov. 1999, pp. 727-736. https://rcr.colab.ws/publications/10.1070/RC1999v068n09ABEH000508.
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Abstract

The review summarises the results of studies on the redox reactions involving sterically hindered quinones and pyrocatechols (phenols) occurring in glassy and single-crystal matrices. Exposure of these systems to light results in the transfer of a hydrogen atom or an electron from the phenol to the quinone accompanied by the formation of radical pairs, viz., two paramagnetic species existing in the triplet state. Studies of the transformations in single-crystal matrices enabled separation of the mechanisms of electron and hydrogen atom transfer. Synchronous transfer of two hydrogen atoms from two sterically hindered phenol molecules to o-benzoquinone is also possible. The bibliography includes 39 references.

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