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Ferroelectricity of polymers based on vinylidene fluoride

Valentin Valentinovich Kochervinskii 1
Valentin Valentinovich Kochervinskii
1 Troitsk Institute for Innovation and Fusion Research
10.1070/RC1999v068n10ABEH000446
Published 30 November 1998
Communication , Volume 68, Issue 10, 821-857
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Kochervinskii V. V. Ferroelectricity of polymers based on vinylidene fluoride // Russian Chemical Reviews. 1999. Vol. 68. No. 10. pp. 821-857.
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Kochervinskii V. V. Ferroelectricity of polymers based on vinylidene fluoride // Russian Chemical Reviews. 1999. Vol. 68. No. 10. pp. 821-857.
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TY - JOUR
DO - 10.1070/RC1999v068n10ABEH000446
UR - https://rcr.colab.ws/publications/10.1070/RC1999v068n10ABEH000446
TI - Ferroelectricity of polymers based on vinylidene fluoride
T2 - Russian Chemical Reviews
AU - Kochervinskii, Valentin Valentinovich
PY - 1999
DA - 1998/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 821-857
IS - 10
VL - 68
ER -
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@article{1999_Kochervinskii,
author = {Valentin Valentinovich Kochervinskii},
title = {Ferroelectricity of polymers based on vinylidene fluoride},
journal = {Russian Chemical Reviews},
year = {1999},
volume = {68},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1999v068n10ABEH000446},
number = {10},
pages = {821--857},
doi = {10.1070/RC1999v068n10ABEH000446}
}
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Kochervinskii, Valentin Valentinovich. “Ferroelectricity of polymers based on vinylidene fluoride.” Russian Chemical Reviews, vol. 68, no. 10, Nov. 1999, pp. 821-857. https://rcr.colab.ws/publications/10.1070/RC1999v068n10ABEH000446.
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Abstract

Characteristics of the ferroelectricity in polyvinylidene fluoride (PVDF) and copolymers based on vinylidene fluoride (VDF) with different previous thermomechanical histories are analysed. Switching of polarisation and the fluctuation mechanism of formation of new nuclei upon the appearance of conformation defects such as kink bonds are considered. The role of the space charge, which stabilises the new polarisation position, is noted. It is shown that the Curie transition can be either a first- or second-order phase transition depending on the copolymer composition. The influence of the morphology of PVDF on some ferroelectric characteristics is found. In particular, the morphology of thick lamellar crystals is favourable for enhanced spontaneous polarisation. It is shown that a ferroelectric structure approaching the texture of an ideal single crystal can be created in Langmuir–Blodgett films. As the number of unimolecular layers decreases, the concentration of conformational defects in these films increases and the crystallographic order in the lattice is violated. This intensifies the low-temperature Curie transition. The bibliography includes 247 references.

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